GB1381149A – Manufacture of cyclohexanol from cyclohexene
– Google Patents
GB1381149A – Manufacture of cyclohexanol from cyclohexene
– Google Patents
Manufacture of cyclohexanol from cyclohexene
Info
Publication number
GB1381149A
GB1381149A
GB2308372A
GB2308372A
GB1381149A
GB 1381149 A
GB1381149 A
GB 1381149A
GB 2308372 A
GB2308372 A
GB 2308372A
GB 2308372 A
GB2308372 A
GB 2308372A
GB 1381149 A
GB1381149 A
GB 1381149A
Authority
GB
United Kingdom
Prior art keywords
cyclohexene
cyclohexanol
column
sulphuric acid
reactor
Prior art date
1971-05-18
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2308372A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Badische Anilin and Sodafabrik AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1971-05-18
Filing date
1972-05-17
Publication date
1975-01-22
1971-05-18
Priority claimed from DE19712124590
external-priority
patent/DE2124590C3/en
1972-05-17
Application filed by BASF SE, Badische Anilin and Sodafabrik AG
filed
Critical
BASF SE
1975-01-22
Publication of GB1381149A
publication
Critical
patent/GB1381149A/en
Status
Expired
legal-status
Critical
Current
Links
Espacenet
Global Dossier
Discuss
Classifications
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
C07C29/03—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2
C07C29/04—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2 by hydration of carbon-to-carbon double bonds
C07C29/05—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2 by hydration of carbon-to-carbon double bonds with formation of absorption products in mineral acids and their hydrolysis
C07C29/06—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2 by hydration of carbon-to-carbon double bonds with formation of absorption products in mineral acids and their hydrolysis the acid being sulfuric acid
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C2601/00—Systems containing only non-condensed rings
C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
C07C2601/14—The ring being saturated
Abstract
1381149 Preparation of cyclohexanol BADISCHE ANILIN- & SODA-FABRIK AG 17 May 1972 [18 May 1971] 23083/72 Heading C2C Cyclohexanol is produced in a continuous process from cyclohexene in two stages involving the addition of sulphuric acid in hydration in which the addition of sulphuric acid is carried out in the presence of ferrous sulphate. As illustrated in the flow diagram cyclohexene is passed through line 6 to the reactor 1, where it is caused to boil and the temperature is maintained at 82‹ C. by vapour cooling while a 60% sulphuric acid solution, heated at 110‹ C., is fed to the reactor through line 7 and thus added to the boiling cyclohexene. The sulphuric acid leaving the reactor is diluted with water to a concentration of 30% in a mixing line 8 and passes to a saponifying and stripping column 2 operating at atmospheric temperature and a temperature of 110‹ C. The concentrated sulphuric acid (60%) which collects at the base of this column is recycled to the absorption reactor 1 through line 9. The overheads leaving column 2 pass to a separator 3 operating at 20‹ C. and in which an aqueous phase containing 3% of cyclohexanol, which is used for the hydrolysis of the alkyl sulphate, and an organic phase comprising cyclohexene, cyclohexanol and traces of water are obtained, which is fed to a column 4 for the removal of cyclohexene and traces of water, residual water being removed by adding cyclohexene at the top of the column and in a second column 5, cyclohexanol is removed from the residue.
GB2308372A
1971-05-18
1972-05-17
Manufacture of cyclohexanol from cyclohexene
Expired
GB1381149A
(en)
Applications Claiming Priority (1)
Application Number
Priority Date
Filing Date
Title
DE19712124590
DE2124590C3
(en)
1971-05-18
Process for the continuous production of cyclohexanol from cyclohexene
Publications (1)
Publication Number
Publication Date
GB1381149A
true
GB1381149A
(en)
1975-01-22
Family
ID=5808219
Family Applications (1)
Application Number
Title
Priority Date
Filing Date
GB2308372A
Expired
GB1381149A
(en)
1971-05-18
1972-05-17
Manufacture of cyclohexanol from cyclohexene
Country Status (4)
Country
Link
BE
(1)
BE783581A
(en)
FR
(1)
FR2138128B1
(en)
GB
(1)
GB1381149A
(en)
NL
(1)
NL7206342A
(en)
Cited By (2)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
EP0087924A2
(en)
*
1982-03-01
1983-09-07
The British Petroleum Company p.l.c.
