GB1111964A

GB1111964A – A composition and method for coating and surfacing papers
– Google Patents

GB1111964A – A composition and method for coating and surfacing papers
– Google Patents
A composition and method for coating and surfacing papers

Info

Publication number
GB1111964A

GB1111964A
GB20055/65A
GB2005565A
GB1111964A
GB 1111964 A
GB1111964 A
GB 1111964A
GB 20055/65 A
GB20055/65 A
GB 20055/65A
GB 2005565 A
GB2005565 A
GB 2005565A
GB 1111964 A
GB1111964 A
GB 1111964A
Authority
GB
United Kingdom
Prior art keywords
copolymer
glyoxal
water
latex
mixed
Prior art date
1964-05-13
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired

Application number
GB20055/65A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Nobel Bozel SA

Original Assignee
Nobel Bozel SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1964-05-13
Filing date
1965-05-12
Publication date
1968-05-01

1965-05-12
Application filed by Nobel Bozel SA
filed
Critical
Nobel Bozel SA

1968-05-01
Publication of GB1111964A
publication
Critical
patent/GB1111964A/en

Status
Expired
legal-status
Critical
Current

Links

Espacenet

Global Dossier

Discuss

Classifications

D—TEXTILES; PAPER

D21—PAPER-MAKING; PRODUCTION OF CELLULOSE

D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR

D21H19/00—Coated paper; Coating material

D21H19/36—Coatings with pigments

D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent

D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds

D21H19/58—Polymers or oligomers of diolefins, aromatic vinyl monomers or unsaturated acids or derivatives thereof

