GB1381104A – Hydroprocessing catalyst
– Google Patents
GB1381104A – Hydroprocessing catalyst
– Google Patents
Hydroprocessing catalyst
Info
Publication number
GB1381104A
GB1381104A
GB5875071A
GB5875071A
GB1381104A
GB 1381104 A
GB1381104 A
GB 1381104A
GB 5875071 A
GB5875071 A
GB 5875071A
GB 5875071 A
GB5875071 A
GB 5875071A
GB 1381104 A
GB1381104 A
GB 1381104A
Authority
GB
United Kingdom
Prior art keywords
diameter
dec
percent
pore volume
total pore
Prior art date
1970-12-28
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5875071A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1970-12-28
Filing date
1971-12-17
Publication date
1975-01-22
1971-12-17
Application filed by Exxon Research and Engineering Co
filed
Critical
Exxon Research and Engineering Co
1975-01-22
Publication of GB1381104A
publication
Critical
patent/GB1381104A/en
Status
Expired
legal-status
Critical
Current
Links
Espacenet
Global Dossier
Discuss
Classifications
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J35/00—Catalysts, in general, characterised by their form or physical properties
B01J35/02—Solids
B01J35/10—Solids characterised by their surface properties or porosity
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
B01J21/04—Alumina
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 – B01J23/36
B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 – B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
B01J23/85—Chromium, molybdenum or tungsten
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J35/00—Catalysts, in general, characterised by their form or physical properties
B01J35/02—Solids
B01J35/10—Solids characterised by their surface properties or porosity
B01J35/1004—Surface area
B01J35/1019—100-500 m2/g
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J35/00—Catalysts, in general, characterised by their form or physical properties
B01J35/02—Solids
B01J35/10—Solids characterised by their surface properties or porosity
B01J35/1033—Pore volume
B01J35/1038—Pore volume less than 0.5 ml/g
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J35/00—Catalysts, in general, characterised by their form or physical properties
B01J35/02—Solids
B01J35/10—Solids characterised by their surface properties or porosity
B01J35/1052—Pore diameter
B01J35/1061—2-50 nm
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J35/00—Catalysts, in general, characterised by their form or physical properties
B01J35/02—Solids
B01J35/10—Solids characterised by their surface properties or porosity
B01J35/1052—Pore diameter
B01J35/1066—50-500 nm
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J35/00—Catalysts, in general, characterised by their form or physical properties
B01J35/02—Solids
B01J35/10—Solids characterised by their surface properties or porosity
B01J35/108—Pore distribution
B01J35/109—Pore distribution bimodal
C—CHEMISTRY; METALLURGY
C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 – C10G99/00
C10G2300/10—Feedstock materials
C10G2300/107—Atmospheric residues having a boiling point of at least about 538 °C
Abstract
1381104 Hydrocarbon conversion catalysts EXXON RESEARCH & ENG CO 17 Dec 1971 [28 Dec 1970 (2)] 58750/71 Heading B1E [Also in Division C5] A hydroprocessing catalyst comprises a hydrogenation component on an aluminacomprising support having a major portion of its surface area in pores ranging from 30 to 80Š in diameter, with less than four percent of the total pore volume being in pores ranging from 200 to 2000Š in diameter, and at least three percent of the. total pore volume being in pores greater than 2000Š in diameter. In an example a catalyst comprises 1.7% SiO 2 , 3.5% CoO, 12.0% Mo, O 3 and the balance alumina, and is prepared by adding H 2 SO 4 to a, mixed solution of sodium silicate and aluminate containing gluconic acid, then adding a solution of aluminium sulphate to the mixture to give a slurry which is filtered and dried and impregnated with the Co-M components. The catalyst may be used to treat residual or residue-containing feedstocks, heavy gas oils and dirty gas oils.
