GB1094994A – Physically stable alumino-silicate zeolite catalysts
– Google Patents
GB1094994A – Physically stable alumino-silicate zeolite catalysts
– Google Patents
Physically stable alumino-silicate zeolite catalysts
Info
Publication number
GB1094994A
GB1094994A
GB19160/65A
GB1916065A
GB1094994A
GB 1094994 A
GB1094994 A
GB 1094994A
GB 19160/65 A
GB19160/65 A
GB 19160/65A
GB 1916065 A
GB1916065 A
GB 1916065A
GB 1094994 A
GB1094994 A
GB 1094994A
Authority
GB
United Kingdom
Prior art keywords
physically stable
zeolite catalysts
silicate zeolite
fanjasite
calcining
Prior art date
1963-06-28
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB19160/65A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Esso Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1963-06-28
Filing date
1965-05-06
Publication date
1967-12-13
1965-05-06
Application filed by Exxon Research and Engineering Co, Esso Research and Engineering Co
filed
Critical
Exxon Research and Engineering Co
1967-12-13
Publication of GB1094994A
publication
Critical
patent/GB1094994A/en
Status
Expired
legal-status
Critical
Current
Links
Espacenet
Global Dossier
Discuss
Classifications
C—CHEMISTRY; METALLURGY
C01—INORGANIC CHEMISTRY
C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
C01B33/00—Silicon; Compounds thereof
C01B33/20—Silicates
C01B33/36—Silicates having base-exchange properties but not having molecular sieve properties
C01B33/46—Amorphous silicates, e.g. so-called «amorphous zeolites»
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
B01J20/16—Alumino-silicates
B01J20/18—Synthetic zeolitic molecular sieves
B01J20/186—Chemical treatments in view of modifying the properties of the sieve, e.g. increasing the stability or the activity, also decreasing the activity
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J29/00—Catalysts comprising molecular sieves
B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
B01J29/061—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing metallic elements added to the zeolite
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J29/00—Catalysts comprising molecular sieves
B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J29/00—Catalysts comprising molecular sieves
B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
B01J29/12—Noble metals
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J29/00—Catalysts comprising molecular sieves
B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 – B01J29/65
C—CHEMISTRY; METALLURGY
C01—INORGANIC CHEMISTRY
C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
C01B33/00—Silicon; Compounds thereof
C01B33/06—Metal silicides
Abstract
An aluminosilicate zeolite is stabilized by calcining at 350-1200 DEG F. in air or an inert gas, e.g. H2 or He, containing >10-50% water. The zeolite may be natural, e.g. fanjasite or mordenite, or synthetic, of formula 0.7-1.1 M2/nO.Al2O3.2.2-14 SiO2, where M is alkali metal; NH4, CO, Ni, Zn, Mg, Ca, Cd, Cu, or Ba (obtained by ion-exchange of the Na form); or H (obtained by calcining the NH4 form). It may, after the calcination, be impregnated with a Pt group metal, e.g. Pd; Co, Fe, Ni, Cu, Ag, Au, Mo, W, V, Zr, Ca, Mg, Hg, Pb or a rare earth metal, or compound thereof. The preparation of 13<\>rA fanjasite from NaOG, Na aluminate, and SiO2 sol is described (Example 1) which was exchanged with a solution of NH4Cl and NH4(OH) (Example 2), dried, and calcined for 16 hours at 650 DEG F. and 2 hours at 950 DEG F. in air containing 16% water (Example 4).
