GB1104939A

GB1104939A – Improvements in and relating to the treatment of pigments
– Google Patents

GB1104939A – Improvements in and relating to the treatment of pigments
– Google Patents
Improvements in and relating to the treatment of pigments

Info

Publication number
GB1104939A

GB1104939A
GB24143/64A
GB2414364A
GB1104939A
GB 1104939 A
GB1104939 A
GB 1104939A
GB 24143/64 A
GB24143/64 A
GB 24143/64A
GB 2414364 A
GB2414364 A
GB 2414364A
GB 1104939 A
GB1104939 A
GB 1104939A
Authority
GB
United Kingdom
Prior art keywords
group
particles
pigment
ring
coxco
Prior art date
1964-06-10
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired

Application number
GB24143/64A
Inventor
Raoul Feld
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Laporte Titanium Ltd

Original Assignee
Laporte Titanium Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1964-06-10
Filing date
1964-06-10
Publication date
1968-03-06

1964-06-10
Application filed by Laporte Titanium Ltd
filed
Critical
Laporte Titanium Ltd

1964-06-10
Priority to GB24143/64A
priority
Critical
patent/GB1104939A/en

1965-06-04
Priority to DE1965L0050858
priority
patent/DE1467461A1/en

1965-06-08
Priority to US462439A
priority
patent/US3453130A/en

1965-06-09
Priority to BE665167D
priority
patent/BE665167A/xx

1965-06-10
Priority to NL6507432A
priority
patent/NL6507432A/xx

1965-06-10
Priority to FR20202A
priority
patent/FR1437065A/en

1968-03-06
Publication of GB1104939A
publication
Critical
patent/GB1104939A/en

Status
Expired
legal-status
Critical
Current

Links

Espacenet

Global Dossier

Discuss

Classifications

C—CHEMISTRY; METALLURGY

C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR

C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS

C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties

C09C3/08—Treatment with low-molecular-weight non-polymer organic compounds

C—CHEMISTRY; METALLURGY

C01—INORGANIC CHEMISTRY

C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS

C01P2006/00—Physical properties of inorganic compounds

C01P2006/60—Optical properties, e.g. expressed in CIELAB-values

Abstract

Particles of a pigment to be used in a paint or lacquer (e.g TiO2, SiO2, blanc fixe, lithopone, BaCO3, ZrO2, ZnO, Al2O3, chrome yellow or phthalocyanine) are treated by contacting them with 0.01-5% by wt. (based on the wt. of the particles) of a dicarbonyl compound of formula R1COXCOR2 wherein R1, R2 may be the same o different and may be a substituted or unsubstituted alkyl, alkoxy, aryl, aryloxy, aralkyl or aralkoxy group or R1, R2 may form a ring with the -COXCO- group, and wherein X is the -CH2-, -NH-, or -CHR3- group wherein R3 may be an alkyl, aralkyl or aryl group or, when R1, R2 do not form a ring with the -COXCO- group, R3 and R1 may complete a ring therewith, and drying the particles. The dicarbonyl compound, which may be acetylacetone, benzoylacetone, dibenzoylmethane, ethylacetoacetate, diethylmalonate, phthalimide, succinimide, methylacetylacetone or 2-acetylcyclohexanone, may be dissolved in an alcohol, acetone or water, or if liquid, may be dispersed in another liquid. The paint or lacquer may be made by incorporation of the pigment in, for examle, air-drying or stoving acrylic or alkyd media. In the examples, the pigment was mixed with an oil paint medium consisting of a linseed oil pentaerythritol modified alkyd resin, soya lecithin oil and white spirit in wt. proportions 100:20:570 respectively.ALSO:Particles of a pigment to be used in a paint or lacquer (e.g TiO2, SiO2, blanc fixe, lithopone, BaCO3, ZrO2, ZnO, Al2O3, chrome yellow or phthalocyanine) are treated by contacting them with 0.01-5% by wt. (based on the wt. of the