GB1153022A – Polymer Latices
– Google Patents
GB1153022A – Polymer Latices
– Google Patents
Polymer Latices
Info
Publication number
GB1153022A
GB1153022A
GB12870/67A
GB1287067A
GB1153022A
GB 1153022 A
GB1153022 A
GB 1153022A
GB 12870/67 A
GB12870/67 A
GB 12870/67A
GB 1287067 A
GB1287067 A
GB 1287067A
GB 1153022 A
GB1153022 A
GB 1153022A
Authority
GB
United Kingdom
Prior art keywords
polymer composition
styrene
acid
component
composition
Prior art date
1966-03-21
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB12870/67A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Co
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1966-03-21
Filing date
1967-03-20
Publication date
1969-05-21
1967-03-20
Application filed by Monsanto Co
filed
Critical
Monsanto Co
1969-05-21
Publication of GB1153022A
publication
Critical
patent/GB1153022A/en
Status
Expired
legal-status
Critical
Current
Links
Espacenet
Global Dossier
Discuss
Classifications
C—CHEMISTRY; METALLURGY
C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
C11D3/16—Organic compounds
C11D3/37—Polymers
C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
A—HUMAN NECESSITIES
A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
A61K8/00—Cosmetics or similar toiletry preparations
A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
A61K8/8105—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
A61K8/8117—Homopolymers or copolymers of aromatic olefines, e.g. polystyrene; Compositions of derivatives of such polymers
A—HUMAN NECESSITIES
A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
A61K8/00—Cosmetics or similar toiletry preparations
A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
A61K8/8147—Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
A—HUMAN NECESSITIES
A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
A61Q5/00—Preparations for care of the hair
C—CHEMISTRY; METALLURGY
C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
C08F220/04—Acids; Metal salts or ammonium salts thereof
C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
C—CHEMISTRY; METALLURGY
C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
C08F257/00—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00
C08F257/02—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00 on to polymers of styrene or alkyl-substituted styrenes
C—CHEMISTRY; METALLURGY
C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 – C08F289/00
C—CHEMISTRY; METALLURGY
C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
C11D3/16—Organic compounds
C11D3/37—Polymers
Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y10S526/00—Synthetic resins or natural rubbers — part of the class 520 series
Y10S526/937—Optical clarity
Abstract
1,153,022. Polymer latices. MONSANTO CO. 20 March, 1967 [21 March, 1966], No. 12870/67. Heading C3P. Polymer latices, suitable for opacifying products such as liquid detergents, hair creams and floor waxes, comprise the polymerization product of (a) an α,#-ethylenically unsaturated carboxylic acid, (b) an at least diolefinically unsaturated compound and (c) a vinylidene monomer, wherein the polymer particles of the latex comprise from 60-90% by weight of an inner polymer composition and 10-40% by weight of an outer polymer composition orientated to the surface of the particles, the outer polymer composition comprising from 24-70 mol. per cent of component (a), from 0À6-3À0 mol. per cent of component (b) and the balance of the outer composition being component (c). Preferably, the inner polymer composition comprises component (c) alone, or together with oomponent(a) and/or component (b). The lances can be obtained by polymerizing, in aqueous emulsion, a monomeric material capable of yielding the inner polymer composition and subsequently polymerizing a monomeric material capable of yielding the outer polymer composition. The process may be effected batchwise in two separate steps, or continuously wherein the composition of the monomer charge is suitably adjusted at appropriate stages in the process. If desired, a homogeneous product can be obtained by making the inner polymer composition the same as the outer polymer composition. In examples the inner polymer compositions comprise (i) styrene-methacrylic acid, (ii) styrene, (iii) styrene-acrylonitrile, (iv) methyl methacrylate, (v) styrene-methyl acrylate, (vi) styrene dibutyl fumarate and (vii) styrenemethacrylic acid-divinyl benzene; and the outer polymer compositions comprise (i) styrenemethacrylic acid-divinyl benzene, (ii) methyl methacrylate-methyacrylic acid-ethylene dimethacrylate, (iii) styrene-methacrylic acidethylene dimethacrylate and (iv) styreneacrylic acid-diallyl fumarate. The monomers of these compositions are polymerized in aqueous emulsion containing sodium alkylbenzene sulphonate, tetrasodium pyrophosphate and potassium persulphate, and when polymerization is completed the latex is neutralized by addition of NH 4 OH.
