GB1128450A – Aqueous compositions comprising carboxy-containing copolymers
– Google Patents
GB1128450A – Aqueous compositions comprising carboxy-containing copolymers
– Google Patents
Aqueous compositions comprising carboxy-containing copolymers
Info
Publication number
GB1128450A
GB1128450A
GB54312/65A
GB5431265A
GB1128450A
GB 1128450 A
GB1128450 A
GB 1128450A
GB 54312/65 A
GB54312/65 A
GB 54312/65A
GB 5431265 A
GB5431265 A
GB 5431265A
GB 1128450 A
GB1128450 A
GB 1128450A
Authority
GB
United Kingdom
Prior art keywords
acid
copolymer
alkyl
peroxide
acrylates
Prior art date
1964-12-29
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB54312/65A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Celanese Coatings Co
Original Assignee
Celanese Coatings Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1964-12-29
Filing date
1965-12-22
Publication date
1968-09-25
1965-12-22
Application filed by Celanese Coatings Co
filed
Critical
Celanese Coatings Co
1968-09-25
Publication of GB1128450A
publication
Critical
patent/GB1128450A/en
Status
Expired
legal-status
Critical
Current
Links
Espacenet
Global Dossier
Discuss
229920001577
copolymer
Polymers
0.000
title
abstract
9
239000000203
mixture
Substances
0.000
title
abstract
3
125000003178
carboxy group
Chemical group
[H]OC(*)=O
0.000
title
abstract
2
QGZKDVFQNNGYKY-UHFFFAOYSA-N
Ammonia
Chemical compound
N
QGZKDVFQNNGYKY-UHFFFAOYSA-N
0.000
abstract
3
XSQUKJJJFZCRTK-UHFFFAOYSA-N
Urea
Chemical compound
NC(N)=O
XSQUKJJJFZCRTK-UHFFFAOYSA-N
0.000
abstract
3
125000000217
alkyl group
Chemical group
0.000
abstract
3
229920005862
polyol
Polymers
0.000
abstract
3
150000003077
polyols
Chemical class
0.000
abstract
3
229920005989
resin
Polymers
0.000
abstract
3
239000011347
resin
Substances
0.000
abstract
3
OZAIFHULBGXAKX-UHFFFAOYSA-N
2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile
Chemical compound
N#CC(C)(C)N=NC(C)(C)C#N
OZAIFHULBGXAKX-UHFFFAOYSA-N
0.000
abstract
2
SMZOUWXMTYCWNB-UHFFFAOYSA-N
2-(2-methoxy-5-methylphenyl)ethanamine
Chemical compound
COC1=CC=C(C)C=C1CCN
SMZOUWXMTYCWNB-UHFFFAOYSA-N
0.000
abstract
2
VZCYOOQTPOCHFL-OWOJBTEDSA-N
Fumaric acid
Chemical compound
OC(=O)\C=C\C(O)=O
VZCYOOQTPOCHFL-OWOJBTEDSA-N
0.000
abstract
2
MHAJPDPJQMAIIY-UHFFFAOYSA-N
Hydrogen peroxide
Chemical compound
OO
MHAJPDPJQMAIIY-UHFFFAOYSA-N
0.000
abstract
2
NBIIXXVUZAFLBC-UHFFFAOYSA-N
Phosphoric acid
Chemical compound
OP(O)(O)=O
NBIIXXVUZAFLBC-UHFFFAOYSA-N
0.000
abstract
2
PPBRXRYQALVLMV-UHFFFAOYSA-N
Styrene
Chemical compound
C=CC1=CC=CC=C1
PPBRXRYQALVLMV-UHFFFAOYSA-N
0.000
abstract
2
239000002253
acid
Substances
0.000
abstract
2
150000001412
amines
Chemical class
0.000
abstract
2
229920003180
amino resin
Polymers
0.000
abstract
2
239000003795
chemical substances by application
Substances
0.000
abstract
2
239000008199
coating composition
Substances
0.000
abstract
2
-1
crotonates
Chemical class
0.000
abstract
2
JDSHMPZPIAZGSV-UHFFFAOYSA-N
melamine
Chemical compound
NC1=NC(N)=NC(N)=N1
JDSHMPZPIAZGSV-UHFFFAOYSA-N
0.000
abstract
2
150000002734
metacrylic acid derivatives
Chemical class
0.000
abstract
2
239000000178
monomer
