GB1340873A – Carbonylation of olefins and acetylenes
– Google Patents
GB1340873A – Carbonylation of olefins and acetylenes
– Google Patents
Carbonylation of olefins and acetylenes
Info
Publication number
GB1340873A
GB1340873A
GB1441570A
GB1340873DA
GB1340873A
GB 1340873 A
GB1340873 A
GB 1340873A
GB 1441570 A
GB1441570 A
GB 1441570A
GB 1340873D A
GB1340873D A
GB 1340873DA
GB 1340873 A
GB1340873 A
GB 1340873A
Authority
GB
United Kingdom
Prior art keywords
ethyl
carboxylate
iiib
ene
oct
Prior art date
1970-03-25
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1441570A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1970-03-25
Filing date
1971-03-25
Publication date
1973-12-19
1971-03-25
Application filed by Imperial Chemical Industries Ltd
filed
Critical
Imperial Chemical Industries Ltd
1973-12-19
Publication of GB1340873A
publication
Critical
patent/GB1340873A/en
Status
Expired
legal-status
Critical
Current
Links
Espacenet
Global Dossier
Discuss
Classifications
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C67/00—Preparation of carboxylic acid esters
C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
B01J2231/32—Addition reactions to C=C or C-C triple bonds
B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
B01J2531/0213—Complexes without C-metal linkages
B01J2531/0219—Bimetallic complexes, i.e. comprising one or more units of two metals, with metal-metal bonds but no all-metal (M)n rings, e.g. Cr2(OAc)4
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
B01J2531/31—Aluminium
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
B01J2531/46—Titanium
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
B01J2531/48—Zirconium
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
B01J2531/50—Complexes comprising metals of Group V (VA or VB) as the central metal
B01J2531/57—Niobium
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
B01J2531/80—Complexes comprising metals of Group VIII as the central metal
B01J2531/82—Metals of the platinum group
B01J2531/824—Palladium
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
B01J2531/80—Complexes comprising metals of Group VIII as the central metal
B01J2531/84—Metals of the iron group
B01J2531/842—Iron
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C2601/00—Systems containing only non-condensed rings
C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
C07C2601/14—The ring being saturated
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C2601/00—Systems containing only non-condensed rings
C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C2601/00—Systems containing only non-condensed rings
C07C2601/18—Systems containing only non-condensed rings with a ring being at least seven-membered
C07C2601/20—Systems containing only non-condensed rings with a ring being at least seven-membered the ring being twelve-membered
Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
Y02P20/00—Technologies relating to chemical industry
Y02P20/50—Improvements relating to the production of bulk chemicals
Y02P20/582—Recycling of unreacted starting or intermediate materials
Abstract
1340873 Carboxylation of unsaturated organic compounds IMPERIAL CHEMICAL INDUSTRIES Ltd 19 April 1971 [25 March 1970 4 Sept 1970] 14415/70 and 42532/70 Heading C2C [Also in Division B1] Olefinically or acetylenically unsaturated compounds are converted to carboxylic acids or esters by reacting the unsaturated compound with water or an alcohol or phenol in the presence of a homogeneous catalyst system containing either a polynuclear complex incorporating palladium in combination with at least one further metal selected from iron and the metals of Groups IVa, Va and IIIb of the Periodic Table (as defined) or a palladium compound in admixture with a halide of at least one metal selected from the metals of Groups IVa, Va and IIIb. Examples describe the preparation of (a) a mixture of ethyl octane-1- and -2-carboxylates; (b) the ethyl, t-butyl, benzyl, cyclohexyl, 2-hydroxyethyl and 1-methyl-2- hydroxy propyl esters of cyclo-oct-4-ene-1- carboxylic acid and the acid itself; diethylcyclooctane dicarboxylates; ethyl 2-phenyl propionate; ethyl 2-(3-cyclohexenyl) propionate; ethyl heptenoate; ethyl cyclohexyl carboxylate, ethyl cyclo-oct-2-ene-1-carboxylate and ethyl cyclododeca-4,8-diene-1-carboxylate.
GB1441570A
1970-03-25
1971-03-25
Carbonylation of olefins and acetylenes
Expired
GB1340873A
(en)
Applications Claiming Priority (2)
Application Number
Priority Date
Filing Date
Title
GB1441570
1970-03-25
GB4253270
1970-09-04
Publications (1)
Publication Number
Publication Date
GB1340873A
true
GB1340873A
(en)
1973-12-19
Family
ID=26250545
Family Applications (1)
Application Number
Title
Priority Date
Filing Date
GB1441570A
Expired
GB1340873A
(en)
1970-03-25
1971-03-25
Carbonylation of olefins and acetylenes
Country Status (6)
Country
Link
US
(1)
US3952034A
(en)
BE
(1)
BE764787A
(en)
DE
(1)
DE2114544B2
(en)
FR
(1)
FR2085113A5
(en)
GB
(1)
GB1340873A
(en)
NL
(1)
NL7103977A
(en)
Families Citing this family (13)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
US3932484A
(en)
*
1974-04-22
1976-01-13
Texaco Inc.