Process for the catalytic oxidation of a paraffinic hydrocarbon to an alcohol and either an aldehyde or a ketone
US6245907B1
(en)
1997-12-08
2001-06-12
Hyosung Corporation
Process for producing a high purity caprolactam
1972
1972-05-10
NL
NL7206342A
patent/NL7206342A/xx
not_active
Application Discontinuation
1972-05-17
BE
BE783581A
patent/BE783581A/en
unknown
1972-05-17
GB
GB2308372A
patent/GB1381149A/en
not_active
Expired
1972-05-18
FR
FR7217934A
patent/FR2138128B1/fr
not_active
Expired
Cited By (3)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
EP0087924A2
(en)
*
1982-03-01
1983-09-07
The British Petroleum Company p.l.c.
Process for the catalytic oxidation of a paraffinic hydrocarbon to an alcohol and either an aldehyde or a ketone
EP0087924A3
(en)
*
1982-03-01
1984-03-28
The British Petroleum Company p.l.c.
Process for the catalytic oxidation of a paraffinic hydrocarbon to an alcohol and either an aldehyde or a ketone
US6245907B1
(en)
1997-12-08
2001-06-12
Hyosung Corporation
Process for producing a high purity caprolactam
Also Published As
Publication number
Publication date
FR2138128A1
(en)
1972-12-29
DE2124590A1
(en)
1972-11-30
DE2124590B2
(en)
1975-06-19
FR2138128B1
(en)
1975-08-08
BE783581A
(en)
1972-11-17
NL7206342A
(en)
1972-11-21
Similar Documents
Publication
Publication Date
Title
GB982647A
(en)
1965-02-10
Preparation of cyclohexanol and cyclohexanone
GB1381149A
(en)
1975-01-22
Manufacture of cyclohexanol from cyclohexene
US2831020A
(en)
1958-04-15
Processes for producing anhydrous aromatic sulfonic acids with low sulfone content and the products thereof
US2304602A
(en)
1942-12-08
Method for the production of sebacic acid and methylhexylcarbinol
GB1030727A
(en)
1966-05-25
Process for the continuous manufacture, purification and isolation of lactic acid
US3988379A
(en)
1976-10-26
Manufacture of cyclohexanol from cyclohexene
US3793373A
(en)
1974-02-19
Recovery of components from the alkaline wash water of oxidation tailings
US1961987A
(en)
1934-06-05
Production of ethers
US2963521A
(en)
1960-12-06
Process for manufacture of acetylenic hydrocarbons
US2377138A
(en)
1945-05-29
Separation of chlorine and sulphur dioxide
GB649286A
(en)
1951-01-24
Manufacture of phenol
US3947490A
(en)
1976-03-30
Process for preparing omega-formyloxy-alkanals
GB1013618A
(en)
1965-12-15
Improved process for recovery of adipic acid precursors
GB963359A
(en)
1964-07-08
Chemical process for recovery of vanadium and copper catalysts
US2490671A
(en)
1949-12-06
Separation of metaethylphenol from paraethylphenol
GB935029A
(en)
1963-08-28
Oxidation process for the production of epsilon-hydroxycaproic acid
GB1026971A
(en)
1966-04-20
Oxidation of hydrocarbons to alcohols
GB1443078A
(en)
1976-07-21
Process for producing ethylphenols
GB978865A
(en)
1964-12-23
Improvements in the production of urea
GB728563A
(en)
1955-04-20
Method of decomposing sulphite liquors at elevated temperatures and pressures
JPS55108825A
(en)
1980-08-21
Separation and recovery of isobutene
GB980028A
(en)
1965-01-13
Process for the production of pure monomeric formaldehyde
GB843587A
(en)
1960-08-04
Improvements relating to the preparation of hydrazine sulphate
GB708312A
(en)
1954-05-05
Improvements in or relating to benzene hexachloride and process for producing same
GB748287A
(en)
1956-04-25
Phenol production
Legal Events
Date
Code
Title
Description
1975-06-04
PS
Patent sealed
1983-12-29
PCNP
Patent ceased through non-payment of renewal fee