Substances
0.000
abstract
2
239000000243
solution
Substances
0.000
abstract
2
UMGDCJDMYOKAJW-UHFFFAOYSA-N
thiourea
Chemical compound
NC(N)=S
UMGDCJDMYOKAJW-UHFFFAOYSA-N
0.000
abstract
2
VZCYOOQTPOCHFL-UHFFFAOYSA-N
trans-butenedioic acid
Natural products
OC(=O)C=CC(O)=O
VZCYOOQTPOCHFL-UHFFFAOYSA-N
0.000
abstract
2
BGJSXRVXTHVRSN-UHFFFAOYSA-N
1,3,5-trioxane
Chemical compound
C1OCOCO1
BGJSXRVXTHVRSN-UHFFFAOYSA-N
0.000
abstract
1
LGJCFVYMIJLQJO-UHFFFAOYSA-N
1-dodecylperoxydodecane
Chemical compound
CCCCCCCCCCCCOOCCCCCCCCCCCC
LGJCFVYMIJLQJO-UHFFFAOYSA-N
0.000
abstract
1
JAHNSTQSQJOJLO-UHFFFAOYSA-N
2-(3-fluorophenyl)-1h-imidazole
Chemical compound
FC1=CC=CC(C=2NC=CN=2)=C1
JAHNSTQSQJOJLO-UHFFFAOYSA-N
0.000
abstract
1
AAMTXHVZOHPPQR-UHFFFAOYSA-N
2-(hydroxymethyl)prop-2-enoic acid
Chemical class
OCC(=C)C(O)=O
AAMTXHVZOHPPQR-UHFFFAOYSA-N
0.000
abstract
1
NIXOWILDQLNWCW-UHFFFAOYSA-N
2-Propenoic acid
Natural products
OC(=O)C=C
NIXOWILDQLNWCW-UHFFFAOYSA-N
0.000
abstract
1
FRIBMENBGGCKPD-UHFFFAOYSA-N
3-(2,3-dimethoxyphenyl)prop-2-enal
Chemical compound
COC1=CC=CC(C=CC=O)=C1OC
FRIBMENBGGCKPD-UHFFFAOYSA-N
0.000
abstract
1
GZVHEAJQGPRDLQ-UHFFFAOYSA-N
6-phenyl-1,3,5-triazine-2,4-diamine
Chemical compound
NC1=NC(N)=NC(C=2C=CC=CC=2)=N1
GZVHEAJQGPRDLQ-UHFFFAOYSA-N
0.000
abstract
1
HRPVXLWXLXDGHG-UHFFFAOYSA-N
Acrylamide
Chemical compound
NC(=O)C=C
HRPVXLWXLXDGHG-UHFFFAOYSA-N
0.000
abstract
1
NLHHRLWOUZZQLW-UHFFFAOYSA-N
Acrylonitrile
Chemical compound
C=CC#N
NLHHRLWOUZZQLW-UHFFFAOYSA-N
0.000
abstract
1
VHUUQVKOLVNVRT-UHFFFAOYSA-N
Ammonium hydroxide
Chemical compound
[NH4+].[OH-]
VHUUQVKOLVNVRT-UHFFFAOYSA-N
0.000
abstract
1
239000004342
Benzoyl peroxide
Substances
0.000
abstract
1
OMPJBNCRMGITSC-UHFFFAOYSA-N
Benzoylperoxide
Chemical compound
C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1
OMPJBNCRMGITSC-UHFFFAOYSA-N
0.000
abstract
1
229920013683
Celanese
Polymers
0.000
abstract
1
239000004593
Epoxy
Substances
0.000
abstract
1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N
Ethanol
Chemical compound
CCO
LFQSCWFLJHTTHZ-UHFFFAOYSA-N
0.000
abstract
1
229920000877
Melamine resin
Polymers
0.000
abstract
1
CERQOIWHTDAKMF-UHFFFAOYSA-N
Methacrylic acid
Chemical compound
CC(=C)C(O)=O
CERQOIWHTDAKMF-UHFFFAOYSA-N
0.000
abstract
1
CNCOEDDPFOAUMB-UHFFFAOYSA-N
N-Methylolacrylamide
Chemical compound
OCNC(=O)C=C
CNCOEDDPFOAUMB-UHFFFAOYSA-N
0.000
abstract
1
229930040373
Paraformaldehyde
Natural products
0.000
abstract
1
OFOBLEOULBTSOW-UHFFFAOYSA-N
Propanedioic acid
Natural products
OC(=O)CC(O)=O
OFOBLEOULBTSOW-UHFFFAOYSA-N
0.000
abstract
1
XTXRWKRVRITETP-UHFFFAOYSA-N
Vinyl acetate
Chemical compound
CC(=O)OC=C
XTXRWKRVRITETP-UHFFFAOYSA-N
0.000
abstract
1
IKHGUXGNUITLKF-XPULMUKRSA-N
acetaldehyde
Chemical compound
[14CH]([14CH3])=O
IKHGUXGNUITLKF-XPULMUKRSA-N
0.000
abstract
1
NJYZCEFQAIUHSD-UHFFFAOYSA-N
acetoguanamine
Chemical compound
CC1=NC(N)=NC(N)=N1
NJYZCEFQAIUHSD-UHFFFAOYSA-N
0.000
abstract
1
239000003377
acid catalyst
Substances
0.000
abstract
1
150000001299
aldehydes
Chemical class
0.000
abstract
1
125000002947
alkylene group
Chemical group
0.000
abstract
1