GB5875071A
1970-12-28
1971-12-17
Hydroprocessing catalyst
Expired
GB1381104A
(en)
Applications Claiming Priority (2)
Application Number
Priority Date
Filing Date
Title
US10195770A
1970-12-28
1970-12-28
US10195670A
1970-12-28
1970-12-28
Publications (1)
Publication Number
Publication Date
GB1381104A
true
GB1381104A
(en)
1975-01-22
Family
ID=26798840
Family Applications (1)
Application Number
Title
Priority Date
Filing Date
GB5875071A
Expired
GB1381104A
(en)
1970-12-28
1971-12-17
Hydroprocessing catalyst
Country Status (6)
Country
Link
US
(2)
US3770617A
(en)
BE
(2)
BE807447Q
(en)
CA
(1)
CA993435A
(en)
DE
(1)
DE2164562A1
(en)
GB
(1)
GB1381104A
(en)
NL
(1)
NL7117882A
(en)
Families Citing this family (48)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
US3900427A
(en)
*
1970-12-28
1975-08-19
Exxon Research Engineering Co
Hydroprocessing catalyst
DE2233943A1
(en)
*
1971-07-14
1973-01-25
Exxon Research Engineering Co
HYDRATION CATALYST, METHOD FOR MANUFACTURING IT AND ITS USE
US3884834A
(en)
*
1971-09-24
1975-05-20
Exxon Research Engineering Co
Process catalyst
USRE30155E
(en)
*
1972-05-22
1979-11-20
American Cyanamid Company
Hydrotreating of petroleum distillates using shaped catalyst particles
US3990964A
(en)
*
1973-08-03
1976-11-09
American Cyanamid Company
Hydrotreating of petroleum distillates using shaped catalyst particles
US3966644A
(en)
*
1973-08-03
1976-06-29
American Cyanamid Company
Shaped catalyst particles
US4341625A
(en)
*
1973-08-09
1982-07-27
Chevron Research Company
Method for preparing a catalyst carrier, a catalyst containing the carrier, and a hydrocarbon hydrodesulfurization process using the catalyst
US4113661A
(en)
*
1973-08-09
1978-09-12
Chevron Research Company
Method for preparing a hydrodesulfurization catalyst
US3876523A
(en)
*
1973-08-29
1975-04-08
Mobil Oil Corp
Catalyst for residua demetalation and desulfurization
US3893947A
(en)
*
1973-09-10
1975-07-08
Union Oil Co
Group VI-B metal catalyst preparation
US4028227A
(en)
*
1974-09-24
1977-06-07
American Cyanamid Company
Hydrotreating of petroleum residuum using shaped catalyst particles of small diameter pores
JPS5857221B2
(en)
*
1974-11-25
1983-12-19
トウアネンリヨウコウギヨウ カブシキガイシヤ
Suisokashiyokubai
US3980552A
(en)
*
1975-05-05
1976-09-14
Union Oil Company Of California
Hydrodesulfurization of residual petroleum oil with a sulfided cobalt-molybdenum-alumina catalyst
US4102822A
(en)
*
1976-07-26
1978-07-25
Chevron Research Company
Hydrocarbon hydroconversion catalyst and the method for its preparation
JPS5850636B2
(en)
*
1977-07-15
1983-11-11
千代田化工建設株式会社
Desulfurization treatment method for heavy hydrocarbon oil
US4105587A
(en)
*
1977-11-16
1978-08-08
Chevron Research Company
Process for producing a particle pack composition comprising alumina and the resulting attrition resistant composition
GB2031011B
(en)
*
1978-10-05
1983-01-06
Chiyoda Chem Eng Construct Co
Processing heavy hydrocarbon oils
US4301037A
(en)
*
1980-04-01
1981-11-17
W. R. Grace & Co.
Extruded alumina catalyst support having controlled distribution of pore sizes
US4454026A
(en)
*
1981-06-17
1984-06-12
Standard Oil Company (Indiana)
Hydrotreating catalyst and process
FR2538811A1
(en)
*
1982-12-30
1984-07-06
Inst Francais Du Petrole
PROCESS FOR TREATING HEAVY OIL OR HEAVY OIL FRACTION TO CONVERT THEM TO LOWER FRACTIONS
FR2538814B1
(en)
*
1982-12-30
1986-06-27
Inst Francais Du Petrole
PROCESS FOR TREATING HEAVY OIL OR HEAVY OIL FRACTION TO CONVERT THERE INTO LIGHTER FRACTIONS
FR2538813A1
(en)
*
1982-12-31
1984-07-06
Inst Francais Du Petrole
HYDROTREATMENT PROCESS CONVERTING IN AT LEAST TWO STEPS A HEAVY FRACTION OF HYDROCARBONS CONTAINING SULFUR IMPURITIES AND METAL IMPURITIES
ZA837785B
(en)
*
1983-03-08
1985-06-26
Dow Chemical Co
Catalyst for selective hydrogenation of alkynes in the presence of dienes
US4547485A
(en)
*
1983-04-29
1985-10-15
Mobil Oil Corporation
Demetalation catalyst and a method for its preparation
US4634515A
(en)
*
1985-10-25
1987-01-06
Exxon Research And Engineering Company
Nickel adsorbent for sulfur removal from hydrocarbon feeds
US4705767A
(en)
*
1986-12-15
1987-11-10
W. R. Grace & Co.
Sulfactants in acid-peptized catalyst compositions
US4758330A
(en)
*
1987-03-11
1988-07-19
Phillips Petroleum Company
Hydrotreating employing silica-modified alumina
US4941964A
(en)
*
1988-03-14
1990-07-17
Texaco Inc.
Hydrotreatment process employing catalyst with specified pore size distribution
US4976848A
(en)
*
1988-10-04
1990-12-11
Chevron Research Company
Hydrodemetalation and hydrodesulfurization using a catalyst of specified macroporosity
US4952306A
(en)
*
1989-09-22
1990-08-28
Exxon Research And Engineering Company
Slurry hydroprocessing process
US5037532A
(en)
*
1989-09-28
1991-08-06
Exxon Research & Engineering Company
Slurry hydrotreating process
US5192734A
(en)
*
1991-10-25
1993-03-09
W. R. Grace & Co.- Conn.
Hydroprocessing catalyst composition
US6560349B1
(en)
*
1994-10-21
2003-05-06
Digimarc Corporation
Audio monitoring using steganographic information
US6387248B2
(en)
1997-11-06
2002-05-14
Texaco Inc.
