GB1102639A – Novel synergistic insecticidal compositions
– Google Patents
GB1102639A – Novel synergistic insecticidal compositions
– Google Patents
Novel synergistic insecticidal compositions
Info
Publication number
GB1102639A
GB1102639A
GB39689/66A
GB3968966A
GB1102639A
GB 1102639 A
GB1102639 A
GB 1102639A
GB 39689/66 A
GB39689/66 A
GB 39689/66A
GB 3968966 A
GB3968966 A
GB 3968966A
GB 1102639 A
GB1102639 A
GB 1102639A
Authority
GB
United Kingdom
Prior art keywords
carbamate
aryl
alkyl
hydrocarbon group
aromatic hydrocarbon
Prior art date
1965-02-16
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB39689/66A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
F Hoffmann La Roche AG
Original Assignee
F Hoffmann La Roche AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1965-02-16
Filing date
1966-09-06
Publication date
1968-02-07
1966-09-06
Application filed by F Hoffmann La Roche AG
filed
Critical
F Hoffmann La Roche AG
1968-02-07
Publication of GB1102639A
publication
Critical
patent/GB1102639A/en
Status
Expired
legal-status
Critical
Current
Links
Espacenet
Global Dossier
Discuss
Classifications
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07D—HETEROCYCLIC COMPOUNDS
C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
C07D317/44—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 ortho- or peri-condensed with carbocyclic rings or ring systems
C07D317/46—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 ortho- or peri-condensed with carbocyclic rings or ring systems condensed with one six-membered ring
C07D317/48—Methylenedioxybenzenes or hydrogenated methylenedioxybenzenes, unsubstituted on the hetero ring
C07D317/62—Methylenedioxybenzenes or hydrogenated methylenedioxybenzenes, unsubstituted on the hetero ring with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to atoms of the carbocyclic ring
C07D317/64—Oxygen atoms
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
Abstract
Propargyl aryl ethers and thioethers of the formula (1) ARYL-Y-CH2-CC-[H or X] wherein Aryl represents an unsubstituted aromatic hydrocarbon group or an aromatic hydrocarbon group which carries one or more halo, C1- 7 alkyl, C1- 7 alkoxy, methylenedioxy, aryl, aryloxy, aralkyl, aralkoxy, nitro, cyano, carboxyl, carboalkoxy, acylamino and/or N,N-di-(C1- 7 alkyl) amido substituents, Y represents an O or S atom, and X represents a halogen atom, are prepared by condensing the appropriate aromatic alcohol or thiol with a halopropyne to form the terminal acetylenic compounds, and where the terminal halo compounds are desired, subsequently halogenating the terminal acetylenic carbon atom.ALSO:Synergistic insecticidal compositions comprise an insecticidal carbamate and a propargyl aryl ether or thioether of the formula ARYL-Y-CH2-CC-[H or X] wherein Aryl represents an unsubstituted aromatic hydrocarbon group or an aromatic hydrocarbon group which carries one or more halo, C1-7 alkyl, C1-7 alkoxy, methylenedioxy, aryl, aryloxy, aralkyl, aralkoxy, nitro, cyano, carboxyl, carboalkoxy, acylamino and/or N, N-di (C1-7 alkyl)-amido substituents, Y represents an O or S atom, and X represents a halogen atom. The insecticidal carbamate may be an unsubstituted or substituted phenyl carbamate, a phenyl N-alkyl or N,N-dialkyl carbamate, an alkyl phenyl N-methyl carbamate, an unsubstituted or substituted naphthyl carbamate, an indanyl carbamate, a pyrazolyl carbamate or a dithiolane-oximino carbamate, numerous examples being specified. The compositions may be formulated as concentrates, granules, or with carriers as sprays, aerosols, or dusts, and may include other known insecticides such as pyrethrins.
