GB1067433A – Improvements in or relating to anaerobic curing compositions
– Google Patents
GB1067433A – Improvements in or relating to anaerobic curing compositions
– Google Patents
Improvements in or relating to anaerobic curing compositions
Info
Publication number
GB1067433A
GB1067433A
GB43958/63A
GB4395863A
GB1067433A
GB 1067433 A
GB1067433 A
GB 1067433A
GB 43958/63 A
GB43958/63 A
GB 43958/63A
GB 4395863 A
GB4395863 A
GB 4395863A
GB 1067433 A
GB1067433 A
GB 1067433A
Authority
GB
United Kingdom
Prior art keywords
acid
butyl
hydroquinone
neopentyl glycol
acrylic
Prior art date
1963-11-07
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB43958/63A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hexion UK Ltd
Original Assignee
Borden Chemical UK Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1963-11-07
Filing date
1963-11-07
Publication date
1967-05-03
Priority to US3125480D
priority
Critical
patent/US3125480A/en
1963-11-07
Application filed by Borden Chemical UK Ltd
filed
Critical
Borden Chemical UK Ltd
1963-11-07
Priority to GB43958/63A
priority
patent/GB1067433A/en
1963-11-26
Priority to FR954963A
priority
patent/FR1376118A/en
1967-05-03
Publication of GB1067433A
publication
Critical
patent/GB1067433A/en
Status
Expired
legal-status
Critical
Current
Links
Espacenet
Global Dossier
Discuss
Classifications
C—CHEMISTRY; METALLURGY
C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
C08F20/10—Esters
C08F20/20—Esters of polyhydric alcohols or polyhydric phenols, e.g. 2-hydroxyethyl (meth)acrylate or glycerol mono-(meth)acrylate
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C67/00—Preparation of carboxylic acid esters
C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
C—CHEMISTRY; METALLURGY
C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 – C09J183/16
Abstract
Neopentyl glycol diacrylate and dimethacrylate are prepared by heating to boiling 1 mole of neopentyl glycol and 2.5 moles of acrylic or methacrylic acid in benzene in the presence of hydroquinone and concentrated sulphuric acid, the water of reaction being removed azeotropically and continuously. The sulphuric acid and unreacted (meth)acrylic acid are removed by washing with water.ALSO:Anaerobic curing compositions suitable for the bonding of metallic surfaces such as nuts and bolts comprise the neopentyl glycol diester of acrylic or methacrylic acid, a polymerization inhibitor, an organic peroxy compound as a polymerization initiator and, optionally, an accelerator or activator. Suitable inhibitors are hydroquinone, pyrogallol, quinhydrone and monoaryl (e.g. monophenyl) or monoalkyl (e.g. monobutyl) ethers of hydroquinone. Initiators specified are di-t.-butyl peroxide, t.-butyl hydroperoxide, t.-butyl perbenzoate, di-t.-butyl perphthalate (used in dimethyl phthalate), methyl ethyl ketone peroxide, cumene hydroperoxide and di-isopropylbenzene hydroperoxide. As accelerator there may be used benzene sulphinic acid, which may be substituted by a methyl and/or chloro group, cobalt compounds, e.g. cobalt chloride, ascorbic and isoascorbic acids, and amines such as dimethylaniline, triethanolamine and triethylamine.
GB43958/63A
1963-11-07
1963-11-07
Improvements in or relating to anaerobic curing compositions
Expired
GB1067433A
(en)
Priority Applications (3)
Application Number
Priority Date
Filing Date
Title
US3125480D
US3125480A
(en)
1963-11-07
Neopentyl glycol acrylate ester
GB43958/63A
GB1067433A
(en)
1963-11-07
1963-11-07
Improvements in or relating to anaerobic curing compositions
FR954963A
FR1376118A
(en)
1963-11-07
1963-11-26
Anaerobic stabilization composition
Applications Claiming Priority (1)
Application Number
Priority Date
Filing Date
Title
GB43958/63A
GB1067433A
(en)
1963-11-07
1963-11-07
Improvements in or relating to anaerobic curing compositions
Publications (1)
Publication Number
Publication Date
GB1067433A
true
GB1067433A
(en)
1967-05-03
Family
ID=10431124
Family Applications (1)
Application Number
Title
Priority Date
Filing Date
GB43958/63A
Expired
GB1067433A
(en)
1963-11-07
1963-11-07
Improvements in or relating to anaerobic curing compositions
Country Status (2)
Country
Link
US
(1)
US3125480A
(en)
GB
(1)
GB1067433A
(en)
Cited By (1)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
GB2247685A
(en)
*
1990-09-05
1992-03-11
Johnson Matthey Plc
Improvements in cross-linked polymers
Families Citing this family (6)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
US3769138A
(en)
*
1964-12-14
1973-10-30
D Robbiati
Apparatus and a method for preparing a composite laminated sheet
US3419512A
(en)
*
1965-12-23
1968-12-31
Borden Inc
Anaerobic curing composition
US3658624A
(en)
*
1969-09-29
1972-04-25
Borden Inc
Bonding method employing a two part anaerobically curing adhesive composition
DE2531180C2
(en)
*
1975-07-11
1982-04-01
Institut chimičeskoj fiziki Akademii Nauk SSSR, Moskva
Anaerobic mixture
US4052244A
(en)
*
1976-08-18
1977-10-04
National Starch And Chemical Corporation
Rapid curing two part adhesive
US4536267A
(en)
*
1983-04-01
1985-08-20
Matsushita Electric Industrial Co., Ltd.
Plastic lens of neopentyl glycol dimethacrylate copolymerized with methoxy diethylene glycol methacrylate or diethylene glycol dimethacrylate
Family Cites Families (5)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
US2346644A
(en)
*
1940-03-18
1944-04-18
Stein Hall Mfg Co
Method of bonding
US2414414A
(en)
*
1942-10-06
1947-01-14
Pennsylvania Coal Products Com
Method of bonding materials with a cold-setting dihydroxy benzene aldehyde adhesive
BE480209A
(en)
*
1947-02-07
BE504916A
(en)
*
1950-07-29
1900-01-01
DE1109891B
(en)
*
1955-08-25
1961-06-29
American Sealants Company
Liquid mixtures that polymerize in the absence of air
0
US
US3125480D
patent/US3125480A/en
not_active
Expired – Lifetime
1963
1963-11-07
GB
GB43958/63A
patent/GB1067433A/en
not_active
Expired
Cited By (1)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
GB2247685A
(en)
*
1990-09-05
1992-03-11
Johnson Matthey Plc
Improvements in cross-linked polymers
Also Published As
Publication number
Publication date
US3125480A
(en)
1964-03-17
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