XYLMUPLGERFSHI-UHFFFAOYSA-N
alpha-Methylstyrene
Chemical compound
CC(=C)C1=CC=CC=C1
XYLMUPLGERFSHI-UHFFFAOYSA-N
0.000
abstract
1
229910000147
aluminium phosphate
Inorganic materials
0.000
abstract
1
229910021529
ammonia
Inorganic materials
0.000
abstract
1
239000007864
aqueous solution
Substances
0.000
abstract
1
235000019400
benzoyl peroxide
Nutrition
0.000
abstract
1
FJTUUPVRIANHEX-UHFFFAOYSA-N
butan-1-ol;phosphoric acid
Chemical compound
CCCCO.OP(O)(O)=O
FJTUUPVRIANHEX-UHFFFAOYSA-N
0.000
abstract
1
239000004202
carbamide
Substances
0.000
abstract
1
239000003054
catalyst
Substances
0.000
abstract
1
239000007795
chemical reaction product
Substances
0.000
abstract
1
238000000576
coating method
Methods
0.000
abstract
1
150000001875
compounds
Chemical class
0.000
abstract
1
239000007859
condensation product
Substances
0.000
abstract
1
LDHQCZJRKDOVOX-NSCUHMNNSA-N
crotonic acid
Chemical compound
C\C=C\C(O)=O
LDHQCZJRKDOVOX-NSCUHMNNSA-N
0.000
abstract
1
LSXWFXONGKSEMY-UHFFFAOYSA-N
di-tert-butyl peroxide
Chemical compound
CC(C)(C)OOC(C)(C)C
LSXWFXONGKSEMY-UHFFFAOYSA-N
0.000
abstract
1
QGBSISYHAICWAH-UHFFFAOYSA-N
dicyandiamide
Chemical compound
NC(N)=NC#N
QGBSISYHAICWAH-UHFFFAOYSA-N
0.000
abstract
1
150000002148
esters
Chemical class
0.000
abstract
1
UIWXSTHGICQLQT-UHFFFAOYSA-N
ethenyl propanoate
Chemical compound
CCC(=O)OC=C
UIWXSTHGICQLQT-UHFFFAOYSA-N
0.000
abstract
1
VZCYOOQTPOCHFL-OWOJBTEDSA-L
fumarate(2-)
Chemical class
[O-]C(=O)\C=C\C([O-])=O
VZCYOOQTPOCHFL-OWOJBTEDSA-L
0.000
abstract
1
239000001530
fumaric acid
Substances
0.000
abstract
1
238000010438
heat treatment
Methods
0.000
abstract
1
125000002887
hydroxy group
Chemical group
[H]O*
0.000
abstract
1
125000002768
hydroxyalkyl group
Chemical group
0.000
abstract
1
VZCYOOQTPOCHFL-UPHRSURJSA-N
maleic acid
Chemical compound
OC(=O)\C=C/C(O)=O
VZCYOOQTPOCHFL-UPHRSURJSA-N
0.000
abstract
1
239000011976
maleic acid
Substances
0.000
abstract
1
150000002688
maleic acid derivatives
Chemical class
0.000
abstract
1
FQPSGWSUVKBHSU-UHFFFAOYSA-N
methacrylamide
Chemical compound
CC(=C)C(N)=O
FQPSGWSUVKBHSU-UHFFFAOYSA-N
0.000
abstract
1
WSFSSNUMVMOOMR-NJFSPNSNSA-N
methanone
Chemical compound
O=[14CH2]
WSFSSNUMVMOOMR-NJFSPNSNSA-N
0.000
abstract
1
LVHBHZANLOWSRM-UHFFFAOYSA-N
methylenebutanedioic acid
Natural products
OC(=O)CC(=C)C(O)=O
LVHBHZANLOWSRM-UHFFFAOYSA-N
0.000
abstract
1
229920002866
paraformaldehyde
Polymers
0.000
abstract
1
229920001515
polyalkylene glycol
Polymers
0.000
abstract
1
230000000379
polymerizing effect
Effects
0.000
abstract
1
239000000047
product
Substances
0.000
abstract
1
HJWLCRVIBGQPNF-UHFFFAOYSA-N
prop-2-enylbenzene
Chemical compound
C=CCC1=CC=CC=C1
HJWLCRVIBGQPNF-UHFFFAOYSA-N
0.000
abstract
1
239000002904
solvent
Substances
0.000
abstract
1
150000005846
sugar alcohols
Polymers
0.000
abstract
1
JOXIMZWYDAKGHI-UHFFFAOYSA-N
toluene-4-sulfonic acid
Chemical compound
CC1=CC=C(S(O)(=O)=O)C=C1
JOXIMZWYDAKGHI-UHFFFAOYSA-N
0.000
abstract
1
LDHQCZJRKDOVOX-UHFFFAOYSA-N
trans-crotonic acid
Natural products
CC=CC(O)=O
LDHQCZJRKDOVOX-UHFFFAOYSA-N
0.000
abstract
1
Classifications
C—CHEMISTRY; METALLURGY