GB19160/65A
1963-06-28
1965-05-06
Physically stable alumino-silicate zeolite catalysts
Expired
GB1094994A
(en)
Applications Claiming Priority (2)
Application Number
Priority Date
Filing Date
Title
US29129963A
1963-06-28
1963-06-28
US420135A
US3392124A
(en)
1963-06-28
1964-12-21
Physically stable alumino-silicate zeolite catalysts
Publications (1)
Publication Number
Publication Date
GB1094994A
true
GB1094994A
(en)
1967-12-13
Family
ID=26966691
Family Applications (2)
Application Number
Title
Priority Date
Filing Date
GB1050385D
Active
GB1050385A
(en)
1963-06-28
GB19160/65A
Expired
GB1094994A
(en)
1963-06-28
1965-05-06
Physically stable alumino-silicate zeolite catalysts
Family Applications Before (1)
Application Number
Title
Priority Date
Filing Date
GB1050385D
Active
GB1050385A
(en)
1963-06-28
Country Status (7)
Country
Link
US
(1)
US3392124A
(en)
JP
(1)
JPS4927040B1
(en)
BE
(1)
BE670036A
(en)
CH
(2)
CH460729A
(en)
DE
(2)
DE1294353B
(en)
GB
(2)
GB1094994A
(en)
NL
(2)
NL6406326A
(en)
Families Citing this family (14)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
US3899441A
(en)
*
1971-08-10
1975-08-12
Union Oil Co
Rejuvenation of damaged zeolite-supported metal catalysts
US4190553A
(en)
*
1974-05-17
1980-02-26
Union Oil Company Of California
Rejuvenation of damaged zeolite-supported metal catalysts
JPS513932U
(en)
*
1974-06-26
1976-01-13
JPS51150746A
(en)
*
1975-06-20
1976-12-24
Matsushita Electric Ind Co Ltd
A conbustion equipment
JPS53129741U
(en)
*
1977-03-23
1978-10-14
US4604187A
(en)
*
1981-12-04
1986-08-05
Union Oil Company Of California
Hydrocracking with rare earth-containing Y zeolite compositions
US4565621A
(en)
*
1981-12-04
1986-01-21
Union Oil Company Of California
Hydrocracking with rare earth-containing Y zeolite compositions
US4584287A
(en)
*
1981-12-04
1986-04-22
Union Oil Company Of California
Rare earth-containing Y zeolite compositions
NZ202947A
(en)
*
1982-02-01
1985-07-31
Chevron Res
Catalytic reforming of hydrocarbons
NZ204092A
(en)
*
1982-05-18
1985-08-16
Mobil Oil Corp
A method for the preparation of acid-stabilised zeolite of the faujasite type
US4840930A
(en)
*
1982-05-18
1989-06-20
Mobil Oil Corporation
Method for preparing acid stable zeolites and high silica zeolites prepared by it
US4539305A
(en)
*
1984-03-08
1985-09-03
Chevron Research Company
Pretreatment method for enhancing the selectivity and increasing the stability of a reforming catalyst
US4608356A
(en)
*
1984-12-20
1986-08-26
Chevron Research Company
Preparation of a reforming catalyst
US4663025A
(en)
*
1986-08-14
1987-05-05
Phillips Petroleum Company
Catalytic cracking processes
Family Cites Families (5)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
US3236762A
(en)
*
1951-01-28
1966-02-22
Union Carbide Corp
Hydrocarbon conversion process with the use of a y type crystalline zeolite
US2971904A
(en)
*
1957-02-12
1961-02-14
Exxon Research Engineering Co
Petroleum process catalyst supported on a molecular sieve zeolite
US3140249A
(en)
*
1960-07-12
1964-07-07
Socony Mobil Oil Co Inc
Catalytic cracking of hydrocarbons with a crystalline zeolite catalyst composite
FR1310520A
(en)
*
1960-07-12
1962-11-30
Socony Mobil Oil Co
Composition which can be used as a catalyst in the cracking of hydrocarbon oils and process for preparing this composition
US3210265A
(en)
*
1962-02-27
1965-10-05
Socony Mobil Oil Co Inc
Hydrocracking with a crystalline zeolite and the regeneration of the catalyst with hydrogen at temperatures above 400 deg. f.
0
GB
GB1050385D
patent/GB1050385A/en
active
Active
1964
1964-05-25
DE
DEE27101A
patent/DE1294353B/en
active
Pending
1964-06-04
NL
NL6406326A
patent/NL6406326A/xx
unknown
1964-06-29
CH
CH848364A
patent/CH460729A/en
unknown
1964-12-21
US
US420135A
patent/US3392124A/en
not_active
Expired – Lifetime
1965
1965-05-06
GB
GB19160/65A
patent/GB1094994A/en
not_active
Expired
1965-05-12
DE
DE19651567475
patent/DE1567475A1/en
active
Pending
1965-06-21
NL
NL6507936A
patent/NL6507936A/xx
unknown
1965-07-14
JP
JP40042071A
patent/JPS4927040B1/ja
active
Pending
1965-09-23
BE
BE670036D
patent/BE670036A/xx
unknown
1965-12-17
CH
CH1743165A
patent/CH493426A/en
not_active
IP Right Cessation
Also Published As
Publication number
Publication date
GB1050385A
(en)
DE1294353B
(en)
1969-05-08
JPS4927040B1
(en)
1974-07-13
US3392124A
(en)
1968-07-09
NL6406326A
(en)
1965-12-06
CH493426A
(en)
1970-07-15
DE1567475A1
(en)
1970-04-16
CH460729A
(en)
1968-08-15
BE670036A
(en)
1966-03-23
NL6507936A
(en)
1966-06-22
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