GB1444659A – Process for producing unsaturated aldehydes unsaturated fatty acids or conjugated butadiene
– Google Patents
GB1444659A – Process for producing unsaturated aldehydes unsaturated fatty acids or conjugated butadiene
– Google Patents
Process for producing unsaturated aldehydes unsaturated fatty acids or conjugated butadiene
Info
Publication number
GB1444659A
GB1444659A
GB2401274A
GB2401274A
GB1444659A
GB 1444659 A
GB1444659 A
GB 1444659A
GB 2401274 A
GB2401274 A
GB 2401274A
GB 2401274 A
GB2401274 A
GB 2401274A
GB 1444659 A
GB1444659 A
GB 1444659A
Authority
GB
United Kingdom
Prior art keywords
unsaturated
fatty acids
oxidation
aldehydes
producing
Prior art date
1973-06-11
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2401274A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Rayon Co Ltd
Original Assignee
Mitsubishi Rayon Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1973-06-11
Filing date
1974-05-30
Publication date
1976-08-04
1973-06-11
Priority claimed from JP6556373A
external-priority
patent/JPS5324403B2/ja
1973-08-28
Priority claimed from JP9634573A
external-priority
patent/JPS535651B2/ja
1973-12-18
Priority claimed from JP14211873A
external-priority
patent/JPS5310964B2/ja
1973-12-26
Priority claimed from JP14400073A
external-priority
patent/JPS5320964B2/ja
1974-05-30
Application filed by Mitsubishi Rayon Co Ltd
filed
Critical
Mitsubishi Rayon Co Ltd
1976-08-04
Publication of GB1444659A
publication
Critical
patent/GB1444659A/en
Status
Expired
legal-status
Critical
Current
Links
Espacenet
Global Dossier
Discuss
Classifications
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 – B01J23/36
B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 – B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
B01J23/85—Chromium, molybdenum or tungsten
B01J23/88—Molybdenum
B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 – B01J23/36
B01J23/8872—Alkali or alkaline earth metals
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 – B01J23/36
B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 – B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
B01J23/85—Chromium, molybdenum or tungsten
B01J23/88—Molybdenum
B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 – B01J23/36
B01J23/8871—Rare earth metals or actinides
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 – B01J23/36
B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 – B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
B01J23/85—Chromium, molybdenum or tungsten
B01J23/88—Molybdenum
B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 – B01J23/36
B01J23/8875—Germanium, tin or lead
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 – B01J23/36
B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 – B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
B01J23/85—Chromium, molybdenum or tungsten
B01J23/88—Molybdenum
B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 – B01J23/36
B01J23/8876—Arsenic, antimony or bismuth
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
C—CHEMISTRY; METALLURGY
C07—ORGANIC CHEMISTRY
C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
B—PERFORMING OPERATIONS; TRANSPORTING
B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
Abstract
1444659 Oxidation catalyst MITSUBISHI RAYON CO Ltd 30 May 1974 [11 June 1973 28 Aug 1973 18 Dec 1973 26 Dec 1973] 24012/ 74 Heading B1E [Also in Divisions C2 and C5] A catalyst composition for the oxidation of unsaturated C 3 or C 4 hydrocarbons or t-butyl alcohol to the corresponding unsaturated aldehydes, unsaturated acid or conjugated dienes has the general formula wherein: X is at least one of K, Rb and Cs; Y is at least one of Pd, Co, U, Ge, W and Ti: a = 12; b = 0.2-20; c = 0.2-12; d = 0.2-12; e = 0.2-12; f = 0-20; g = 0.01-4; h = 0-6; and i is determined according to the state of oxidation. The Examples describe silica-supported compositions. The use of alumina or silicon carbide supports is also mentioned.