C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
C09D161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
C—CHEMISTRY; METALLURGY
C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
C08F20/62—Monocarboxylic acids having ten or more carbon atoms; Derivatives thereof
C—CHEMISTRY; METALLURGY
C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
C08F22/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides or nitriles thereof
C—CHEMISTRY; METALLURGY
C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
C08F283/06—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polyethers, polyoxymethylenes or polyacetals
C—CHEMISTRY; METALLURGY
C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
C09D157/00—Coating compositions based on unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
C09D157/04—Copolymers in which only the monomer in minority is defined
Abstract
1,128,450. Coating compositions containing carboxy-copolymers. CELANESE COATINGS CO. 22 Dec., 1965 [29 Dec., 1964], No. 54312/65. Headings C3P and C3R. Film-forming or coating compositions comprise an aqueous solution containing ammonia or an amine, a copolymer of a monoethylenically unsaturated carboxylie acid with one or more other mono-ethylenically unsaturated monomers, a substantially non-volatile polyol which is a solvent for the copolymer, and an aminoplast resin curing agent. Suitable polyols are polyalkylene glycols and alkylene oxide condensation products with polyhydric alcohols, preferably with a molecular weight of 200- 2000. The acid component of the copolymer may be acrylic, methacrylic, crotonic or itaconic acid, or a half ester of maleic or fumaric acid; suitable comonomer components include alkyl and hydroxyl alkyl acrylates, methacrylates, α-(hydroxymethyl)-acrylates, crotonates, fumarates or maleates, vinyl acetate, vinyl propionate, acrylonitrile, acrylamide, methacrylamide, N-methylol-acrylamide and its alkyl derivatives, styrene, vinyl toluene and α-methyl styrene. Some of the carboxy groups of the copolymer may be esterified by reacting with an epoxy compound, thereby introducing hydroxy groups into the copolymer. The resin curing agent may be the reaction product of an aldehyde, e.g. formaldehyde, acetaldehyde, paraformaldehyde or trioxane, with urea, thiourea, melamine, benzoguanamine, acetoguanamine or dicyandiamide, preferably etherified with a lower alcohol. The compositions are prepared by polymerizing the monomer components of the copolymer in solution in the polyol in the presence of a catalyst, such as hydrogen peroxide, benzoyl peroxide, dilauryl peroxide, di-t-butyl peroxide, cumene hydroperoxide or azobisisobutyronitrile, dissolving the product in aqueous ammonia or an aqueous amine solution, and adding the aminoplast resin. An acid catalyst may also be included, e.g. p-toluenesulphonic acid, butyl acid phosphate or phosphoric acid. Films or coatings obtained with the compositions can be cured by heating at 100-250 C. In the examples, the copolymers are derived from acrylic acid and alkyl and hydroxyalkyl acrylates, methacrylates and crotonates.
