GB1249079A

GB1249079A – A process for epoxidizing olefins with organic hydroperoxides
– Google Patents

GB1249079A – A process for epoxidizing olefins with organic hydroperoxides
– Google Patents
A process for epoxidizing olefins with organic hydroperoxides

Info

Publication number
GB1249079A

GB1249079A
GB05373/70D
GB1537370D
GB1249079A
GB 1249079 A
GB1249079 A
GB 1249079A
GB 05373/70 D
GB05373/70 D
GB 05373/70D
GB 1537370 D
GB1537370 D
GB 1537370D
GB 1249079 A
GB1249079 A
GB 1249079A
Authority
GB
United Kingdom
Prior art keywords
silica
catalysts
molybdenum
didymium
april
Prior art date
1969-04-02
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired

Application number
GB05373/70D
Inventor
F Wattimena
H P Wulff
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Shell Internationale Research Maatschappij BV

Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1969-04-02
Filing date
1970-04-01
Publication date
1971-10-06

1970-04-01
Application filed by Shell Internationale Research Maatschappij BV
filed
Critical
Shell Internationale Research Maatschappij BV

1971-10-06
Publication of GB1249079A
publication
Critical
patent/GB1249079A/en

Status
Expired
legal-status
Critical
Current

Links

Espacenet

Global Dossier

Discuss

Classifications

C—CHEMISTRY; METALLURGY

C07—ORGANIC CHEMISTRY

C07D—HETEROCYCLIC COMPOUNDS

C07D301/00—Preparation of oxiranes

C07D301/02—Synthesis of the oxirane ring

C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds

C07D301/19—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic hydroperoxides

B—PERFORMING OPERATIONS; TRANSPORTING

B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL

B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS

B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium

B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof

B01J21/063—Titanium; Oxides or hydroxides thereof

B—PERFORMING OPERATIONS; TRANSPORTING

B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL

B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS

B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium

B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof

B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof

B—PERFORMING OPERATIONS; TRANSPORTING

B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL

B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS

B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00

B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium

C—CHEMISTRY; METALLURGY

C07—ORGANIC CHEMISTRY

C07D—HETEROCYCLIC COMPOUNDS

C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom

C07D303/02—Compounds containing oxirane rings

Abstract

1,249,079. Epoxidation catalysts. SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ N.V. 1 April, 1970 [2 April, 1969], No. 15373/70. Heading B1E. [Also in Division C2] Catalysts used in the epoxidation of olefinic compounds with organic hydroperoxides comprise titanium in chemical combination with a solid silica and/or an inorganic silicate. In addition the catalyst may contain a promoter e.g. a compound of magnesium, calcium, strontium or barium and also an oxide or hydroxide of boron, tin, miobium, tantalum, chromium, molybdenum, rhenium, uranium, bismuth or rare earth metals (atomic numbers 57-71). Preferably the catalyst has a specific surface area of at least 1m2/g. In the examples catalysts are used comprising in addition to the titanium compound the following:-(a) zirconium, (b) niobium, (c) boron, (d) tin, (e) «didymium» (a complex mixture of rare earth metals), (f) molybdenum, (g) molybdenum and didymium and (h) alumina alone or with magnesium or calcium. For comparative purposes examples are given of the use of other catalysts e.g. mixtures of titania and silica or silicates, various other metals are silica and various metal compounds without silica.

GB05373/70D
1969-04-02
1970-04-01
A process for epoxidizing olefins with organic hydroperoxides

Expired

GB1249079A
(en)

Applications Claiming Priority (1)

Application Number
Priority Date
Filing Date
Title

US81292069A

1969-04-02
1969-04-02

Publications (1)

Publication Number
Publication Date

GB1249079A
true

GB1249079A
(en)

1971-10-06

Family
ID=25210968
Family Applications (1)

Application Number
Title
Priority Date
Filing Date

GB05373/70D
Expired

GB1249079A
(en)

1969-04-02
1970-04-01
A process for epoxidizing olefins with organic hydroperoxides

Country Status (15)

Country
Link

JP
(1)

JPS5030049B1
(en)

AT
(1)

AT302983B
(en)

BE
(1)

BE748314A
(en)

BR
(1)

BR7017923D0
(en)

CH
(1)

CH543497A
(en)

DE
(1)

DE2015503C3
(en)

DK
(1)

DK133746B
(en)

ES
(1)

ES378130A1
(en)

FR
(1)

FR2042772A5
(en)

GB
(1)

GB1249079A
(en)

IE
(1)

IE34185B1
(en)

NL
(1)

NL145233C
(en)

NO
(1)

