GB1324392A – Agglomerates of zeolitic molecular sieves
– Google Patents
GB1324392A – Agglomerates of zeolitic molecular sieves
– Google Patents
Agglomerates of zeolitic molecular sieves
Info
Publication number
GB1324392A
GB1324392A
GB3566170A
GB3566170A
GB1324392A
GB 1324392 A
GB1324392 A
GB 1324392A
GB 3566170 A
GB3566170 A
GB 3566170A
GB 3566170 A
GB3566170 A
GB 3566170A
GB 1324392 A
GB1324392 A
GB 1324392A
Authority
GB
United Kingdom
Prior art keywords
agglomerates
agglomerate
molecular sieve
weight
potassium silicate
Prior art date
1969-07-24
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3566170A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1969-07-24
Filing date
1970-07-23
Publication date
1973-07-25
1970-07-23
Application filed by Union Carbide Corp
filed
Critical
Union Carbide Corp
1973-07-25
Publication of GB1324392A
publication
Critical
patent/GB1324392A/en
Status
Expired
legal-status
Critical
Current
Links
Espacenet
Global Dossier
Discuss
Classifications
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
B01J20/16—Alumino-silicates
B01J20/18—Synthetic zeolitic molecular sieves
B01J20/183—Physical conditioning without chemical treatment, e.g. drying, granulating, coating, irradiation
Abstract
1324392 Zeolitic molecular sieve agglomerates UNION CARBIDE CORP 23 July 1970 [24 July 1969] 35661/70 Heading C1A Hardened agglomerates of zeolitic molecular sieve crystals are prepared by forming an initial agglomerate comprising compacted molecular sieve crystals, applying a uniform thin continuous coating of boehmite alumina particles to the agglomerate, impregnating the alumina coated agglomerate with an aqueous potassium silicate solution (2-4 wt. per cent solids) and then firing the impregnated agglomerate at a temperature (e.g. 1050‹ to 1220‹ F.) sufficient to set and harden the silicate. The boehmite alumina particles used have been thermally deactivated at 250‹ to 350‹ C. for from 0À75 to 1À5 hours, may be less than 300 U.S. mesh in particle size, and form a coating of thickness 1 micron to 0À003 inch. The potassium silicate solution may have a K 2 O : SiO 2 ratio by weight of 0À477 to 0À40 : 1, and from 0À03 to 0À07 pounds of solution solid may be used per pound of agglomerate. Colloidal silica in suspension may also be present in the silicate solution. The agglomerates may be bonded with 5-35 wt. per cent clay (e.g. attapulgite, kaolin, sepiolite, polygorskite, plastic ball clays, bentonite, montmorillonite, illite and chlorite). The agglomerates may be dried between impregnation and firing. In Example 1, Type 3A molecular sieve crystals (80 pts. by weight anhydrous) and attapulgus clay (20 pts. by weight anhy- .drous) were dry blended, water (21 parts) was then added, and spherical bodies were formed by tumbling. 2% By weight boehmite alumina (particle size = 44 microns), previously heated at 300‹ C. for l hour in air, was tumbled with the spherical agglomerates. The coated agglomerates were soaked for 6 hours at 70‹ F. in aqueous potassium silicate (solids content = 2À9%), dried, and fired at 625‹ C. for 30 minutes.
GB3566170A
1969-07-24
1970-07-23
Agglomerates of zeolitic molecular sieves
Expired
GB1324392A
(en)
Applications Claiming Priority (1)
Application Number
Priority Date
Filing Date
Title
US84461269A
1969-07-24
1969-07-24
Publications (1)
Publication Number
Publication Date
GB1324392A
true
GB1324392A
(en)
1973-07-25
Family
ID=25293210
Family Applications (1)
Application Number
Title
Priority Date
Filing Date
GB3566170A
Expired
GB1324392A
(en)
1969-07-24
1970-07-23
Agglomerates of zeolitic molecular sieves
Country Status (6)
Country
Link
US
(1)
US3624003A
(en)
JP
(1)
JPS5144111B1
(en)
DE
(1)
DE2036310A1
(en)
FR
(1)
FR2055567A5
(en)
GB
(1)
GB1324392A
(en)
NO
(1)
NO126832B
(en)
Cited By (2)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
GB2252968A
(en)
*
1990-12-28
1992-08-26
Nikki Universal Co Ltd
Adsorbent comprising sepiolite and zeolite
ES2124200A1
(en)
*
1997-06-25
1999-01-16
Jimenez Juan Carlos Garcia
Absorbent air-freshening product.
