GB1113825A

GB1113825A – Graft polymers
– Google Patents

GB1113825A – Graft polymers
– Google Patents
Graft polymers

Info

Publication number
GB1113825A

GB1113825A
GB8983/66A
GB898366A
GB1113825A
GB 1113825 A
GB1113825 A
GB 1113825A
GB 8983/66 A
GB8983/66 A
GB 8983/66A
GB 898366 A
GB898366 A
GB 898366A
GB 1113825 A
GB1113825 A
GB 1113825A
Authority
GB
United Kingdom
Prior art keywords
acid
recurring
carbon atoms
radical
monomer
Prior art date
1965-03-02
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired

Application number
GB8983/66A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Allied Corp

Original Assignee
Allied Chemical and Dye Corp
Allied Chemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1965-03-02
Filing date
1966-03-01
Publication date
1968-05-15

1966-03-01
Application filed by Allied Chemical and Dye Corp, Allied Chemical Corp
filed
Critical
Allied Chemical and Dye Corp

1968-05-15
Publication of GB1113825A
publication
Critical
patent/GB1113825A/en

Status
Expired
legal-status
Critical
Current

Links

Espacenet

Global Dossier

Discuss

Classifications

C—CHEMISTRY; METALLURGY

C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON

C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS

C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule

C—CHEMISTRY; METALLURGY

C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON

C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS

C08F8/00—Chemical modification by after-treatment

C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups

Abstract

Graft polymers have (1) a copolymeric backbone derived from (a) a major amount of at least one monomer providing one of the following recurring units: or wherein the R’s, which may be the same or different, each represent hydrogen, halogen or an alkyl radical of not more than 8 carbon atoms and in the unit of Formula 3 the two vicinal R’s may, together with the carbon atoms to which they are attached, form a cycloaliphatic ring, or a substituted said recurring unit in which the substituents are non-aromatic and inert in a polyamide grafting reaction, the said recurring or substituted recurring units containing not more than 10 carbon atoms and (b) a minor amount of at least one comonomer providing recurring alkylene units of not more than 10 carbon atoms, said alkylene units having a single pendant organic radical which contains a single monofunctional acid group or a salt or ester of such a group and (2) a plurality of polyamide grafts each attached via its terminal nitrogen atom to the acid, salt or ester group of said pendant radical and each graft having the recurring unit where R1 is a polymethylene radical of at least 5 methylene groups and X is an integer of at least 2. Monomer (a) is e.g. butene, heptene, decene, ethylene, propylene, cyclopentene, cyclohexene, butadiene, 2,3-dimethylbutadiene-1,3, tetrafluorethylene or chloroprene. Monomer (b) may be (meth)acrylic acid or an alkyl (meth)acrylate. The amino compound grafted on is e.g. a monoamino-monocarboxylic acid such as e -aminocaproic acid, 11-aminoundecanoic acid or 12-aminododecanoic acid; or esters, amides or lactams of such acids, e.g. e -caprolactam, ethyl-e -aminocaproate, e -aminocaproamide, lauryl lactam, ethyl-11-amino-undecanoate or 11-aminoundecanoamide. In the examples, graft polymers are formed from a copolymer of ethylene and ethyl acrylate or acrylic acid and e -caprolactam by a melt-polymerization process, the product being a mixture of nylon 6 and the graft copolymer, the former only being soluble in hot trifluoroethanol.

GB8983/66A
1965-03-02
1966-03-01
Graft polymers

Expired

GB1113825A
(en)

Applications Claiming Priority (1)

Application Number
Priority Date
Filing Date
Title

US436685A

US3388186A
(en)

1965-03-02
1965-03-02
Carboxy terminated graft copolymers of amino-carboxylic acids or lactams on acrylic copolymers

Publications (1)

Publication Number
Publication Date

GB1113825A
true

GB1113825A
(en)

1968-05-15

Family
ID=23733411
Family Applications (1)

Application Number
Title
Priority Date
Filing Date

GB8983/66A
Expired

GB1113825A
(en)

1965-03-02
1966-03-01
Graft polymers

Country Status (5)

Country
Link

US
(1)

US3388186A
(en)

DE
(1)

DE1595259A1
(en)

ES
(1)

ES323693A1
(en)

GB
(1)

GB1113825A
(en)

NL
(1)