GB39689/66A
1965-02-16
1966-09-06
Novel synergistic insecticidal compositions
Expired
GB1102639A
(en)
Applications Claiming Priority (11)
Application Number
Priority Date
Filing Date
Title
US43320965A
1965-02-16
1965-02-16
US48590465A
1965-09-08
1965-09-08
US48590865A
1965-09-08
1965-09-08
US48595165A
1965-09-08
1965-09-08
US48594765A
1965-09-08
1965-09-08
US48593465A
1965-09-08
1965-09-08
US48591165A
1965-09-08
1965-09-08
US48592265A
1965-09-08
1965-09-08
US486545A
US3362871A
(en)
1965-02-16
1965-09-10
Novel insecticidal carbamate-propar-gylaryl ether compositions
US53137166A
1966-03-03
1966-03-03
DEH0060346
1966-08-26
Publications (1)
Publication Number
Publication Date
GB1102639A
true
GB1102639A
(en)
1968-02-07
Family
ID=27581505
Family Applications (3)
Application Number
Title
Priority Date
Filing Date
GB6018/66A
Expired
GB1069350A
(en)
1965-02-16
1966-02-11
Propynyl ethers and a process for the manufacture thereof
GB39689/66A
Expired
GB1102639A
(en)
1965-02-16
1966-09-06
Novel synergistic insecticidal compositions
GB8393/67A
Expired
GB1105848A
(en)
1965-02-16
1967-02-22
Novel propynyl ethers and a process for the manufacture thereof
Family Applications Before (1)
Application Number
Title
Priority Date
Filing Date
GB6018/66A
Expired
GB1069350A
(en)
1965-02-16
1966-02-11
Propynyl ethers and a process for the manufacture thereof
Family Applications After (1)
Application Number
Title
Priority Date
Filing Date
GB8393/67A
Expired
GB1105848A
(en)
1965-02-16
1967-02-22
Novel propynyl ethers and a process for the manufacture thereof
Country Status (17)
Country
Link
US
(3)
US3489805A
(en)
AT
(1)
AT276852B
(en)
BE
(4)
BE676476A
(en)
BR
(2)
BR6677162D0
(en)
CH
(2)
CH464600A
(en)
DE
(3)
DE1568744A1
(en)
DK
(3)
DK123165B
(en)
ES
(1)
ES337469A1
(en)
FI
(2)
FI45951C
(en)
FR
(4)
FR5407M
(en)
GB
(3)
GB1069350A
(en)
IL
(2)
IL25076A
(en)
IT
(3)
IT1053658B
(en)
MY
(2)
MY6800052A
(en)
NL
(5)
NL6601926A
(en)
NO
(2)
NO118909B
(en)
SE
(2)
SE346985B
(en)
Cited By (2)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
US4153731A
(en)
1973-04-18
1979-05-08
Ciba-Geigy Corporation
Phenoxy (benzyloxy/benzylthio) benzene derivatives
US4997989A
(en)
*
1988-01-08
1991-03-05
Basf Aktiengesellschaft
Tert-butylalkynols
Families Citing this family (12)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
US3524915A
(en)
*
1968-09-16
1970-08-18
Hoffmann La Roche
Synergistic insecticidal carbamates with 3,4 – methylenedioxyphenyl-3- halo-2-propynyl ethers
BE758735A
(en)
*
1969-11-14
1971-05-10
Hoffmann La Roche
ACETYLENIC COMPOUNDS
US3946040A
(en)
*
1971-03-19
1976-03-23
Hoffmann-La Roche Inc.