D—TEXTILES; PAPER

D21—PAPER-MAKING; PRODUCTION OF CELLULOSE

D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR

D21H19/00—Coated paper; Coating material

D21H19/36—Coatings with pigments

D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent

D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds

D21H19/60—Polyalkenylalcohols; Polyalkenylethers; Polyalkenylesters

Abstract

A composition for coating or surfacing paper comprises a synthetic latex of a copolymer of a vinyl ester and an acrylic ester, an acrylic copolymer or homopolymer or a styrenebutadiene copolymer and glyoxal. It may also contain a starch or casein adhesive and a filler. In the Examples: (1) potato starch is degraded by an enzymatic process, kaolin is mixed with hexametaphosphate and water and then with the degraded starch and the dispersion divided into portions, to some portions is added a latex of a copolymer of vinyl acetate, 2-ethylhexyl acrylate and acrylic acid plasticized by dibutyl phthalate, to others glyoxal and to others both latex and glyoxal in various proportions; (2) kaolin, sodium hexametaphosphate, oxidized starch and water are mixed, various quantities of glyoxal, the latex of Example 1 or a similar atex containing no acrylic acid, and a protective colloid, are added; (3) clay, sodium hexametaphosphate, oxidized starch, polyvinyl alcohol and water are mixed and divided into portions, to these are added various amounts of glyoxal and a styrene-butadiene latex; (4) chalk, enzyme-converted starch, water-dispersible pigment and water are mixed, to the mixture are added various proportions of glyoxal and a copolymer of vinyl acetate and ethyl acrylate plasticized by hexylene glycols; (5) talc, kaolin, carboxymethylcellulose, sodium hexametaphosphate, water-dispersible pigment and water are mixed and to the mixture are added various quantities of glyoxal, and the copolymer of Example 4 or a copolymer of ethyl acrylate, methyl methacrylate and acrylic acid; (6) water, starch, oxalic acid and glyoxal are mixed and heated at 90 DEG C. to gel it, when it is neutralized with calcium carbonate, this material is mixed with fine chalk and water and then with the copolymer of Example 4 and glyoxal; (7) a composition comprises the copolymer of Example 2, a latex of a copolymer of ethyl acrylate, butyl acrylate and methyl methacrylate, glyoxal and water.ALSO:Paper is coated with a composition comprising a synthetic latex, glyoxal and optionally a starch or casein adhesive and a filler. The synthetic latex is of a copolymer of a vinyl ester and an acrylic ester, an acrylic copolymer or homopolymer or a styrene-butadiene copolymer. In the Examples: (1) potato starch is degraded by an enzymatic process, kaolin is mixed with hexametaphosphate and coated and then with the degraded starch and the dispersion divided into portions, to some parts is added a latex of a copolymer of vinyl acetate, 2-ethylhexyl acrylate and acrylic acid plasticized by dibutyl phthalate, to others glyoxal and to others both latex and glyoxal in various proportions, the resulting compositions are coated on to paper (2) kaolin, sodium hexametaphosphate oxidized starch and water are mixed, various quantities of glyoxal, the latex of example 1 and a similar latex containing no acrylic acid, but a protective colloid, are added and the compositions coated on to paper; (3) clay, sodium hexametaphosphate, oxidized starch, polyvinyl alcohol and water are mixed and divided into portions, to these are added various amounts of glyoxal and a styrene-butadiene latex, the compositions are coated on to paper; (4) chalk, enzyme-converted starch, water-dispersible pigments and water are mixed to the mixture are added various proportions of glyoxal and a copolymer of vinyl acetate and ethyl acrylate plasticized by hexylene glycol; these compositions are coated on to paper; (5) talc, kaolin, carboxymethylcellulose, sodium hexametaphosphate, water-dispersible pigment and water are mixed and to the mixture are added various quantities of glyoxal, the copolymer of Example 4 and a copolymer of ethyl acrylate, methyl methacrylate and acrylic acid; (7) wall-paper is coated with a composition comprising the copolymer of Example 2, a latex of a copolymer of ethyl acrylate, butyl acrylate and methyl methacrylate, glyoxal and water.ALSO:Paper is surface-sized with a composition comprising a synthetic latex, glyoxal and optionally a starch or casein adhesive and a filler. The synthetic latex is of a copolymer of a vinyl ester and an acrylic ester, an acrylic copolymer or homopolymer or a styrenebutadiene copolymer. In the Examples: (5) talc, kaolin, carboxymethylcellulose, sodium hexametaphosphate, water-dispersible pigment and water are mixed and to the mixture are added various quantities of glyoxal, a copolymer of vinyl acetate and ethyl acrylate and a copolymer of ethyl acrylate, methyl metacrylate and acrylic acid; (6) water, starch, oxalic acid and glyoxal are mixed and heated at 90 DEG C to gel it, when it is neutralised with calcium carbonate, this material is mixed with fine chalk and water and then with a copolymer of vinyl acetate and ethyl acrylate, and with glyoxal, this composition is used in the manufacture of wallpaper; (8) and (9) thin unsized papers and commercial grades of paper are treated with glyoxal alone, the latex of a copolymer of ethyl acrylate, methyl methyacrylate and acrylic acid alone or various mixtures of the two, in a size press. The product may be used for offset printing, decorative wallpaper, serviettes or handkerchiefs.

GB20055/65A
1964-05-13
1965-05-12
A composition and method for coating and surfacing papers

Expired

GB1111964A
(en)

Applications Claiming Priority (1)

Application Number
Priority Date
Filing Date
Title

FR974389A

FR1409758A
(en)

1964-05-13
1964-05-13

Compositions improving the resistance to wet friction of coated papers and papers obtained

Publications (1)

Publication Number
Publication Date

GB1111964A
true

GB1111964A
(en)

1968-05-01

Family
ID=8829964
Family Applications (1)

Application Number
Title
Priority Date
Filing Date

GB20055/65A
Expired

GB1111964A
(en)

1964-05-13
1965-05-12
A composition and method for coating and surfacing papers

Country Status (8)

Country
Link

US
(1)

US3395072A
(en)

BE
(1)

BE662811A
(en)

DE
(1)

DE1546415A1
(en)

ES
(1)

ES312840A1
(en)

FR
(1)

FR1409758A
(en)

GB
(1)

GB1111964A
(en)

LU
(1)

LU48466A1
(en)

NL
(1)

NL6506097A
(en)