particles) of a dicarbonyl compound of formula R1COXCOR2, wherein R1, R2 may be the same or different, and may be a substituted or unsubstituted alkyl, alkoxy, aryl, aryloxy, aralkyl or aralkoxy group or R1, R2 may form a ring with the -COXCO- group, and wherein X is the -CH2-, -NH-, or -CHR3- group, wherein R3 may be an alkyl, aralkyl or aryl group or when R1, R2 do not form a ring with the -COXCO- group, R3 and R1 may complete a ring therewith, and drying the treated particles. The dicarbonyl compound, which may be e.g. acetylacetone, benzoylacetone, dibenzoyl methane, ethyl acetoacetate, diethyl malonate, phthalimide, succinimide, methyl-acetylacetone or 2-acetylcyclohexanone, may be dissolved in an alcohol, acetone or water, or if liquid may be dipersed in another liquid. The pigment particles may be mixed with water before treatment to form a slurry, pulp or paste and may be dried thereafter by heating, e.g. at 120 DEG C. Such treatment gives improved gloss and/or hiding power in the paint or lacquer, which may be made by incorporation of the pigment in, for example, air-drying or stoving acrylic or alkyd media.ALSO:Particles of a pigment (e.g. TiO2, SiO2, blanc fixe, lithopone, BaCO3, ZrO2, ZnO, Al2O3, chrome yellow or phthalocyanine) are treated by contacting them with 0.01-5% (preferably 0.1-1.5%) by wt., based on the wt. of the particles) of a dicarbonyl compound of formula R1COXCOR2 in which R1, R2, which may be th same or different, each is a substituted or unsubstituted alkyl, alkoxy, aryl, aryloxy, aralkyl or aralkoxy group or in which R1 and R2 form a ring system with the group-COXCO-, and in which X is the -CH2-, -NH-, or -CHR3-group, wherein R3 is an alkyl, aralkyl or aryl group or, when R1 and R2 do not form a ring system with the group -COXCO-,R3 and R1 together complete a ring system, and drying the treated particles. The dicarbonyl compound may be, for example, acetylacetone, benzoyl-acetone, dibenzoyl methane, ethyl acetoacetate, diethyl malonate, phthalimide, succinimide, methyl acetylacetone or 2-acetyl cyclohexanone. The dicarbonyl compound may be dissolved in an alcohol, acetone or water or if a liquid may be dispersed in another liquid. The pigment particles may be mixed with water before treatment to form a slurry, pulp or paste and may be dried after treatment by heating, e.g. at 120 DEG C. The pigment may be used in a paint or lacquer.

GB24143/64A
1964-06-10
1964-06-10
Improvements in and relating to the treatment of pigments

Expired

GB1104939A
(en)

Priority Applications (6)

Application Number
Priority Date
Filing Date
Title

GB24143/64A

GB1104939A
(en)

1964-06-10
1964-06-10
Improvements in and relating to the treatment of pigments

DE1965L0050858

DE1467461A1
(en)

1964-06-10
1965-06-04

Method of treating a pigment

US462439A

US3453130A
(en)

1964-06-10
1965-06-08
Inorganic pigments

BE665167D

BE665167A
(en)

1964-06-10
1965-06-09

NL6507432A

NL6507432A
(en)

1964-06-10
1965-06-10

FR20202A

FR1437065A
(en)

1964-06-10
1965-06-10

Improvements in pigment processing

Applications Claiming Priority (1)

Application Number
Priority Date
Filing Date
Title

GB24143/64A

GB1104939A
(en)

1964-06-10
1964-06-10
Improvements in and relating to the treatment of pigments

Publications (1)

Publication Number
Publication Date

GB1104939A
true

GB1104939A
(en)

1968-03-06

Family
ID=10207077
Family Applications (1)

Application Number
Title
Priority Date
Filing Date

GB24143/64A
Expired

GB1104939A
(en)

1964-06-10
1964-06-10
Improvements in and relating to the treatment of pigments

Country Status (6)

Country
Link

US
(1)

US3453130A
(en)

BE
(1)

BE665167A
(en)

DE
(1)

DE1467461A1
(en)