GB54312/65A
1964-12-29
1965-12-22
Aqueous compositions comprising carboxy-containing copolymers
Expired
GB1128450A
(en)
Applications Claiming Priority (1)
Application Number
Priority Date
Filing Date
Title
US421999A
US3352806A
(en)
1964-12-29
1964-12-29
Process for preparing aqueous carboxy containing copolymer solutions
Publications (1)
Publication Number
Publication Date
GB1128450A
true
GB1128450A
(en)
1968-09-25
Family
ID=23672966
Family Applications (1)
Application Number
Title
Priority Date
Filing Date
GB54312/65A
Expired
GB1128450A
(en)
1964-12-29
1965-12-22
Aqueous compositions comprising carboxy-containing copolymers
Country Status (6)
Country
Link
US
(1)
US3352806A
(en)
BE
(1)
BE674488A
(en)
DE
(1)
DE1519112A1
(en)
FR
(1)
FR1469126A
(en)
GB
(1)
GB1128450A
(en)
NL
(1)
NL6516808A
(en)
Cited By (1)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
US3959201A
(en)
1972-10-26
1976-05-25
Ppg Industries, Inc.
High solids, water thinnable compositions
Families Citing this family (38)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
US3471388A
(en)
*
1966-02-07
1969-10-07
American Cyanamid Co
Electrodeposition of aqueous coatings containing etherified methylolated melamine
DE1669026C3
(en)
*
1966-03-28
1974-10-03
Reichold-Albert-Chemie Ag, 2000 Hamburg
Thermosetting binders for coating compounds
US3506601A
(en)
*
1966-10-06
1970-04-14
Desoto Inc
Electrodeposition of thermosetting coatings from aqueous medium utilizing copolymers containing insufficient carboxylic acid for effective dispersion in water in the absence of an hydroxy component in the copolymer
US3446769A
(en)
*
1966-10-12
1969-05-27
Celanese Coatings Co
High solids coating compositions
US3489708A
(en)
*
1967-03-07
1970-01-13
Monsanto Co
Aqueous alkali-sensitive polymeric blends for the protection of finished surfaces
US4017662A
(en)
*
1967-11-29
1977-04-12
Rohm And Haas Company
Polishing method
US3959202A
(en)
*
1973-02-12
1976-05-25
American Cyanamid Company
Composition of matter comprising a blend of certain polyether polyols, certain vinyl emulsion polymers and an aminoplast cross-linking agent
US4062821A
(en)
*
1973-02-20
1977-12-13
Rohm And Haas Company
Rheologically modified metal decorating and aqueous coating composition comprising copolymer latex and aminoplast
JPS49132117A
(en)
*
1973-04-13
1974-12-18
US4106421A
(en)
*
1973-06-21
1978-08-15
Rohm And Haas Company
Method of coating utilizing rheologically modified metal decorating and aqueous coating composition comprising latex and aminoplast
JPS5442013B2
(en)
*
1974-03-05
1979-12-12
US3949107A
(en)
*
1974-05-31
1976-04-06
Liggett & Myers Incorporated
Method of polishing floors
US4137205A
(en)
*
1974-08-15
1979-01-30
Desoto, Inc.
Aqueous emulsion thermosetting coating compositions
JPS5525238B2
(en)
*
1974-12-26
1980-07-04
US4076766A
(en)
*
1975-03-27
1978-02-28
E. I. Du Pont De Nemours And Company
Flexible thermosetting acrylic enamels
US4144220A
(en)
*
1975-10-29
1979-03-13
Desoto, Inc.
High solids coating compositions and production thereof
DE2700575B2
(en)
*
1976-01-09
1981-01-29
Mitsubishi Rayon Co., Ltd.
Process for the preparation of hydrogels of water-soluble polymers or copolymers of acrylamide with reduced tack
US4273632A
(en)
*
1976-04-22
1981-06-16
Mobil Oil Corporation
Aminoplast-containing radiation curing coating compositions
US4052480A
(en)
*
1976-06-23
1977-10-04
Desoto, Inc.
High solids coating compositions containing liquid bishydroxy propyl ether of a bisphenol
US4083892A
(en)
*
1976-06-23
1978-04-11
Desoto, Inc.
High solids coating compositions containing tetrahydric adduct
US4040995A
(en)
*
1976-08-09
1977-08-09
Desoto, Inc.
High solids overprint varnish
US4154891A
(en)
*
1977-03-07
1979-05-15
Ppg Industries, Inc.