Preparation of monocarboxylated cyclododeca derivatives
DE2646792C2
(en)
*
1975-10-23
1985-05-09
Mitsubishi Petrochemical Co., Ltd., Tokio/Tokyo
Process for the preparation of an α- (aryl-substituted) -propionic acid and / or an ester thereof
US4171450A
(en)
*
1977-06-22
1979-10-16
Atlantic Richfield Company
Preparation of unsaturated diesters by catalytic oxidative carbonylation of diolefins
US4093647A
(en)
*
1977-08-22
1978-06-06
Suntech, Inc.
Process for oxycarbonylation of aromatic hydrocarbons
IE53193B1
(en)
*
1981-07-14
1988-08-17
Smithkline Beckman Corp
Preparation of lower alkyl 2-formyl-3-(6-methyl-3-pyridinyl)-propionates
FR2512813A1
(en)
*
1981-09-16
1983-03-18
Rhone Poulenc Chim Base
PROCESS FOR THE CARBONYLATION OF CONJUGATED DIENES IN THE PRESENCE OF A PALLADIUM CATALYST WITH RECYCLING OF SAID CATALYST
US4681707A
(en)
*
1982-09-30
1987-07-21
The British Petroleum Company P.L.C.
Process for the production of carboxylic acid esters and/or carboxylic acids
GB8432376D0
(en)
*
1984-12-21
1985-02-06
Shell Int Research
Carbonylation of acetylenically unsaturated compounds
GB8501919D0
(en)
*
1985-01-25
1985-02-27
Shell Int Research
Carbonylation of allenically unsaturated compounds
DE3917329A1
(en)
*
1989-05-27
1990-11-29
Huels Chemische Werke Ag
PROCESS FOR THE PREPARATION OF CYCLOOCTANDICARBONSAEUREDIESTERNES
US5254720A
(en)
*
1992-12-28
1993-10-19
Ethyl Corporation
Process for preparing aryl-substituted aliphatic carboxylic acids and their alkyl esters
US6331502B1
(en)
*
1998-12-09
2001-12-18
Council Of Scientific And Industrial Research
Catalyst system containing a semilabile anionic ligand and a use of such catalyst system to produce α, β, -unsaturated carboxylic acids and their esters
WO2019219227A1
(en)
*
2018-05-15
2019-11-21
Givaudan Sa
Organic compounds
Family Cites Families (8)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
US3043872A
(en)
*
1958-11-07
1962-07-10
Union Carbide Corp
Decolorization method for pimelic acid
US3468927A
(en)
*
1965-03-15
1969-09-23
Eastman Kodak Co
Process for preparing pimelic acid and a 2,2-dialkyl-1,3-propanediol
US3453299A
(en)
*
1965-08-13
1969-07-01
Ici Ltd
Dinuclear bridged copper and palladium complexes
GB1182932A
(en)
*
1967-04-17
1970-03-04
Ici Ltd
Transition Metal Complexes
US3717670A
(en)
*
1968-08-02
1973-02-20
Monsanto Co
Production of carboxylic acids and esters
US3579552A
(en)
*
1968-08-15
1971-05-18
Monsanto Co
Production of carboxylic acids
US3661949A
(en)
*
1969-06-11
1972-05-09
Union Oil Co
Hydrocarboxylation process utilizing an iron salt cocatalyst
US3622607A
(en)
*
1969-11-03
1971-11-23
Union Oil Co
Palladium chelates having a palladium-carbon bond
1971
1971-03-24
FR
FR7110473A
patent/FR2085113A5/en
not_active
Expired
1971-03-24
BE
BE764787A
patent/BE764787A/en
unknown
1971-03-24
NL
NL7103977A
patent/NL7103977A/xx
unknown
1971-03-25
DE
DE2114544A
patent/DE2114544B2/en
not_active
Withdrawn
1971-03-25
GB
GB1441570A
patent/GB1340873A/en
not_active
Expired
1973
1973-12-03
US
US05/421,348
patent/US3952034A/en
not_active
Expired – Lifetime
Also Published As
Publication number
Publication date
FR2085113A5
(en)
1971-12-17
DE2114544A1
(en)
1971-10-14
NL7103977A
(en)
1971-09-28
DE2114544B2
(en)
1975-02-06
US3952034A
(en)
1976-04-20
BE764787A
(en)
1971-09-24
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Legal Events
Date
Code
Title
Description
1974-05-01
PS
Patent sealed [section 19, patents act 1949]
1978-11-22
PCNP
Patent ceased through non-payment of renewal fee