GB2401274A
1973-06-11
1974-05-30
Process for producing unsaturated aldehydes unsaturated fatty acids or conjugated butadiene
Expired
GB1444659A
(en)
Applications Claiming Priority (4)
Application Number
Priority Date
Filing Date
Title
JP6556373A
JPS5324403B2
(en)
1973-06-11
1973-06-11
JP9634573A
JPS535651B2
(en)
1973-08-28
1973-08-28
JP14211873A
JPS5310964B2
(en)
1973-12-18
1973-12-18
JP14400073A
JPS5320964B2
(en)
1973-12-26
1973-12-26
Publications (1)
Publication Number
Publication Date
GB1444659A
true
GB1444659A
(en)
1976-08-04
Family
ID=27464592
Family Applications (1)
Application Number
Title
Priority Date
Filing Date
GB2401274A
Expired
GB1444659A
(en)
1973-06-11
1974-05-30
Process for producing unsaturated aldehydes unsaturated fatty acids or conjugated butadiene
Country Status (5)
Country
Link
US
(1)
US3972920A
(en)
DE
(1)
DE2427670C3
(en)
FR
(1)
FR2232524B1
(en)
GB
(1)
GB1444659A
(en)
NL
(1)
NL170620C
(en)
Cited By (3)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
US4778930A
(en)
*
1974-08-05
1988-10-18
The Standard Oil Company
Process for the oxidation of olefins using catalysts contaning antimony
US6399818B2
(en)
2000-05-19
2002-06-04
Nippon Shokubai Co. Ltd.
Process for producing unsaturated aldehydes and unsaturated carboxylic acids
US7850928B2
(en)
2001-01-25
2010-12-14
Nippon Shokubai Co., Ltd.
Fixed-bed shell-and-tube reactor and its usage
Families Citing this family (31)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
US4111984A
(en)
*
1973-06-11
1978-09-05
Mitsubishi Rayon Co., Ltd.
Process for producing unsaturated aldehydes, and unsaturated fatty acids
GB1523772A
(en)
*
1974-07-22
1978-09-06
Standard Oil Co
Oxidation catalysts
US4162234A
(en)
*
1974-07-22
1979-07-24
The Standard Oil Company
Oxidation catalysts
GB1490683A
(en)
*
1975-03-12
1977-11-02
Mitsubishi Rayon Co
Process and a catalyst for producing unsaturated aldehydes unsaturated carboxylic acids or conjugated diene
US4065507A
(en)
*
1976-08-02
1977-12-27
Standard Oil Company
Preparation of methacrylic derivatives from tertiary butyl-containing compounds
IL55073A
(en)
*
1977-07-28
1982-01-31
Standard Oil Co
Catalysts for the oxidation and ammoxidation of olefins
CA1133505A
(en)
*
1977-07-28
1982-10-12
Andrew T. Guttmann
Process for the oxidation of olefins
US4167494A
(en)
*
1977-08-21
1979-09-11
The Standard Oil Company
Production of unsaturated nitriles using catalysts containing boron, gallium or indium
US4092132A
(en)
*
1977-09-06
1978-05-30
Halcon Research And Development Corp.
Recovery of methacrolein
US4191710A
(en)
*
1977-09-06
1980-03-04
Halcon Research And Development Corp.
Treatment of methacrolein-containing gases
US4413155A
(en)
*
1977-12-20
1983-11-01
The Standard Oil Co.
Ammoxidation of olefins with novel antimonate catalysts
US4234519A
(en)
*
1979-01-26
1980-11-18
Halcon Research And Development Corp.
Recovery of methacrolein
US4306090A
(en)
*
1979-10-12
1981-12-15
Rohm And Haas Company
Catalyst compositions and their use for the preparation of methacrolein
US4280928A
(en)
*
1979-10-12
1981-07-28
Rohm And Haas Company
Catalyst compositions and their use for the preparation of methacrolein
GB2077257B
(en)
*
1980-05-19
1984-06-27
Asahi Chemical Ind
Process for producing methacrolein
EP0058046B1
(en)
*
1981-02-05
1984-08-01
Ube Industries, Ltd.
Process for producing methacrolein and methacrylic acid
US4537874A
(en)
*
1982-10-22
1985-08-27
Nippon Shokubai Kagaku Kogyo Co Ltd
Catalyst for production of unsaturated aldehydes
US5208371A
(en)
*
1986-11-11
1993-05-04
Mitsubishi Rayon Co., Ltd.
Process for production of methacrolein and methacrylic acid
DE69109746T2
(en)
*
1990-06-06
1995-10-26
Mitsui Toatsu Chemicals
Process for the production of acrolein or methacrolein.