NO127499B
(en)

SE
(1)

SE375530B
(en)

ZA
(1)

ZA702171B
(en)

Cited By (13)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

EP0345856A1
(en)

1988-06-08
1989-12-13
Shell Internationale Researchmaatschappij B.V.
A process for the preparation of an oxirane compound

US5760253A
(en)

*

1997-01-29
1998-06-02
Arco Chemical Technology, L.P.
Catalytic converter and method for highly exothermic reactions

US5795555A
(en)

*

1994-11-24
1998-08-18
Alive; Keshavaraja
Micro-meso porous amorphous titanium silicates and a process for preparing the same

US5840933A
(en)

*

1996-10-29
1998-11-24
Arco Chemical Technology, L.P.
Catalytic converter system and progress

US5932751A
(en)

*

1998-06-23
1999-08-03
Arco Chemical Technology, L.P.
Epoxidation catalyst and process

WO2001097967A1
(en)

*

2000-06-21
2001-12-27
Shell Internationale Research Maatschappij B.V.
Catalyst composition, process for its preparation and use thereof

WO2002066433A1
(en)

*

2001-02-19
2002-08-29
Lonza Ag
Process and catalyst for the preparation of acetylpyridines

US6562987B1
(en)

2002-02-28
2003-05-13
Arco Chemical Technology, L.P.
Method for highly exothermic epoxidation reactions

US6605733B2
(en)

*

2001-01-15
2003-08-12
Maruzen Petrochemical Co., Ltd.
Titanium-containing solid catalyst and process for producing epoxy compound using the same

FR2841797A1
(en)

*

2002-07-03
2004-01-09
Centre Nat Rech Scient

CATALYSTS BASED ON TUNGSTEN

US7067673B2
(en)

2001-02-19
2006-06-27
Lonza Ag
Process and catalyst for the preparation of acetylpyridines

EP1894621A1
(en)

*

2006-08-29
2008-03-05
Oxeno Olefinchemie GmbH
Catalyst and method for producing iso-olefins

WO2009106237A2
(en)

*

2008-02-26
2009-09-03
Bayer Materialscience Ag
Catalyst for the synthesis of alkyl carbamates, the method for preparing the same and the use thereof

Families Citing this family (3)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

DE3322745A1
(en)

*

1983-06-24
1985-01-03
Basf Ag, 6700 Ludwigshafen

METHOD FOR PRODUCING OXIRANES

US5723637A
(en)

*

1995-12-06
1998-03-03
Sumitomo Chemical Company, Limited
Process for producing propylene oxide

CN111377951B
(en)

*

2018-12-28
2022-09-20
万华化学集团股份有限公司
Rare earth metal compound, preparation method, composition and method for catalyzing olefin epoxidation

Family Cites Families (1)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

DE1518644A1
(en)

*

1965-04-09
1969-04-03
Huels Chemische Werke Ag

Process for the catalytic epoxidation of olefinic compounds

1970

1970-04-01
DE
DE2015503A
patent/DE2015503C3/en
not_active
Expired

1970-04-01
JP
JP45027353A
patent/JPS5030049B1/ja
active
Pending

1970-04-01
GB
GB05373/70D
patent/GB1249079A/en
not_active
Expired

1970-04-01
SE
SE7004441A
patent/SE375530B/xx
unknown

1970-04-01
IE
IE401/70A
patent/IE34185B1/en
unknown

1970-04-01
ZA
ZA702171A
patent/ZA702171B/en
unknown

1970-04-01
DK
DK163670AA
patent/DK133746B/en
not_active
IP Right Cessation

1970-04-01
BR
BR217923/70A
patent/BR7017923D0/en
unknown

1970-04-01
NL
NL7004582.A
patent/NL145233C/en
not_active
IP Right Cessation

1970-04-01
AT
AT297770A
patent/AT302983B/en
active

1970-04-01
BE
BE748314D
patent/BE748314A/en
not_active
IP Right Cessation

1970-04-01
FR
FR7011643A
patent/FR2042772A5/fr
not_active
Expired

1970-04-01
NO
NO01186/70*[A
patent/NO127499B/no
unknown

1970-04-01
ES
ES378130A
patent/ES378130A1/en
not_active
Expired

1970-04-01
CH
CH482970A
patent/CH543497A/en
not_active
IP Right Cessation

Cited By (23)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

EP0345856A1
(en)

1988-06-08
1989-12-13
Shell Internationale Researchmaatschappij B.V.
A process for the preparation of an oxirane compound

US5795555A
(en)

*

1994-11-24
1998-08-18
Alive; Keshavaraja
Micro-meso porous amorphous titanium silicates and a process for preparing the same

