GB1114174A

GB1114174A – Synthetic thermoplastic polymer composition
– Google Patents

GB1114174A – Synthetic thermoplastic polymer composition
– Google Patents
Synthetic thermoplastic polymer composition

Info

Publication number
GB1114174A

GB1114174A
GB51680/64A
GB5168064A
GB1114174A
GB 1114174 A
GB1114174 A
GB 1114174A
GB 51680/64 A
GB51680/64 A
GB 51680/64A
GB 5168064 A
GB5168064 A
GB 5168064A
GB 1114174 A
GB1114174 A
GB 1114174A
Authority
GB
United Kingdom
Prior art keywords
clay
polyethylene
ammonium
dimethyl dioctadecyl
phosphate
Prior art date
1964-12-18
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired

Application number
GB51680/64A
Inventor
Donald Moore Jonas
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Berk Ltd

Original Assignee
Berk Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1964-12-18
Filing date
1964-12-18
Publication date
1968-05-15

1964-12-18
Application filed by Berk Ltd
filed
Critical
Berk Ltd

1964-12-18
Priority to GB51680/64A
priority
Critical
patent/GB1114174A/en

1965-12-14
Priority to US513858A
priority
patent/US3516959A/en

1965-12-17
Priority to DE1544666A
priority
patent/DE1544666C3/en

1968-05-15
Publication of GB1114174A
publication
Critical
patent/GB1114174A/en

Status
Expired
legal-status
Critical
Current

Links

Espacenet

Global Dossier

Discuss

Classifications

C—CHEMISTRY; METALLURGY

C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON

C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients

C08K3/00—Use of inorganic substances as compounding ingredients

C—CHEMISTRY; METALLURGY

C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON

C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients

C08K3/00—Use of inorganic substances as compounding ingredients

C08K3/34—Silicon-containing compounds

C08K3/346—Clay

C—CHEMISTRY; METALLURGY

C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON

C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients

C08K5/00—Use of organic ingredients

C—CHEMISTRY; METALLURGY

C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON

C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients

C08K5/00—Use of organic ingredients

C08K5/0008—Organic ingredients according to more than one of the «one dot» groups of C08K5/01 – C08K5/59

C08K5/0066—Flame-proofing or flame-retarding additives

Abstract

Compositions comprise a synthetic thermoplastic polymer, selected from polyamides, polystyrene and polyolefins derived from straight-chain olefins, one or more flame retardants and up to 10 weight per cent based on the polymer of an organophilic cation-modified clay. Specified polymers are polyethylene, polypropylene, polystyrene and nylon. Specified fire retardants are chlorinated paraffins, trichlorethyl phosphate, tribromophenol, ammonium chloride, ammonium bromide, phosphoric acid esters, antimony trioxide and arsenic trioxide. The clay may be a medium or high exchange capacity clay modified with an onium base, e.g. an ammonium, phosphonium, arsonium, stibonium, oxonium, sulphonium, selenonium, telluronium, stannonium or iodonium base, or associated with an aliphatic amine containing at least 12 carbon atoms, or a derivative thereof such as may be obtained by fusing said amines with stearamide, stearonitrile or cetyl alcohol. The compositions may comprise other conventional ingredients such as plasticizers, pigments, fillers, stabilizers, anti-oxidants and antistatic agents. The clay may be dispersed in a volatile or non-volatile medium, e.g. trichlorethylene, toluene, xylene, white spirit, paraffin wax or polyethylene wax; and is preferably treated with an organic polar liquid, e.g. methanol, acetone, methyl ethyl ketone or propylene carbonate, before incorporation in the polymer. Alternatively a polymer additive may be prepared by mixing the clay and flame retardant in the presence of a volatile organic liquid, adding the polar liquid and then mixing and evaporating the liquids to obtain a mixture in gel form. Examples describe compositions comprising polyethylene, dimethyl dioctadecyl ammonium hectorite and (1-4) chlorinated paraffin and antimony trioxide, (5 and 6) trichlorethyl phosphate, (7 and 8) tritolyl phosphate and (13-16) chlorinated paraffin; polyethylene, dimethyl dioctadecyl ammonium montmorillonite and (9) ammonium bromide; polyethylene, dimethyl dioctadecyl ammonium sepiolite and (10 and 11) trichlorethyl phosphate, and (12, 17 and 18) chlorinated paraffin; polypropylene, dimethyl dioctadecyl ammonium hectorite and (19) chlorinated paraffin, (20 and 21) chlorinated paraffin and antimony trioxide, and (22 and 23) trichlorethyl phosphate; nylon 11, trichlorethyl phosphate and (24) dimethyl dioctadecyl ammonium hectorite, and (25) an organophilic zeolite clay; and polystyrene, dimethyl dioctadecyl ammonium hectorite and (26) trichlorethyl phosphate.