Novel thermosetting resinous compositions
US4177076A
(en)
*
1977-04-15
1979-12-04
Nippon Oil Company, Ltd.
Water or alcohol soluble printing ink composition
GB1577998A
(en)
*
1977-09-28
1980-10-29
Kansai Paint Co Ltd
Low temperature curing high solid acrylic copolymer-aminoplast resin coating compositions
US4150007A
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*
1977-10-25
1979-04-17
Eastman Kodak Company
Aqueous coating of curable binder, cross-linker and oxyethylated 2,2,4-trimethylpentane-1,3-diol
EP0005649B1
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1978-05-24
1982-05-19
Courtaulds Plc
Water-based coating compositions and coating processes using them
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1978-05-30
1980-03-18
Desoto, Inc.
Copolymerization in water soluble polyol with controlled reaction with the polyol and aqueous coatings containing the resulting copolymer solution
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1978-09-28
1980-10-28
E. I. Du Pont De Nemours And Company
Processes for the preparation of polymeric thickeners and uses thereof
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1978-12-11
1981-06-30
E. I. Du Pont De Nemours And Company
High solids coating composition of a low molecular weight acrylic polymer and an alkylated melamine cross-linking agent
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1980-01-10
1982-03-23
Desoto, Inc.
Emulsion polymerization in water-insoluble polyol
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1980-04-28
1982-05-18
E. I. Du Pont De Nemours And Company
High solids coating composition of a blend of a low molecular weight acrylic polymer and a medium molecular weight acrylic polymer and an alkylated melamine cross-linking agent
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*
1980-04-28
1983-09-13
E. I. Du Pont De Nemours And Company
Clear coat/color coat finish from a high solids coating composition of a blend of a low molecular weight acrylic polymer and a medium molecular weight acrylic polymer and an alkylated melamine cross-linking agent
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*
1982-12-23
1985-05-07
Rohm And Haas Company
High solids thermosetting coating compositions, cured coatings, coated articles, and processes
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1986-12-12
1988-06-23
Basf Ag
ADHESIVES FOR ADHESIVES WITH INCREASED HEAT RESISTANCE
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*
1992-12-08
1994-06-09
Sueddeutsche Kalkstickstoff
Water-soluble graft copolymers, used as dispersants for concrete etc.
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*
1992-12-08
1998-04-14
Skw Trostberg Aktiengesellschaft
Water-soluble graft polymers
AU737455B2
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1996-11-01
2001-08-23
Laboratoires Choisy Ltee
Improved coating or sealing composition
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2006-09-14
2008-03-20
Borst Joseph P
Method of forming a graft polyol and polyurethane article formed from the graft polyol
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Assignee
Title
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*
1956-06-25
US2906724A
(en)
*
1957-03-21
1959-09-29
American Cyanamid Co
Composition containing polymethylol melamine and an ammonium salt of a copolymer of an unsaturated monocarboxylic acid and an alkyl ester of such an acid
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1960-05-03
1964-01-21
Cook Paint & Varnish Co
Coating compositions comprising a water-soluble salt of a vinyl copolymer and a water-soluble epoxy or polyhydroxy compound
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1960-05-19
1966-04-12
Sinclair Research Inc
Styrene-maleic anhydride copolymers cross-linked with aliphatic polyhydroxy compounds
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1963-05-01
1967-01-24
Soto Chemical Coatings Inc De
Solvent solution of an alkylol ethylenically unsaturated amide copolymer having at least a portion of said alkylol groups etherified with a mixture of a monohydric alcohol and a polyhydric alcohol
1964
1964-12-29
US
US421999A
patent/US3352806A/en
not_active
Expired – Lifetime
1965
1965-12-22
GB
GB54312/65A
patent/GB1128450A/en
not_active
Expired
1965-12-23
NL
NL6516808A
patent/NL6516808A/xx
unknown
1965-12-27
DE
DE19651519112
patent/DE1519112A1/en
active
Pending
1965-12-28
FR
FR43964A
patent/FR1469126A/en
not_active
Expired
1965-12-29
BE
BE674488D
patent/BE674488A/xx
unknown
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Assignee
Title
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(en)
1972-10-26
1976-05-25
Ppg Industries, Inc.
High solids, water thinnable compositions
Also Published As
Publication number
Publication date
BE674488A
(en)
1966-06-29
NL6516808A
(en)
1966-06-30
DE1519112A1
(en)
1970-07-02
US3352806A
(en)
1967-11-14
FR1469126A
(en)
1967-02-10
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