US5840933A
(en)

*

1996-10-29
1998-11-24
Arco Chemical Technology, L.P.
Catalytic converter system and progress

US6153153A
(en)

*

1996-10-29
2000-11-28
Arco Chemical Technology, L.P.
Exothermic reaction system

US5760253A
(en)

*

1997-01-29
1998-06-02
Arco Chemical Technology, L.P.
Catalytic converter and method for highly exothermic reactions

US5932751A
(en)

*

1998-06-23
1999-08-03
Arco Chemical Technology, L.P.
Epoxidation catalyst and process

WO2001097967A1
(en)

*

2000-06-21
2001-12-27
Shell Internationale Research Maatschappij B.V.
Catalyst composition, process for its preparation and use thereof

US7713906B2
(en)

2000-06-21
2010-05-11
Shell Oil Company
Catalyst composition, process for its preparation and use thereof

US6605733B2
(en)

*

2001-01-15
2003-08-12
Maruzen Petrochemical Co., Ltd.
Titanium-containing solid catalyst and process for producing epoxy compound using the same

US7067673B2
(en)

2001-02-19
2006-06-27
Lonza Ag
Process and catalyst for the preparation of acetylpyridines

WO2002066433A1
(en)

*

2001-02-19
2002-08-29
Lonza Ag
Process and catalyst for the preparation of acetylpyridines

US6562987B1
(en)

2002-02-28
2003-05-13
Arco Chemical Technology, L.P.
Method for highly exothermic epoxidation reactions

FR2841797A1
(en)

*

2002-07-03
2004-01-09
Centre Nat Rech Scient

CATALYSTS BASED ON TUNGSTEN

WO2004004893A3
(en)

*

2002-07-03
2004-04-15
Centre Nat Rech Scient
Catalysts comprising a tungsten oxide layer on a zirconia and/or titanium oxide support

WO2004004893A2
(en)

*

2002-07-03
2004-01-15
Centre National De La Recherche Scientifique (C.N.R.S)
Catalysts comprising a tungsten oxide layer on a zirconia and/or titanium oxide support

US7851401B2
(en)

2002-07-03
2010-12-14
Centre National De La Recherche Scientifique (C.N.R.S.)
Tungsten catalysts

EP1894621A1
(en)

*

2006-08-29
2008-03-05
Oxeno Olefinchemie GmbH
Catalyst and method for producing iso-olefins

US7977523B2
(en)

2006-08-29
2011-07-12
Evonik Oxeno Gmbh
Catalyst and process for preparing isoolefins

EP2620214A2
(en)

*

2006-08-29
2013-07-31
Evonik Oxeno GmbH
Method for manufacturing a catalyst, catalyst thereby obtained and method for manufacturing iso-olefines

EP2620214A3
(en)

*

2006-08-29
2014-01-01
Evonik Degussa GmbH
Method for manufacturing a catalyst, catalyst thereby obtained and method for manufacturing iso-olefines

US8680356B2
(en)

2006-08-29
2014-03-25
Evonik Oxeno Gmbh
Catalyst and process for preparing isoolefins

WO2009106237A2
(en)

*

2008-02-26
2009-09-03
Bayer Materialscience Ag
Catalyst for the synthesis of alkyl carbamates, the method for preparing the same and the use thereof

WO2009106237A3
(en)

*

2008-02-26
2010-01-21
Bayer Materialscience Ag
Catalyst for the synthesis of alkyl carbamates, the method for preparing the same and the use thereof

Also Published As

Publication number
Publication date

CH543497A
(en)

1973-10-31

DK133746B
(en)

1976-07-12

SE375530B
(en)

1975-04-21

BE748314A
(en)

1970-10-01

IE34185L
(en)

1970-10-02

DK133746C
(en)

1976-11-29

ZA702171B
(en)

1971-11-24

IE34185B1
(en)

1975-03-05

ES378130A1
(en)

1972-06-01

BR7017923D0
(en)

1973-01-11

NL145233C
(en)

1980-12-15

DE2015503B2
(en)

1980-04-24

AT302983B
(en)

1972-11-10

DE2015503C3
(en)

1981-04-09

NO127499B
(en)

1973-07-02

FR2042772A5
(en)

1971-02-12

NL145233B
(en)

1975-03-17

NL7004582A
(en)

1970-10-06

DE2015503A1
(en)

1970-10-29

JPS5030049B1
(en)

1975-09-29

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Legal Events

Date
Code
Title
Description

1972-02-16
PS
Patent sealed [section 19, patents act 1949]

1990-05-02
PE20
Patent expired after termination of 20 years

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