NL6602669A
(en)

Families Citing this family (44)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

US3465059A
(en)

*

1966-11-28
1969-09-02
Allied Chem
Carboxy terminated graft copolymers of carbonamide group on acrylic copolymers

US3441469A
(en)

*

1967-06-07
1969-04-29
Continental Can Co
Process for preparing polyamide/olefin polymer graft copolymer adhesive

US3539664A
(en)

*

1968-02-14
1970-11-10
Allied Chem
Homogeneous nylon graft copolymers onto ethylene copolymer backbones

US3640838A
(en)

*

1970-06-24
1972-02-08
Union Carbide Corp
Ionically interacting polymers

US3976720A
(en)

*

1974-11-13
1976-08-24
E. I. Du Pont De Nemours And Company
Polyamide/polyolefin plastic graft copolymers

US4017557A
(en)

*

1974-11-13
1977-04-12
E. I. Du Pont De Nemours And Company
Novel elastomeric graft copolymers

US3963799A
(en)

*

1974-11-13
1976-06-15
E. I. Du Pont De Nemours And Company
Graft copolymer in polyamide polyethylene blends

USRE30322E
(en)

*

1974-11-13
1980-07-01
E. I. Du Pont De Nemours And Company
Novel elastomeric graft copolymers

NL168540B
(en)

*

1975-05-23
1981-11-16
Du Pont

PROCESS FOR PREPARING A TOUGH, THERMOPLASTIC MULTI-PHASE PREPARATION.

US4217430A
(en)

*

1978-08-01
1980-08-12
E. I. Du Pont De Nemours And Company
Graft copolymer of neutralized acid copolymer trunk and polyamide oligomeric branches and method for making such copolymer

US4346024A
(en)

*

1979-12-10
1982-08-24
Rhone-Poulenc Industries
Heat-stable polyphase polyamide/polyesteramide compositions

US4387184A
(en)

*

1979-12-10
1983-06-07
Rhone-Poulenc Industries
Heat stable polyphase polyamide compositions and preparation thereof

US4299744A
(en)

*

1980-06-06
1981-11-10
American Hoechst Corporation
High impact polyamides

CA1172789A
(en)

*

1980-09-25
1984-08-14
Hideo Kasahara
POLYMERIC MATERIAL COMPRISING A POLYAMIDE BONDED TO A COPOLYMER CONTAINING AN IMIDE OF AN .alpha.,.beta. UNSATURATED CARBOXYLIC ACID

US4544702A
(en)

*

1984-06-11
1985-10-01
Uniroyal, Inc.
Modified ionic elastomer and blend with nylon

US4945129A
(en)

*

1987-08-27
1990-07-31
Allied-Signal Inc.
Polyamide compositions with high impact strength at low temperatures

US4847322A
(en)

*

1987-10-22
1989-07-11
Allied-Signal Inc.
Thermoplastic compositions containing acyllactam graft linkages

US4884814A
(en)

*

1988-01-15
1989-12-05
Spalding & Evenflo Companies, Inc.
Golf ball

US5342886A
(en)

*

1988-03-24
1994-08-30
Atochem
α-monoolefinic graft copolymers

JP2611383B2
(en)

*

1988-10-15
1997-05-21
住友化学工業株式会社

Method for producing graft copolymer

US5290865A
(en)

*

1988-10-15
1994-03-01
Sumitomo Chemical Company, Ltd.
Process for producing a lactam compound graft copolymer of ethylene copolymer

US5130372A
(en)

*

1989-12-18
1992-07-14
Allied-Signal Inc.
Ionomers of low molecular weight copolymer amides

BR9007889A
(en)

*

1989-12-18
1992-09-15
Allied Signal Inc

COPOLIMER REACTION PRODUCT AND COMPOSITION WHICH INCLUDES A PIGMENT AND THE COPOLIMER REACTION PRODUCT

US5389432A
(en)

*

1993-01-19
1995-02-14
Alliedsignal Inc.
Binders based on α-olefin/carboxylic acid/polyamide polymers and their ionomers

US6077906A
(en)

*

1998-03-11
2000-06-20
Thiruvengada; Seshan
Nylon modifiers hauling enhanced flow properties

CA2483196A1
(en)

*

2002-05-23
2003-12-04
E. I. Du Pont De Nemours And Company
Toughened thermoplastic polyamide compositions

