GB1289517A

GB1289517A – – Google Patents

GB1289517A – – Google Patents

Info

Publication number
GB1289517A

GB1289517A

GB1289517DA
GB1289517A
GB 1289517 A
GB1289517 A
GB 1289517A

GB 1289517D A
GB1289517D A
GB 1289517DA
GB 1289517 A
GB1289517 A
GB 1289517A
Authority
GB
United Kingdom
Prior art keywords
acid
anhydride
diisocyanate
copolyesterpolyol
polyurethanes
Prior art date
1968-09-23
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired

Application number

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1968-09-23
Filing date
1969-09-05
Publication date
1972-09-20

1969-09-05
Application filed
filed
Critical

1972-09-20
Publication of GB1289517A
publication
Critical
patent/GB1289517A/en

Status
Expired
legal-status
Critical
Current

Links

Espacenet

Global Dossier

Discuss

Classifications

C—CHEMISTRY; METALLURGY

C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON

C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS

C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule

C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds

C—CHEMISTRY; METALLURGY

C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON

C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS

C08G18/00—Polymeric products of isocyanates or isothiocyanates

C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen

C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen

C08G18/40—High-molecular-weight compounds

C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain

C—CHEMISTRY; METALLURGY

C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON

C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS

C08G18/00—Polymeric products of isocyanates or isothiocyanates

C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen

C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen

C08G18/40—High-molecular-weight compounds

C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain

C08G18/4266—Polycondensates having carboxylic or carbonic ester groups in the main chain prepared from hydroxycarboxylic acids and/or lactones

C—CHEMISTRY; METALLURGY

C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON

C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS

C08G18/00—Polymeric products of isocyanates or isothiocyanates

C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen

C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen

C08G18/40—High-molecular-weight compounds

C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain

C08G18/4266—Polycondensates having carboxylic or carbonic ester groups in the main chain prepared from hydroxycarboxylic acids and/or lactones

C08G18/4286—Polycondensates having carboxylic or carbonic ester groups in the main chain prepared from hydroxycarboxylic acids and/or lactones prepared from a combination of hydroxycarboxylic acids and/or lactones with polycarboxylic acids or ester forming derivatives thereof and polyhydroxy compounds

C—CHEMISTRY; METALLURGY

C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON

C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS

C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers

Abstract

1289517 Copolyesterpolyols and their polyurethanes INTER-POLYMER RESEARCH CORP 5 Sept 1969 [23 Sept 1968] 44103/69 Headings C3C and C3R Polyurethanes are obtained by reacting a copolyesterpolyol with an organic polyisocyanate wherein the copolyesterpolyol is prepared by equilibrating a mixture of at least two polyols selected from polyesterpolyols and polyetherpolyols at least one of which is a polyesterpolyol, by heating at 150-300‹ C. until the melting point of the equilibrated mixture becomes substantially constant, the copolyesterpolyol having approximately the same melting point as a copolyesterpolyol produced by normal polyesterification techniques and having the same final composition. A process also disclosed for the preparation of copolyesterpolyols comprises equilibrating a mixture of at least one polyesterpolyol and at least one polyetherpolyol, by heating under the above-mentioned conditions. Polyesterpolyols are derived from succinic acid and its anhydride, glutaric acid and its anhydride, adipic acid, pimelic acid, azelaic acid, sebacic acid, phthalic anhydride, isophthalic acid, terephthalic acid, chlorendic acid and its anhydride, tetrahydrophthalic acid and its anhydride with a glycol of the formula HO(CH 2 ) n OH, wherein n is 2-10, diethylene glycol, dipropylene glycol, 1,3-butyleneglycol, neopentylene glycol, lower molecular weight polypropylene glycols, trimethylol propane, 1,2,6-hexanetriol, pentaerythritol, alpha-methylglucoside or sorbitol. Preferred polyetherpolyols include the reaction product of 1,2-alkylene oxides with THF and of glycols, triols or higher polyols with propylene oxide or mixtures of propylene and ethylene oxides. Preferred polyisocyanates are 2,4- or 2,6-toluenediisocyanate; 4,41-diphenylmethane diisocyanate; 1,5-naphthalene diisocyanate, 4,- 41-biphenylene diisocyanate; 3,31-dimethyl-4,- 41-biphenylene diisocyanate, meta-xylene diisocyanate or hexamethylene diisocyanate. Polyurethanes are preferably prepared using an isocyanate catalyst, e.g. tertiary amine catalyst, metallic catalysts or mixtures thereof, and optionally in presence of chain extenders, e.g. water, glycols, amino alcohols and diamines In the examples the polyesters are prepared from epsilon-caprolactone.

GB1289517D
1968-09-23
1969-09-05

Expired

GB1289517A
(en)

Applications Claiming Priority (2)

Application Number
Priority Date
Filing Date
Title

US76179068A

1968-09-23
1968-09-23

US6363570A

1970-08-13
1970-08-13

Publications (1)

Publication Number
Publication Date

GB1289517A
true

GB1289517A
(en)

1972-09-20

Family
ID=26743610
Family Applications (1)

Application Number
Title
Priority Date
Filing Date

GB1289517D
Expired

GB1289517A
(en)

1968-09-23
1969-09-05

Country Status (4)

Country
Link

US
(1)

US3666724A
(en)

DE
(1)

DE1947781A1
(en)

FR
(1)

FR2019483A1
(en)

GB
(1)

GB1289517A
(en)

Families Citing this family (28)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

FR2178757B2
(en)

*

1972-04-05
1974-08-02
Pechiney Ugine Kuhlmann

US3899623A
(en)