GB12870/67A
1966-03-21
1967-03-20
Polymer Latices
Expired
GB1153022A
(en)
Applications Claiming Priority (2)
Application Number
Priority Date
Filing Date
Title
US53568966A
1966-03-21
1966-03-21
US81285269A
1969-04-02
1969-04-02
Publications (1)
Publication Number
Publication Date
GB1153022A
true
GB1153022A
(en)
1969-05-21
Family
ID=27064909
Family Applications (1)
Application Number
Title
Priority Date
Filing Date
GB12870/67A
Expired
GB1153022A
(en)
1966-03-21
1967-03-20
Polymer Latices
Country Status (2)
Country
Link
US
(1)
US3582512A
(en)
GB
(1)
GB1153022A
(en)
Cited By (4)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
DE3232827A1
(en)
*
1981-09-04
1983-03-24
NL Industries, Inc., 10020 New York, N.Y.
OPALIZING POLYMERS PARTICLES AND THEIR USE
EP0242478A2
(en)
*
1986-04-21
1987-10-28
American Colloid Company
Water absorbent acrylic copolymers
FR2658095A1
(en)
*
1989-12-18
1991-08-16
Coatex Sa
NON-TOXIC STABILIZING AGENT FOR AQUEOUS SUSPENSIONS OF SODIUM SILICO ALUMINATES
US5216100A
(en)
*
1989-12-18
1993-06-01
Coatex S.A.
Non-toxic stabilizing agent for aqueous suspensions of sodium silico-aluminates
Families Citing this family (5)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
EP0335029B1
(en)
*
1988-03-30
1994-03-16
Japan Synthetic Rubber Co., Ltd.
Highly crosslinked polymer particles and process for producing the same
US5360881A
(en)
*
1989-06-14
1994-11-01
Societe Francaise Hoechst
Method of cross-linking ethylene monomers using diallyloxyacetic acid and its basic addition salts as cross-linking agents
DE4331805A1
(en)
*
1993-09-18
1995-03-23
Basf Ag
Matt, transparent thermoplastic resins
US6544537B1
(en)
1995-07-17
2003-04-08
Milliken & Company
Opacified aqueous composition for toilets
EP1776945A1
(en)
2005-10-20
2007-04-25
Cognis IP Management GmbH
Opacifiers containing styrene copolymers
1967
1967-03-20
GB
GB12870/67A
patent/GB1153022A/en
not_active
Expired
1969
1969-04-02
US
US812852A
patent/US3582512A/en
not_active
Expired – Lifetime
Cited By (5)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
DE3232827A1
(en)
*
1981-09-04
1983-03-24
NL Industries, Inc., 10020 New York, N.Y.
OPALIZING POLYMERS PARTICLES AND THEIR USE
EP0242478A2
(en)
*
1986-04-21
1987-10-28
American Colloid Company
Water absorbent acrylic copolymers
EP0242478A3
(en)
*
1986-04-21
1988-01-07
American Colloid Company
Water absorbent acrylic copolymers
FR2658095A1
(en)
*
1989-12-18
1991-08-16
Coatex Sa
NON-TOXIC STABILIZING AGENT FOR AQUEOUS SUSPENSIONS OF SODIUM SILICO ALUMINATES
US5216100A
(en)
*
1989-12-18
1993-06-01
Coatex S.A.
Non-toxic stabilizing agent for aqueous suspensions of sodium silico-aluminates
Also Published As
Publication number
Publication date
US3582512A
(en)
1971-06-01
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Legal Events
Date
Code
Title
Description
1969-10-01
PS
Patent sealed [section 19, patents act 1949]
1980-10-29
PCNP
Patent ceased through non-payment of renewal fee