Cited By (2)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

GB2170210A
(en)

*

1985-01-30
1986-07-30
Warner Lambert Co
Coating composition for dosage forms

EP0261878A2
(en)

*

1986-09-22
1988-03-30
Sequa Chemicals Inc.
Coating binder additive

Families Citing this family (8)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

US3442685A
(en)

*

1967-03-07
1969-05-06
West Virginia Pulp & Paper Co
Preparation of coated paper having high gloss and high wet rub resistance

US3884853A
(en)

*

1973-11-14
1975-05-20
Staley Mfg Co A E
Alkali-curable cationic/anionic starch for paper coating binders

US4109056A
(en)

*

1975-05-05
1978-08-22
Champion International Corporation
Starch/latex cast coatings for paper

US4160750A
(en)

*

1977-02-22
1979-07-10
Borden, Inc.
Aqueous acrylic contact cement

GB8806497D0
(en)

*

1988-03-18
1988-04-20
Mortile Acoustic Ind Ltd
Non-toxic fire retardant thermoplastic material

EP1203120A1
(en)

*

1999-06-11
2002-05-08
Unidur GmbH
Composition for the impregnation of paper, method for the production thereof, impregnated paper and laminate comprising said impregnated paper

PT2627821T
(en)

*

2010-10-15
2018-08-03
Univ Maine System
Filler composition and method of producing composite materials

CN110485193B
(en)

*

2019-06-20
2021-08-27
浙江夏王纸业有限公司
Production process of pre-impregnated paper

Family Cites Families (7)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

CA492815A
(en)

*

1953-05-12
G. Kunze Walter
Polyvinyl acetate emulsion capable of depositing water-resistant films and bonds

US2622960A
(en)

*

1948-03-16
1952-12-23
A P W Products Company Inc
Glyoxal treatment of absorbent paper to improve wet strength

US2616818A
(en)

*

1948-11-18
1952-11-04
Hercules Powder Co Ltd
Paper coating

US3028340A
(en)

*

1956-12-28
1962-04-03
Nobel Bozel
Production of new compositions from glyoxal and alkali metal silicates

GB878114A
(en)

*

1958-11-17
1961-09-27
Shawinigan Resins Corp
Improvements in and relating to polyvinyl ester emulsions

US3256221A
(en)

*

1961-06-15
1966-06-14
Monsanto Co
Powdered polyvinyl ester admixtures with glyoxal

US3266971A
(en)

*

1964-03-31
1966-08-16
Formica Corp
Acrylic latex coating composition containing amine mixtures

1964

1964-05-13
FR
FR974389A
patent/FR1409758A/en
not_active
Expired

1965

1965-04-21
BE
BE662811D
patent/BE662811A/xx
unknown

1965-04-26
LU
LU48466D
patent/LU48466A1/xx
unknown

1965-05-03
DE
DE19651546415
patent/DE1546415A1/en
active
Pending

1965-05-11
US
US454996A
patent/US3395072A/en
not_active
Expired – Lifetime

1965-05-12
GB
GB20055/65A
patent/GB1111964A/en
not_active
Expired

1965-05-12
ES
ES0312840A
patent/ES312840A1/en
not_active
Expired

1965-05-13
NL
NL6506097A
patent/NL6506097A/xx
unknown

Cited By (3)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

GB2170210A
(en)

*

1985-01-30
1986-07-30
Warner Lambert Co
Coating composition for dosage forms

EP0261878A2
(en)

*

1986-09-22
1988-03-30
Sequa Chemicals Inc.
Coating binder additive

EP0261878A3
(en)

*

1986-09-22
1989-03-15
Sequa Corporation
Coating binder additive

Also Published As

Publication number
Publication date

DE1546415A1
(en)

1970-07-23

FR1409758A
(en)

1965-09-03

BE662811A
(en)

1965-10-21

ES312840A1
(en)

1965-07-01

US3395072A
(en)

1968-07-30

LU48466A1
(en)

1965-10-26

NL6506097A
(en)

1965-11-15

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