*

1972-04-10
1975-08-12
Toray Industries
Synthetic leather combination of needle-punched fabric and polyetherester polyurethane

GB1406511A
(en)

*

1973-01-19
1975-09-17
Ici Ltd
Cellular polyurethanes

US3923747A
(en)

*

1973-11-23
1975-12-02
Goodrich Co B F
Poly(caprolactone)based polyurethanes having improved blocking characteristics

US3929730A
(en)

*

1973-12-28
1975-12-30
Inter Polymer Res Corp
Process for preparing polyurethanes employing a mixture of butanediol and phenylene diethanolamine as a chain extender

JPS5830346B2
(en)

*

1974-04-04
1983-06-28
ニツポンエステル カブシキガイシヤ

Fun Taiyoyou Soseibutsu

US4096129A
(en)

*

1975-10-06
1978-06-20
Fabridyne, Inc.
Glutarate-containing polyesterpolyols, methods of preparation and polyurethane compositions derived therefrom

US4124572A
(en)

*

1977-07-05
1978-11-07
Uniroyal, Inc.
Thermoplastic polyurethane elastomer

US4452922A
(en)

*

1983-02-22
1984-06-05
Texaco Inc.
Polyamide co-polymer polyols made with diesters and diamines and polyurethanes therefrom

US4800040A
(en)

*

1983-06-27
1989-01-24
Fritz Hostettler
Low temperature, storage stable mixtures of prepolymers and flow modifiers

WO1985000175A1
(en)

*

1983-06-27
1985-01-17
Pirri, Jaquelyn, P.
Low temperature, storage stable mixtures of prepolymers and flow modifiers

US4554185A
(en)

*

1984-05-15
1985-11-19
Marine Shield Corporation
Anti-fouling coating composition, process for applying same and coating thereby obtained

US4576838A
(en)

*

1984-08-15
1986-03-18
Marine Shield Corp.
Anti-fouling coating composition, process for applying same and coating thereby obtained

US4797226A
(en)

*

1985-09-24
1989-01-10
Fritz Hostettler
Low temperature, compatible mixtures of polyether prepolymers and flow modifiers

US4785026A
(en)

*

1987-11-24
1988-11-15
Arco Chemical Company
Polymer polyols with high solids content

US5578662A
(en)

1994-07-22
1996-11-26
United States Surgical Corporation
Bioabsorbable branched polymers containing units derived from dioxanone and medical/surgical devices manufactured therefrom

US20020032298A1
(en)

*

1994-07-22
2002-03-14
Bennett Steven L.
Bioabsorbable branched polymers containing units derived from dioxanone and medical/surgical devices manufactured therefrom

US6339130B1
(en)

*

1994-07-22
2002-01-15
United States Surgical Corporation
Bioabsorbable branched polymers containing units derived from dioxanone and medical/surgical devices manufactured therefrom

JPH09310059A
(en)

*

1996-05-24
1997-12-02
Nitto Denko Corp
Tacky agent composition and its tacky sheets

EP1556430B1
(en)

*

2002-10-28
2009-06-24
Tyco Healthcare Group Lp
Bioabsorbable adhesive compounds

EP1622960A4
(en)

*

2003-04-23
2008-04-23
Stepan Co
Liquid hardness agent for open cell foams

DE602004010290T2
(en)

*

2004-12-08
2008-10-02
Maeda Shell Service Co., Ltd., Okazaki

Retreaded solid tire and method of making it

US20060118223A1
(en)

*

2004-12-08
2006-06-08
Maeda Shell Service Co., Ltd.
Renewed solid tire and method of producing same

WO2007025649A1
(en)

*

2005-07-22
2007-03-08
Bayer Materialscience Ag
Process for preparing polyester polyols and their use

DE102005040617A1
(en)

*

2005-08-27
2007-03-22
Bayer Materialscience Ag

Process for the preparation of polyester polyols and their use

US8500947B2
(en)

2007-11-15
2013-08-06
Covidien Lp
Speeding cure rate of bioadhesives

CN113121786B
(en)

*

2020-01-16
2022-05-24
北京化工大学
Polyurethane elastomer with bio-based amorphous multi-polyester as soft segment and preparation method thereof

CN112457476A
(en)

*

2020-12-09
2021-03-09
福建汇得新材料有限公司
Polyester polyol with good polyether intermiscibility and preparation method thereof

Family Cites Families (4)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

US2691006A
(en)

*

1948-09-21
1954-10-05
Goodyear Tire & Rubber
Copolymers of two different linear polyesters

GB731071A
(en)

*

1951-07-19
1955-06-01
Du Pont
Preparation of elastomers from polyalkylene ether glycols and diisocyanates

GB898775A
(en)

*

1958-01-13
1962-06-14
Bexford Ltd
Improvements in or relating to polymeric materials

US3248373A
(en)

*

1961-11-14
1966-04-26
Du Pont
Urethanes containing bis (beta-hydroxyalkyl) carbamate as a chain extender

1969

1969-09-05
GB
GB1289517D
patent/GB1289517A/en
not_active
Expired

1969-09-20
DE
DE19691947781
patent/DE1947781A1/en
active
Pending

1969-09-23
FR
FR6932383A
patent/FR2019483A1/fr
not_active
Withdrawn

1970

1970-08-13
US
US63635A
patent/US3666724A/en
not_active
Expired – Lifetime

Also Published As

Publication number
Publication date

DE1947781A1
(en)

1970-04-02

FR2019483A1
(en)

1970-07-03

US3666724A
(en)

1972-05-30

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Legal Events

Date
Code
Title
Description

1973-01-31
PS
Patent sealed [section 19, patents act 1949]

1978-04-12
PLNP
Patent lapsed through nonpayment of renewal fees

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