Method of preparing a catalyst for use in the hydrotreating of high boiling hydrocarbon feedstocks
US6110862A
(en)
*
1998-05-07
2000-08-29
Engelhard Corporation
Catalytic material having improved conversion performance
JP4303820B2
(en)
*
1999-01-26
2009-07-29
日本ケッチェン株式会社
Hydrotreating catalyst and hydrotreating method
US6281158B1
(en)
1999-02-15
2001-08-28
Shell Oil Company
Preparation of a co-containing hydrotreating catalyst precursor and catalyst
US6218333B1
(en)
1999-02-15
2001-04-17
Shell Oil Company
Preparation of a hydrotreating catalyst
EP1511564A1
(en)
*
2002-06-12
2005-03-09
Sulzer Metco (Canada) Inc.
Hydrometallurgical process for production of supported catalysts
US7977274B2
(en)
2006-09-29
2011-07-12
Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg
Catalyst with bimodal pore size distribution and the use thereof
US7932408B2
(en)
*
2006-09-29
2011-04-26
Scientific Design Company, Inc.
Catalyst with bimodal pore size distribution and the use thereof
MX2009002359A
(en)
*
2009-03-03
2010-10-01
Mexicano Inst Petrol
Carbon supported catalyst for demetallation of heavy crude oil and residue.
US9108188B2
(en)
2012-03-07
2015-08-18
Chevoron Phillip Chemical Company, LP
Selective hydrogenation catalyst and methods of making and using same
SG11201807943UA
(en)
*
2016-03-23
2018-10-30
Shell Int Research
High metals content hydrolysis catalyst for catalytic reduction of sulfur in a gas stream
US11590485B2
(en)
2021-01-13
2023-02-28
Saudi Arabian Oil Company
Process for modifying a hydroprocessing catalyst
US11529625B2
(en)
2021-02-02
2022-12-20
Saudi Arabian Oil Company
Method of producing an encapsulated hydroprocessing catalyst
US11529614B2
(en)
2021-02-02
2022-12-20
Saudi Arabian Oil Company
Coated hydroprocessing catalyst
US20230095045A1
(en)
*
2021-09-30
2023-03-30
ExxonMobil Technology and Engineering Company
Low pressure hydroprocessing catalyst
Family Cites Families (6)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
US3267025A
(en)
*
1961-05-22
1966-08-16
Sinclair Refining Co
Catalytic hydrocarbon conversion process
US3322666A
(en)
*
1964-08-25
1967-05-30
Gulf Research Development Co
Chemical process for hydrocracking and hydrorefining of hydrocarbon oils
US3471399A
(en)
*
1967-06-09
1969-10-07
Universal Oil Prod Co
Hydrodesulfurization catalyst and process for treating residual fuel oils
US3531398A
(en)
*
1968-05-03
1970-09-29
Exxon Research Engineering Co
Hydrodesulfurization of heavy petroleum distillates
US3630888A
(en)
*
1970-03-02
1971-12-28
Hydrocarbon Research Inc
Hydrocracking and desulfurization with a catalyst having
US3668116A
(en)
*
1970-10-16
1972-06-06
Exxon Research Engineering Co
Slurry hydrodesulfurization of a heavy petroleum oil
1970
1970-12-28
US
US00101957A
patent/US3770617A/en
not_active
Expired – Lifetime
1970-12-28
US
US101956A
patent/US3692698A/en
not_active
Expired – Lifetime
1971
1971-12-17
GB
GB5875071A
patent/GB1381104A/en
not_active
Expired
1971-12-21
CA
CA130,731A
patent/CA993435A/en
not_active
Expired
1971-12-24
DE
DE19712164562
patent/DE2164562A1/en
not_active
Ceased
1971-12-27
NL
NL7117882A
patent/NL7117882A/xx
not_active
Application Discontinuation
1973
1973-11-16
BE
BE137863A
patent/BE807447Q/en
active
1976
1976-02-03
BE
BE164054A
patent/BE838223Q/en
active
Also Published As
Publication number
Publication date
NL7117882A
(en)
1972-06-30
CA993435A
(en)
1976-07-20
BE838223Q
(en)
1976-05-28
US3770617A
(en)
1973-11-06
US3692698A
(en)
1972-09-19
DE2164562A1
(en)
1972-07-27
BE807447Q
(en)
1974-05-16
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Legal Events
Date
Code
Title
Description
1975-06-04
PS
Patent sealed [section 19, patents act 1949]
1982-07-21
PCNP
Patent ceased through non-payment of renewal fee