Propynyl benzyl ethers
US3880999A
(en)
*
1971-07-20
1975-04-29
Douglas J Hennessy
Synergistic insecticidal compositions containing benzyl 2-propynyl ethers
US3879421A
(en)
*
1972-01-17
1975-04-22
Stauffer Chemical Co
Certain methylenedioxyphenyl propynes
US4141921A
(en)
1972-02-09
1979-02-27
Ciba-Geigy Corporation
Phenoxyphenyl- and phenoxybenzyl-alkynyl ethers
US4020111A
(en)
*
1973-09-13
1977-04-26
Hennessy Douglas J
Propynyloxy alkyl arene insecticides
IT1059127B
(en)
*
1976-04-15
1982-05-31
Montedison Spa
BENZYL ETHERS AND THIOETERS OR LINEAR ALIPHATIC CHAIN PHENES WITH HALOGEN TERMINAL WITH ACTIVATED TA HORMONIC YOUTH AND ACARIC / DA
US4191773A
(en)
*
1977-11-25
1980-03-04
Hoffmann-La Roche Inc.
Synergistic insecticidal composition
JPH0749379B2
(en)
*
1985-12-27
1995-05-31
住友化学工業株式会社
Substituted benzene derivative and agricultural and horticultural fungicide containing the same as active ingredient
EP2289889A1
(en)
*
2009-08-18
2011-03-02
Endura S.p.a.
Substituted alkynyl phenoxy compounds and their uses
EP3141115A1
(en)
2015-09-09
2017-03-15
Endura S.p.a.
Substituted methylenedioxybenzyl compounds and their uses as synergists
Family Cites Families (4)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
US2942014A
(en)
*
1955-12-07
1960-06-21
Monsanto Chemicals
Oxidative coupling process
US2993934A
(en)
*
1956-08-08
1961-07-25
Diamond Alkali Co
Derivatives of pentachlorophenol
US3009855A
(en)
*
1958-08-07
1961-11-21
Union Carbide Corp
Method and composition of destroying insects employing 1-naphthyl n-methyl carbamate
US3322813A
(en)
*
1962-06-30
1967-05-30
Meiji Seika Kaisha
Halopropargyl aryl ether compounds
1965
1965-09-08
US
US485904A
patent/US3489805A/en
not_active
Expired – Lifetime
1965-09-10
US
US486545A
patent/US3362871A/en
not_active
Expired – Lifetime
1966
1966-01-27
CH
CH1146567A
patent/CH464600A/en
unknown
1966-01-29
DE
DE19661568744
patent/DE1568744A1/en
active
Pending
1966-01-31
IL
IL25076A
patent/IL25076A/en
unknown
1966-02-11
GB
GB6018/66A
patent/GB1069350A/en
not_active
Expired
1966-02-14
FR
FR49431A
patent/FR5407M/fr
not_active
Expired
1966-02-15
NO
NO161707A
patent/NO118909B/no
unknown
1966-02-15
NL
NL6601926A
patent/NL6601926A/xx
unknown
1966-02-15
BE
BE676476D
patent/BE676476A/xx
unknown
1966-02-16
BR
BR177162/66A
patent/BR6677162D0/en
unknown
1966-02-16
IT
IT3414/66A
patent/IT1053658B/en
active
1966-02-16
SE
SE02009/66A
patent/SE346985B/xx
unknown
1966-02-16
DK
DK81166AA
patent/DK123165B/en
unknown
1966-02-16
FI
FI660383A
patent/FI45951C/en
active
1966-03-03
US
US531371A
patent/US3423428A/en
not_active
Expired – Lifetime
1966-08-23
DE
DE19661568780
patent/DE1568780A1/en
active
Pending
1966-08-24
CH
CH1223566A
patent/CH477815A/en
not_active
IP Right Cessation
1966-08-26
AT
AT809466A
patent/AT276852B/en
not_active
IP Right Cessation
1966-08-26
DE
DE19661542909
patent/DE1542909A1/en
active
Pending
1966-08-29
FR