GB51680/64A
1964-12-18
1964-12-18
Synthetic thermoplastic polymer composition

Expired

GB1114174A
(en)

Priority Applications (3)

Application Number
Priority Date
Filing Date
Title

GB51680/64A

GB1114174A
(en)

1964-12-18
1964-12-18
Synthetic thermoplastic polymer composition

US513858A

US3516959A
(en)

1964-12-18
1965-12-14
Solid polymer compositions having flame retardant and drip resistant properties and additive compositions for imparting said properties thereto

DE1544666A

DE1544666C3
(en)

1964-12-18
1965-12-17

Organophilic, cation-modified clay as an additive to increase the drip resistance in the event of fire

Applications Claiming Priority (1)

Application Number
Priority Date
Filing Date
Title

GB51680/64A

GB1114174A
(en)

1964-12-18
1964-12-18
Synthetic thermoplastic polymer composition

Publications (1)

Publication Number
Publication Date

GB1114174A
true

GB1114174A
(en)

1968-05-15

Family
ID=10460978
Family Applications (1)

Application Number
Title
Priority Date
Filing Date

GB51680/64A
Expired

GB1114174A
(en)

1964-12-18
1964-12-18
Synthetic thermoplastic polymer composition

Country Status (3)

Country
Link

US
(1)

US3516959A
(en)

DE
(1)

DE1544666C3
(en)

GB
(1)

GB1114174A
(en)

Cited By (4)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

WO2001066627A1
(en)

*

2000-03-08
2001-09-13
Omnova Solutions Inc.
Flame resistant polyolefin compositions containing organically modified clay

WO2007146390A2
(en)

*

2006-06-15
2007-12-21
E.I. Du Pont De Nemours And Company
Nanocomposite compositions of polyamides and sepiolite-type clays

AU2009281930B2
(en)

*

2008-08-15
2015-03-12
Invista Technologies S. Ar. L.
Flame retardant polymer composites, fibers, carpets, and methods of making each

US9745515B2
(en)

2002-10-31
2017-08-29
Commonwealth Scientific And Industrial Research Organisation
Fire resistant material

Families Citing this family (26)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

US3715310A
(en)

*

1968-07-17
1973-02-06
Bakelite Xylonite Ltd
Fire-retardant compositions

US3765825A
(en)

*

1969-07-22
1973-10-16
V Hurst
Viscosity reduction of kaolin by hydrothermal treatment

US3916057A
(en)

*

1973-08-31
1975-10-28
Minnesota Mining & Mfg
Intumescent sheet material

US4070315A
(en)

*

1976-04-12
1978-01-24
General Motors Corporation
Bentonite/halogen flame retarding additive

US4069288A
(en)

*

1976-04-26
1978-01-17
Monsanto Company
Method for preparing fire retardant molding compositions

US4173561A
(en)

*

1977-01-12
1979-11-06
Sumitomo Chemical Company, Limited
Flame retardant polymer composition

CA1124930A
(en)

*

1977-03-31
1982-06-01
Fred J. Meyer
Silicate filled polyolefin resin composites

US4582866A
(en)

*

1984-04-30
1986-04-15
E. I. Du Pont De Nemours And Company
Flame retardant thermoplastic multi-block copolyester elastomers

US4742098A
(en)

*

1985-08-20
1988-05-03
Nl Chemicals, Inc.
Organophilic clay gellants and process for preparation

US4695402A
(en)

*

1985-08-20
1987-09-22
Nl Chemicals, Inc.
Organophilic clay gellants and process for preparation

GB2254081B
(en)

*

1991-03-25
1994-11-09
Ecc Int Ltd
Mineral fillers

EP0506290B1
(en)

*

1991-03-25
1999-04-28
Ecc International Limited
Mineral fillers

DE19642491A1
(en)

*

1996-10-15
1998-04-16
Basf Ag

Flame retardant thermoplastic molding compounds based on polyphenylene ethers and vinyl aromatic polymers

JP2000053858A
(en)

*

1998-08-07
2000-02-22
Showa Denko Kk
High rigidity flame retarded polyamide composite material

US6747074B1
(en)