Families Citing this family (17)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
US4086187A
(en)
*
1976-06-17
1978-04-25
Filtrol Corporation
Attrition resistant zeolitic catalyst
US4253989A
(en)
*
1978-04-14
1981-03-03
Filtrol Corporation
Zeolitic catalyst and method of producing same
DE3312876A1
(en)
*
1983-04-11
1984-10-11
Degussa Ag, 6000 Frankfurt
SILICATE-TIED ZEOLITE GRANULES, METHOD FOR THE PRODUCTION AND USE THEREOF
DE3312877A1
(en)
*
1983-04-11
1984-10-11
Degussa Ag, 6000 Frankfurt
MAGNESIUM SILICATE-TIED ZEOLITE GRANULES, TYPE ZEOLITH A, METHOD FOR THE PRODUCTION AND USE THEREOF
US4613578A
(en)
*
1984-06-20
1986-09-23
Pq Corporation
Porous zeolite granules stable in aqueous solutions
DE3600628A1
(en)
*
1986-01-11
1987-07-16
Degussa
ZEOLITE SHAPED BODY
US4853355A
(en)
*
1988-01-07
1989-08-01
Uop
Silica bonding of molecular sieves
US5045295A
(en)
*
1989-02-10
1991-09-03
Uop
Silicate treatment of molecular sieve agglomerates
US5026531A
(en)
*
1989-02-10
1991-06-25
Uop
Silicate treatment of molecular sieve agglomerates
US5120693A
(en)
*
1991-03-25
1992-06-09
Uop
Bonded adsorbent agglomerates
JP3213828B2
(en)
*
1993-05-24
2001-10-02
ユニオン昭和株式会社
Desiccant for HFC-32, HFC-152a
US5773380A
(en)
*
1995-05-26
1998-06-30
W. R. Grace & Co.-Conn.
Compositions using high-potassium zeolite A
GB0711979D0
(en)
*
2007-06-21
2007-08-01
Swelltec Ltd
Method and apparatus
US8540032B2
(en)
*
2007-06-21
2013-09-24
Swelltec Limited
Apparatus and method with hydrocarbon swellable and water swellable body
JP5523924B2
(en)
*
2010-04-30
2014-06-18
Jx日鉱日石エネルギー株式会社
Solid molding adsorbent and hydrocarbon purification method
US8207255B2
(en)
*
2010-08-24
2012-06-26
Equistar Chemicals, Lp
Polyethylene compositions and films having improved strength and optical properties
CN106853325A
(en)
*
2016-11-03
2017-06-16
明光市大全甜叶菊专业合作社
A kind of STEVIA REBAUDIANA anti-blushing agent
Family Cites Families (6)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
US2865867A
(en)
*
1956-12-26
1958-12-23
Shell Dev
Solid contact material
US3251783A
(en)
*
1960-07-20
1966-05-17
Engelhard Ind Inc
Method of preparing an alumina supported catalyst composition
US3234147A
(en)
*
1961-09-25
1966-02-08
Union Carbide Corp
Hardened molecular sieve agglomerates and manufacture thereof
US3268295A
(en)
*
1961-10-06
1966-08-23
Reynolds Metals Co
Alumina hydrate and its method of preparation
US3255027A
(en)
*
1962-09-07
1966-06-07
Du Pont
Refractory product and process
US3301788A
(en)
*
1964-03-26
1967-01-31
Grace W R & Co
Process for preparing a desiccant pellet
1969
1969-07-24
US
US844612A
patent/US3624003A/en
not_active
Expired – Lifetime
1970
1970-07-22
DE
DE19702036310
patent/DE2036310A1/en
active
Pending
1970-07-23
FR
FR7027319A
patent/FR2055567A5/fr
not_active
Expired
1970-07-23
GB
GB3566170A
patent/GB1324392A/en
not_active
Expired
1970-07-23
JP
JP45064019A
patent/JPS5144111B1/ja
active
Pending
1970-07-23
NO
NO02884/70A
patent/NO126832B/no
unknown
Cited By (5)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
GB2252968A
(en)
*
1990-12-28
1992-08-26
Nikki Universal Co Ltd
Adsorbent comprising sepiolite and zeolite
US5236878A
(en)
*
1990-12-28
1993-08-17
Nikki-Universal Co., Ltd.
Zeolite-containing adsorptive composition and adsorptive decomposition composition containing such zeolite-containing composition
GB2252968B
(en)
*
1990-12-28
1994-09-28
Nikki Universal Co Ltd
Zeolite-containing adsorptive composition and adsorptive decomposition composition containing such zeolite-containing composition
US5447701A
(en)
*
1990-12-28
1995-09-05
Nikki-Universal Co., Ltd.
Gas purification method
ES2124200A1
(en)
*
1997-06-25
1999-01-16
Jimenez Juan Carlos Garcia
Absorbent air-freshening product.
Also Published As
Publication number
Publication date
DE2036310A1
(en)
1971-02-11
FR2055567A5
(en)
1971-05-07
US3624003A
(en)
1971-11-30
NO126832B
(en)
1973-04-02
JPS5144111B1
(en)
1976-11-26
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Legal Events
Date
Code
Title
Description
1973-09-05
49R
Reference inserted (sect. 9/1949)
1973-12-05
PS
Patent sealed [section 19, patents act 1949]
1975-02-19
PLNP
Patent lapsed through nonpayment of renewal fees