FR
(1)

FR1437065A
(en)

GB
(1)

GB1104939A
(en)

NL
(1)

NL6507432A
(en)

Cited By (5)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

US5849074A
(en)

*

1996-07-19
1998-12-15
Videojet Systems International, Inc.
Method for preparing magnetic ink and dry pigment particles used therefor

US5855661A
(en)

*

1995-10-03
1999-01-05
Videojet Systems International, Inc.
Pigment dispersion

US5922121A
(en)

*

1995-10-03
1999-07-13
Videojet Systems International, Inc.
Hydrophobic treatment of pigments

US6179907B1
(en)

1998-05-29
2001-01-30
Marconi Data Systems Inc.
Black iron oxide with improved heat stability and method of preparing same

US6235829B1
(en)

1998-07-24
2001-05-22
Marconi Data Systems Inc.
Modification of chargeable pigment particles

Families Citing this family (8)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

US3549396A
(en)

*

1969-08-13
1970-12-22
Ppg Industries Inc
Method for producing pigments of improved dispersibility

US3650792A
(en)

*

1970-08-07
1972-03-21
Ppg Industries Inc
Method for producing pigments of improved dispersibility

GB1327833A
(en)

*

1971-04-28
1973-08-22
British Titan Ltd
Pigments

EP0232219A1
(en)

*

1986-01-21
1987-08-12
Ciba-Geigy Ag
Metal chromate pigments treated with esters

EP0350035B1
(en)

*

1988-07-06
1995-04-05
OSi Specialties, Inc.
Method of forming stable dispersions of particulate matter

DE10053119A1
(en)

*

2000-10-26
2002-05-08
Clariant Gmbh

Phthalimides as synergists to improve the properties of aqueous pigment preparations

WO2013159098A1
(en)

2012-04-20
2013-10-24
Valspar Sourcing, Inc.
Method for making titanium dioxide pigment grind dispersion and paint

US9284467B2
(en)

2012-04-20
2016-03-15
Valspar Sourcing, Inc.
Titanium dioxide pigment grind dispersion and paint

Family Cites Families (3)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

US2313621A
(en)

*

1939-06-14
1943-03-09
Rohm & Haas
Capillary-active composition

US2226147A
(en)

*

1940-01-23
1940-12-24
Du Pont
Pigment substance and process for producing the same

US3198647A
(en)

*

1961-04-19
1965-08-03
Quaker Chem Corp
Treated pigments and process for modifying the surface of pigments

1964

1964-06-10
GB
GB24143/64A
patent/GB1104939A/en
not_active
Expired

1965

1965-06-04
DE
DE1965L0050858
patent/DE1467461A1/en
active
Pending

1965-06-08
US
US462439A
patent/US3453130A/en
not_active
Expired – Lifetime

1965-06-09
BE
BE665167D
patent/BE665167A/xx
unknown

1965-06-10
FR
FR20202A
patent/FR1437065A/en
not_active
Expired

1965-06-10
NL
NL6507432A
patent/NL6507432A/xx
unknown

Cited By (5)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

US5855661A
(en)

*

1995-10-03
1999-01-05
Videojet Systems International, Inc.
Pigment dispersion

US5922121A
(en)

*

1995-10-03
1999-07-13
Videojet Systems International, Inc.
Hydrophobic treatment of pigments

US5849074A
(en)

*

1996-07-19
1998-12-15
Videojet Systems International, Inc.
Method for preparing magnetic ink and dry pigment particles used therefor

US6179907B1
(en)

1998-05-29
2001-01-30
Marconi Data Systems Inc.
Black iron oxide with improved heat stability and method of preparing same

US6235829B1
(en)

1998-07-24
2001-05-22
Marconi Data Systems Inc.
Modification of chargeable pigment particles

Also Published As

Publication number
Publication date

FR1437065A
(en)

1966-04-29

NL6507432A
(en)

1965-12-13

US3453130A
(en)

1969-07-01

DE1467461A1
(en)

1968-11-28

BE665167A
(en)

1965-10-01

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