*

1999-03-26
2004-06-08
3M Innovative Properties Company
Intumescent fire sealing composition

JP2002543260A
(en)

1999-04-30
2002-12-17
アルキャン・インターナショナル・リミテッド

Flame retardant composition

US6610770B1
(en)

*

1999-10-04
2003-08-26
Elementis Specialties, Inc.
Organoclay/polymer compositions with flame retardant properties

US6579926B2
(en)

*

1999-11-15
2003-06-17
General Electric Company
Fire retardant polyphenylene ether-organoclay composition and method of making same

US6596802B1
(en)

*

2000-08-28
2003-07-22
Eastman Chemical Company
Organoclays as processing aids for plasticized thermoplastics

ATE335784T1
(en)

*

2001-06-13
2006-09-15
Exxonmobil Chem Patents Inc

NANOCOMPOSITE MATERIALS WITH LOW PERMEABILITY

KR20050097502A
(en)

*

2003-01-08
2005-10-07
쉬드-케미아크티엔게젤샤프트
Composition based on pre-exfoliated nanoclay and use thereof

CN100406522C
(en)

*

2004-01-30
2008-07-30
三井化学株式会社
Flame-retardant polyamide composition and its use

DE102004039451A1
(en)

*

2004-08-13
2006-03-02
Süd-Chemie AG

Polymer blend of incompatible polymers

WO2009064295A1
(en)

*

2007-11-14
2009-05-22
Exxonmobil Chemical Patents, Inc.
Triethylamine functionalized elastomer in barrier applications

US7714611B1
(en)

*

2008-12-03
2010-05-11
Advantage Logic, Inc.
Permutable switching network with enhanced multicasting signals routing for interconnection fabric

US20170247539A1
(en)

2014-10-22
2017-08-31
Sabic Global Technologies B.V.
Polycarbonate/polyester composition and article prepared therefrom

Family Cites Families (7)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

CA589819A
(en)

*

1959-12-29
W. Jordan John
Modified clay and process of producing the same

US2531427A
(en)

*

1946-05-03
1950-11-28
Ernst A Hauser
Modified gel-forming clay and process of producing same

US2531396A
(en)

*

1947-03-29
1950-11-28
Nat Lead Co
Elastomer reinforced with a modified clay

US2743188A
(en)

*

1952-04-11
1956-04-24
Hunter Metallic Products Corp
Putty

US2676892A
(en)

*

1953-11-13
1954-04-27
Kanium Corp
Method for making unicellular spherulized clay particles and articles and composition thereof

US2874139A
(en)

*

1954-07-21
1959-02-17
Du Pont
Silica-filled polycaproamide

US3014001A
(en)

*

1957-01-04
1961-12-19
Reichhold Chemicals Inc
Production of glossy, air-curing, noninhibited polyester coatings

1964

1964-12-18
GB
GB51680/64A
patent/GB1114174A/en
not_active
Expired

1965

1965-12-14
US
US513858A
patent/US3516959A/en
not_active
Expired – Lifetime

1965-12-17
DE
DE1544666A
patent/DE1544666C3/en
not_active
Expired

Cited By (7)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

WO2001066627A1
(en)

*

2000-03-08
2001-09-13
Omnova Solutions Inc.
Flame resistant polyolefin compositions containing organically modified clay

US6414070B1
(en)

2000-03-08
2002-07-02
Omnova Solutions Inc.
Flame resistant polyolefin compositions containing organically modified clay

US9745515B2
(en)

2002-10-31
2017-08-29
Commonwealth Scientific And Industrial Research Organisation
Fire resistant material

WO2007146390A2
(en)

*

2006-06-15
2007-12-21
E.I. Du Pont De Nemours And Company
Nanocomposite compositions of polyamides and sepiolite-type clays

WO2007146390A3
(en)

*

2006-06-15
2008-03-27
Du Pont
Nanocomposite compositions of polyamides and sepiolite-type clays

US8198355B2
(en)

2006-06-15
2012-06-12
E. I. Du Pont De Nemours And Company
Nanocomposite compositions of polyamides and sepiolite-type clays

AU2009281930B2
(en)

*

2008-08-15
2015-03-12
Invista Technologies S. Ar. L.
Flame retardant polymer composites, fibers, carpets, and methods of making each

Also Published As

Publication number
Publication date

US3516959A
(en)

1970-06-23

DE1544666B2
(en)

1974-09-05

DE1544666C3
(en)

1975-05-07

DE1544666A1
(en)

1969-04-10

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