JP2841324B2
(en)
*
1990-06-06
1998-12-24
三井化学株式会社
Method for producing methacrolein
JP4242597B2
(en)
*
2002-02-28
2009-03-25
株式会社日本触媒
Unsaturated aldehyde synthesis catalyst, production method thereof, and production method of unsaturated aldehyde using the catalyst
US7649111B2
(en)
2005-07-25
2010-01-19
Saudi Basic Industries Corporation
Catalyst for the oxidation of a mixed aldehyde feedstock to methacrylic acid and methods for making and using same
US7851397B2
(en)
2005-07-25
2010-12-14
Saudi Basic Industries Corporation
Catalyst for methacrolein oxidation and method for making and using same
US7732367B2
(en)
2005-07-25
2010-06-08
Saudi Basic Industries Corporation
Catalyst for methacrolein oxidation and method for making and using same
US7649112B2
(en)
2005-07-25
2010-01-19
Saudi Basic Industries Corporation
Integrated plant for producing 2-ethyl-hexanol and methacrylic acid and a method based thereon
JP2011121048A
(en)
*
2009-12-09
2011-06-23
Rohm & Haas Co
Method for blending and loading solid catalyst material into tubular structure
US8921257B2
(en)
2011-12-02
2014-12-30
Saudi Basic Industries Corporation
Dual function partial oxidation catalyst for propane to acrylic acid conversion
US8722940B2
(en)
2012-03-01
2014-05-13
Saudi Basic Industries Corporation
High molybdenum mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
WO2014182026A1
(en)
*
2013-05-06
2014-11-13
(주) 엘지화학
Oxidation catalyst for preparing butadiene and method for preparing same
KR101495478B1
(en)
2013-05-06
2015-02-23
주식회사 엘지화학
oxidation catalyst for production of butadiene and method of preparing the same
RU2552984C1
(en)
*
2014-01-17
2015-06-10
Общество С Ограниченной Ответственностью «Научно-Производственная Компания «Синтез»
Catalyst for producing butadiene-1,3 and method of producing butadiene-1,3 using said catalyst
Family Cites Families (7)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
US3470239A
(en)
*
1968-06-07
1969-09-30
Halcon International Inc
Process for preparing methacrylic acid and its esters from isobutane
US3642930A
(en)
*
1968-12-30
1972-02-15
Standard Oil Co Ohio
Process for the manufacture of isoprene from isoamylenes and methyl butanols and catalyst therefor
DE2000425A1
(en)
*
1969-01-11
1970-07-16
Toa Gosei Chem Ind
Process for the oxidation of olefins
JPS494441B1
(en)
*
1970-11-07
1974-02-01
JPS4817253B1
(en)
*
1970-11-07
1973-05-28
JPS5112603B1
(en)
*
1971-05-26
1976-04-21
US3892794A
(en)
*
1972-02-09
1975-07-01
Standard Oil Co
Process for the manufacture of unsaturated aldehydes acids and nitriles from the corresponding olefins
1974
1974-05-29
US
US05/474,218
patent/US3972920A/en
not_active
Expired – Lifetime
1974-05-30
GB
GB2401274A
patent/GB1444659A/en
not_active
Expired
1974-06-07
DE
DE2427670A
patent/DE2427670C3/en
not_active
Expired
1974-06-11
FR
FR7420203A
patent/FR2232524B1/fr
not_active
Expired
1974-06-11
NL
NLAANVRAGE7407755,A
patent/NL170620C/en
not_active
IP Right Cessation
Cited By (3)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
US4778930A
(en)
*
1974-08-05
1988-10-18
The Standard Oil Company
Process for the oxidation of olefins using catalysts contaning antimony
US6399818B2
(en)
2000-05-19
2002-06-04
Nippon Shokubai Co. Ltd.
Process for producing unsaturated aldehydes and unsaturated carboxylic acids
US7850928B2
(en)
2001-01-25
2010-12-14
Nippon Shokubai Co., Ltd.
Fixed-bed shell-and-tube reactor and its usage
Also Published As
Publication number
Publication date
US3972920A
(en)
1976-08-03
NL170620B
(en)
1982-07-01
FR2232524A1
(en)
1975-01-03
NL170620C
(en)
1982-12-01
NL7407755A
(en)
1974-12-13
DE2427670B2
(en)
1981-04-02
FR2232524B1
(en)
1976-06-25
DE2427670C3
(en)
1982-01-14
DE2427670A1
(en)
1975-01-02
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A process for the production of highly active silver catalysts
GB1268303A
(en)
1972-03-29
Carbonylation process
GB1503788A
(en)
1978-03-15
Preparation of aldehydes and unsaturated carboxylic acids by catalytic oxidation of the corresponding olefines
Legal Events
Date
Code
Title
Description
1976-12-15
PS
Patent sealed [section 19, patents act 1949]
1994-06-29
PE20
Patent expired after termination of 20 years
Effective date:
19940529