US20060148988A1
(en)

*

2004-10-06
2006-07-06
Chou Richard T
Miscible blends of ethylene copolymers with improved temperature resistance

US7879949B2
(en)

2004-10-06
2011-02-01
E.I. Du Pont De Nemours And Company
Blends of ethylene copolymers with high-frequency weldability

US7767759B2
(en)

*

2004-07-16
2010-08-03
Taylor Made Golf Company, Inc.
Composition for use in golf balls

US7819761B2
(en)

2005-01-26
2010-10-26
Taylor Made Golf Company, Inc.
Golf ball having cross-core hardness differential and method for making it

US8030411B2
(en)

2005-12-21
2011-10-04
Taylor Made Golf Company, Inc.
Polymer compositions comprising peptizers, sports equipment comprising such compositions, and method for their manufacture

US20070238833A1
(en)

*

2006-04-10
2007-10-11
Christian Leboeuf
Polyamide composition comprising a modifier

US8211976B2
(en)

2007-12-21
2012-07-03
Taylor Made Golf Company, Inc.
Sports equipment compositions comprising a polyurethane, polyurea or prepolymer thereof and a polyfunctional modifier

US8096899B2
(en)

2007-12-28
2012-01-17
Taylor Made Golf Company, Inc.
Golf ball comprising isocyanate-modified composition

US20100125002A1
(en)

*

2008-11-14
2010-05-20
Taylor Made Golf Company, Inc.
Resin compositions incorporating modified polyisocyanate and method for their manufacture and use

US8680204B2
(en)

*

2009-12-23
2014-03-25
Hyun J. Kim
Crosslinked ionomer compositions

US8575278B2
(en)

2009-12-31
2013-11-05
Taylor Made Golf Company, Inc.
Ionomer compositions for golf balls

US8674023B2
(en)

2009-12-31
2014-03-18
Taylor Made Golf Company, Inc.
Ionomer compositions for golf balls

US8629228B2
(en)

2009-12-31
2014-01-14
Taylor Made Golf Company, Inc.
Ionomer compositions for golf balls

TWI529212B
(en)

2010-08-18
2016-04-11
Vertellus Specialties Inc
Compositions, methods and articles produced by compounding polymides with olefin-maleic anhydride polymers

US8858365B2
(en)

2011-12-23
2014-10-14
Taylor Made Golf Company, Inc.
Multi-layer golf ball construction

MY175183A
(en)

2013-03-15
2020-06-12
Vertellus Holdings Llc
Impact-modified polyamide compositions

US10682553B2
(en)

2018-04-18
2020-06-16
Acushnet Company
Golf ball incorporating melt processable highly-crosslinked ethylene acid copolymer(s) and/or ionomer(s)

US10773132B2
(en)

2018-04-18
2020-09-15
Acushnet Company
Golf ball incorporating melt processable highly-crosslinked rubber-containing ionomer(s)

Family Cites Families (4)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

US3017391A
(en)

*

1956-12-13
1962-01-16
Monsanto Chemicals
Preparation of polycaprolactam using n-acyl activators

US3136738A
(en)

*

1960-02-10
1964-06-09
Monsanto Co
Graft copolymer of polylactam on polymer containing tertiary amine group

US3243477A
(en)

*

1962-12-10
1966-03-29
Monsanto Co
Process of grafting a 7-8 membered lactam ring onto polyacrylyl halide

US3325561A
(en)

*

1964-10-22
1967-06-13
Foster Grant Co Inc
Graft copolymer of polyamide onto a vinyl aromatic-unsaturated carboxylic acid copolymeric backbone

1965

1965-03-02
US
US436685A
patent/US3388186A/en
not_active
Expired – Lifetime

1966

1966-03-01
NL
NL6602669A
patent/NL6602669A/xx
unknown

1966-03-01
DE
DE19661595259
patent/DE1595259A1/en
active
Pending

1966-03-01
GB
GB8983/66A
patent/GB1113825A/en
not_active
Expired

1966-03-01
ES
ES0323693A
patent/ES323693A1/en
not_active
Expired

Also Published As

Publication number
Publication date

NL6602669A
(en)

1966-09-05

DE1595259A1
(en)

1970-04-16

ES323693A1
(en)

1967-01-16

US3388186A
(en)

1968-06-11

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