GB1229314A

GB1229314A – – Google Patents

GB1229314A – – Google Patents

Info

Publication number
GB1229314A

GB1229314A

GB1229314DA
GB1229314A
GB 1229314 A
GB1229314 A
GB 1229314A

GB 1229314D A
GB1229314D A
GB 1229314DA
GB 1229314 A
GB1229314 A
GB 1229314A
Authority
GB
United Kingdom
Prior art keywords
ppr
aryl
alkyl
components
alcl
Prior art date
1967-08-05
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired

Application number

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1967-08-05
Filing date
1968-07-18
Publication date
1971-04-21

1967-08-05
Priority claimed from DE19671643995
external-priority
patent/DE1643995A1/en

1968-07-18
Application filed
filed
Critical

1971-04-21
Publication of GB1229314A
publication
Critical
patent/GB1229314A/en

Status
Expired
legal-status
Critical
Current

Links

Espacenet

Global Dossier

Discuss

Classifications

B—PERFORMING OPERATIONS; TRANSPORTING

B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL

B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS

B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds

B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes

B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms

B01J31/189—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms containing both nitrogen and phosphorus as complexing atoms, including e.g. phosphino moieties, in one at least bidentate or bridging ligand

B—PERFORMING OPERATIONS; TRANSPORTING

B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL

B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS

B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds

B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes

B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms

B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus

B—PERFORMING OPERATIONS; TRANSPORTING

B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL

B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS

B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds

B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes

B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands

B—PERFORMING OPERATIONS; TRANSPORTING

B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL

B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS

B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds

B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes

B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands

B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring

B—PERFORMING OPERATIONS; TRANSPORTING

B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL

B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS

B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds

B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 – B01J31/24

C—CHEMISTRY; METALLURGY

C07—ORGANIC CHEMISTRY

C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS

C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms

C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons

C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation

C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond

C07C2/08—Catalytic processes

C07C2/26—Catalytic processes with hydrides or organic compounds

C07C2/36—Catalytic processes with hydrides or organic compounds as phosphines, arsines, stilbines or bismuthines

B—PERFORMING OPERATIONS; TRANSPORTING

B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL

B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS

B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00

B01J2231/20—Olefin oligomerisation or telomerisation

B—PERFORMING OPERATIONS; TRANSPORTING

B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL

B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS

B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00

B01J2531/80—Complexes comprising metals of Group VIII as the central metal

B01J2531/84—Metals of the iron group

B01J2531/847—Nickel

B—PERFORMING OPERATIONS; TRANSPORTING

B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL

B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS

B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds

B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes

B01J31/22—Organic complexes

B01J31/2282—Unsaturated compounds used as ligands

B01J31/2291—Olefins

C—CHEMISTRY; METALLURGY

C07—ORGANIC CHEMISTRY

C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS

C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds

C07C2527/06—Halogens; Compounds thereof

C07C2527/125—Compounds comprising a halogen and scandium, yttrium, aluminium, gallium, indium or thallium

C—CHEMISTRY; METALLURGY

C07—ORGANIC CHEMISTRY

C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS

C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds

C07C2527/06—Halogens; Compounds thereof

C07C2527/125—Compounds comprising a halogen and scandium, yttrium, aluminium, gallium, indium or thallium

C07C2527/126—Aluminium chloride

C—CHEMISTRY; METALLURGY

C07—ORGANIC CHEMISTRY

C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS

C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds

C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes

C07C2531/24—Phosphines

Abstract

1,229,314. Oligomerisation catalysts. FARBWERKE HOECHST A.G. 18 July, 1968 [5 Aug., 1967], No. 34318/68. Heading B1E. [Also in Division C5] An oligomerisation catalyst comprises:- (1) a nickel compound having the formula: (a) Ni(PR 3 ) 4 , (b) Ni(PR 3 ) 2 (CH 3 =CHR1) (c) Ni(PR 3 ) 3 or (d) Ni(PR 3 ) 3 X wherein R is principally C 1 -C 8 alkyl or C 6 -C 12 aryl but may have other meanings for each of (a) (b) (c) or (d) and X is Cl, Br or I; and (2) AlCl 3 or AlBr 3 , and optionally (3) a compound PR 3 wherein R is a C 1 -C 8 alkyl, C 6 -C 12 cycloalkyl or aryl, piperidyl, dialkylamino, alkoxy, aryloxy group or chlorine. Preferred nickel components are Ni(PPR 3 ) 4 , Ni(Pn-Bu 3 ) 4 , Ni(PCl 3 ) 4 , Ni(PPR 3 ) 2 CH 2 =CH 2 , and Ni(PPR 3 ) 3 Cl. The other components are preferably AlCl 3 Cl 3 and PPR 3 ; a tertiary aliphatic amine such as triethylamine may also be present.

GB1229314D
1967-08-05
1968-07-18

Expired

GB1229314A
(en)

Applications Claiming Priority (1)

Application Number
Priority Date
Filing Date
Title

DE19671643995

DE1643995A1
(en)

1967-08-05
1967-08-05

Process for the oligomerization of linear alpha-olefins

Publications (1)

Publication Number
Publication Date

GB1229314A
true

GB1229314A
(en)

1971-04-21

Family
ID=5684427
Family Applications (1)

Application Number
Title
Priority Date
Filing Date

GB1229314D
Expired

GB1229314A
(en)

1967-08-05
1968-07-18

Country Status (2)

Country
Link

FR
(1)

FR1576134A
(en)

GB
(1)

GB1229314A
(en)

Cited By (1)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

EP0012201A2
(en)

*

1978-10-30
1980-06-25
Amoco Corporation
Coupling of aryl and heteroaryl monochlorides

Families Citing this family (1)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

FR2611700B1
(en)

*

1987-03-05
1989-07-07
Inst Francais Du Petrole

METHOD FOR DIMERIZATION OR CODIMERIZATION OF OLEFINS

1968

1968-07-18
GB
GB1229314D
patent/GB1229314A/en
not_active
Expired

1968-08-05
FR
FR1576134D
patent/FR1576134A/fr
not_active
Expired

Cited By (2)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

EP0012201A2
(en)

*

1978-10-30
1980-06-25
Amoco Corporation
Coupling of aryl and heteroaryl monochlorides

EP0012201A3
(en)

*

1978-10-30
1981-11-18
Union Carbide Corporation
Coupling of aryl and heteroaryl monochlorides; catalyst composition

Also Published As

Publication number
Publication date

FR1576134A
(en)

1969-07-25

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Legal Events

Date
Code
Title
Description

1971-09-02
PS
Patent sealed

1974-02-13
PLNP
Patent lapsed through nonpayment of renewal fees

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