FR74427A
patent/FR5694M/fr
not_active
Expired
1966-08-29
IL
IL26400A
patent/IL26400A/en
unknown
1966-09-01
BR
BR182528/66A
patent/BR6682528D0/en
unknown
1966-09-02
FR
FR75009A
patent/FR1510861A/en
not_active
Expired
1966-09-05
BE
BE686415D
patent/BE686415A/xx
unknown
1966-09-05
BE
BE686416D
patent/BE686416A/xx
unknown
1966-09-06
GB
GB39689/66A
patent/GB1102639A/en
not_active
Expired
1966-09-07
NO
NO66164608A
patent/NO116567B/no
unknown
1966-09-08
IT
IT20649/66A
patent/IT947002B/en
active
1966-09-08
NL
NL6612646A
patent/NL6612646A/xx
unknown
1966-09-08
SE
SE12097/66A
patent/SE360002B/xx
unknown
1966-09-08
NL
NL6612645A
patent/NL6612645A/xx
unknown
1966-09-08
NL
NL6612647A
patent/NL6612647A/xx
unknown
1966-09-08
FI
FI2343/66A
patent/FI43797B/fi
active
1966-09-08
DK
DK462366AA
patent/DK116481B/en
unknown
1966-09-08
IT
IT20643/66A
patent/IT986752B/en
active
1967
1967-02-13
NL
NL6702139A
patent/NL6702139A/xx
unknown
1967-02-22
GB
GB8393/67A
patent/GB1105848A/en
not_active
Expired
1967-02-28
BE
BE694744D
patent/BE694744A/xx
unknown
1967-03-01
FR
FR96924A
patent/FR1512869A/en
not_active
Expired
1967-03-02
ES
ES337469A
patent/ES337469A1/en
not_active
Expired
1968
1968-12-31
MY
MY196852A
patent/MY6800052A/en
unknown
1969
1969-06-06
DK
DK306369AA
patent/DK125239B/en
unknown
1969-12-31
MY
MY196968A
patent/MY6900068A/en
unknown
Cited By (2)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
US4153731A
(en)
1973-04-18
1979-05-08
Ciba-Geigy Corporation
Phenoxy (benzyloxy/benzylthio) benzene derivatives
US4997989A
(en)
*
1988-01-08
1991-03-05
Basf Aktiengesellschaft
Tert-butylalkynols
Also Published As
Publication number
Publication date
AT276852B
(en)
1969-12-10
NL6612646A
(en)
1967-03-09
GB1105848A
(en)
1968-03-13
IL26400A
(en)
1970-10-30
BR6682528D0
(en)
1973-03-08
FI45951B
(en)
1972-07-31
FR5694M
(en)
1968-01-08
SE346985B
(en)
1972-07-24
NL6601926A
(en)
1966-08-17
IT947002B
(en)
1973-05-21
BE676476A
(en)
1966-08-16
US3423428A
(en)
1969-01-21
DE1568780A1
(en)
1970-04-02
MY6900068A
(en)
1969-12-31
US3489805A
(en)
1970-01-13
NO118909B
(en)
1970-03-02
SE360002B
(en)
1973-09-17
CH1146567A4
(en)
1968-07-15
NO116567B
(en)
1969-04-14
DK125239B
(en)
1973-01-22
FI45951C
(en)
1972-11-10
CH464600A
(en)
1968-12-13
US3362871A
(en)
1968-01-09
FI43797B
(en)
1971-03-01
BE694744A
(en)
1967-08-28
NL6612647A
(en)
1967-03-09
ES337469A1
(en)
1968-03-01
IT986752B
(en)
1975-01-30
IT1053658B
(en)
1981-10-10
DK123165B
(en)
1972-05-23
DK116481B
(en)
1970-01-12
MY6800052A
(en)
1968-12-31
GB1069350A
(en)
1967-05-17
CH477815A
(en)
1969-09-15
BE686415A
(en)
1967-03-06
BE686416A
(en)
1967-03-06
BR6677162D0
(en)
1973-09-06
DE1568744A1
(en)
1970-04-16
NL6612645A
(en)
1967-03-09
FR1510861A
(en)
1968-01-26
NL6702139A
(en)
1967-09-04
DE1542909A1
(en)
1970-04-16
FR1512869A
(en)
1968-02-09
IL25076A
(en)
1969-11-30
FR5407M
(en)
1967-09-25
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