GB1479394A

GB1479394A – Solutions of polyhydrazides
– Google Patents

GB1479394A – Solutions of polyhydrazides
– Google Patents
Solutions of polyhydrazides

Info

Publication number
GB1479394A

GB1479394A
GB38787/75A
GB3878775A
GB1479394A
GB 1479394 A
GB1479394 A
GB 1479394A
GB 38787/75 A
GB38787/75 A
GB 38787/75A
GB 3878775 A
GB3878775 A
GB 3878775A
GB 1479394 A
GB1479394 A
GB 1479394A
Authority
GB
United Kingdom
Prior art keywords
chloride
dihydrazide
solution
acid
dihydrazides
Prior art date
1974-09-23
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired

Application number
GB38787/75A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

EIDP Inc

Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1974-09-23
Filing date
1975-09-22
Publication date
1977-07-13

1975-09-22
Application filed by EI Du Pont de Nemours and Co
filed
Critical
EI Du Pont de Nemours and Co

1977-07-13
Publication of GB1479394A
publication
Critical
patent/GB1479394A/en

Status
Expired
legal-status
Critical
Current

Links

Espacenet

Global Dossier

Discuss

RWRDLPDLKQPQOW-UHFFFAOYSA-N
Pyrrolidine
Chemical compound

C1CCNC1
RWRDLPDLKQPQOW-UHFFFAOYSA-N
0.000
abstract
3

ZMANZCXQSJIPKH-UHFFFAOYSA-N
Triethylamine
Chemical compound

CCN(CC)CC
ZMANZCXQSJIPKH-UHFFFAOYSA-N
0.000
abstract
3

229920000642
polymer
Polymers

0.000
abstract
3

239000000243
solution
Substances

0.000
abstract
3

QCOGKXLOEWLIDC-UHFFFAOYSA-N
N-methylbutylamine
Chemical compound

CCCCNC
QCOGKXLOEWLIDC-UHFFFAOYSA-N
0.000
abstract
2

NQRYJNQNLNOLGT-UHFFFAOYSA-N
Piperidine
Chemical compound

C1CCNCC1
NQRYJNQNLNOLGT-UHFFFAOYSA-N
0.000
abstract
2

239000007864
aqueous solution
Substances

0.000
abstract
2

-1
dicarboxylic acid chlorides
Chemical class

0.000
abstract
2

CTSLXHKWHWQRSH-UHFFFAOYSA-N
oxalyl chloride
Chemical compound

ClC(=O)C(Cl)=O
CTSLXHKWHWQRSH-UHFFFAOYSA-N
0.000
abstract
2

WGTYBPLFGIVFAS-UHFFFAOYSA-M
tetramethylammonium hydroxide
Chemical compound

[OH-].C[N+](C)(C)C
WGTYBPLFGIVFAS-UHFFFAOYSA-M
0.000
abstract
2

FYTVIRMGRCDOSB-UHFFFAOYSA-N
1-n’,4-n’-dimethylbenzene-1,4-dicarbohydrazide
Chemical compound

CNNC(=O)C1=CC=C(C(=O)NNC)C=C1
FYTVIRMGRCDOSB-UHFFFAOYSA-N
0.000
abstract
1

SLWIPPZWFZGHEU-UHFFFAOYSA-N
2-[4-(carboxymethyl)phenyl]acetic acid
Chemical compound

OC(=O)CC1=CC=C(CC(O)=O)C=C1
SLWIPPZWFZGHEU-UHFFFAOYSA-N
0.000
abstract
1

IYEYXZCZYYIUBF-UHFFFAOYSA-N
2-chlorobenzene-1,4-dicarbohydrazide
Chemical compound

NNC(=O)C1=CC=C(C(=O)NN)C(Cl)=C1
IYEYXZCZYYIUBF-UHFFFAOYSA-N
0.000
abstract
1

MSWAXXJAPIGEGZ-UHFFFAOYSA-N
2-chlorobenzene-1,4-dicarbonyl chloride
Chemical compound

ClC(=O)C1=CC=C(C(Cl)=O)C(Cl)=C1
MSWAXXJAPIGEGZ-UHFFFAOYSA-N
0.000
abstract
1

UFHFLCQGNIYNRP-UHFFFAOYSA-N
Hydrogen
Chemical compound

[H][H]
UFHFLCQGNIYNRP-UHFFFAOYSA-N
0.000
abstract
1

QSBINWBNXWAVAK-PSXMRANNSA-N
PE-NMe(16:0/16:0)
Chemical compound

CCCCCCCCCCCCCCCC(=O)OC[C@H](COP(O)(=O)OCCNC)OC(=O)CCCCCCCCCCCCCCC
QSBINWBNXWAVAK-PSXMRANNSA-N
0.000
abstract
1

239000002253
acid
Substances

0.000
abstract
1

230000002378
acidificating effect
Effects

0.000
abstract
1

ALHNLFMSAXZKRC-UHFFFAOYSA-N
benzene-1,4-dicarbohydrazide
Chemical compound

NNC(=O)C1=CC=C(C(=O)NN)C=C1
ALHNLFMSAXZKRC-UHFFFAOYSA-N
0.000
abstract
1

150000001805
chlorine compounds
Chemical class

0.000
abstract
1

229920001577
copolymer
Polymers

0.000
abstract
1

PFWZLYYJIRGACT-UHFFFAOYSA-N
cyclohexa-1,4-diene-1,4-dicarbonyl chloride
Chemical compound

ClC(=O)C1=CCC(C(Cl)=O)=CC1
PFWZLYYJIRGACT-UHFFFAOYSA-N
0.000
abstract
1

HPNMFZURTQLUMO-UHFFFAOYSA-N
diethylamine
Chemical compound

CCNCC
HPNMFZURTQLUMO-UHFFFAOYSA-N
0.000
abstract
1

SWRGUMCEJHQWEE-UHFFFAOYSA-N
ethanedihydrazide
Chemical compound

NNC(=O)C(=O)NN
SWRGUMCEJHQWEE-UHFFFAOYSA-N
0.000
abstract
1

229910052739
hydrogen
Inorganic materials

0.000
abstract
1

239000001257
hydrogen
Substances

0.000
abstract
1

125000002496
methyl group
Chemical group

[H]C([H])([H])*

0.000
abstract
1

150000007530
organic bases
Chemical class

0.000
abstract
1

OTPQUWGVUDNOLP-UHFFFAOYSA-N
pyridine-2,5-dicarbohydrazide
Chemical compound

NNC(=O)C1=CC=C(C(=O)NN)N=C1
OTPQUWGVUDNOLP-UHFFFAOYSA-N
0.000
abstract
1

RWEWEOKGGLQXPR-UHFFFAOYSA-N
pyridine-2,5-dicarbonyl chloride
Chemical compound

ClC(=O)C1=CC=C(C(Cl)=O)N=C1
RWEWEOKGGLQXPR-UHFFFAOYSA-N
0.000
abstract
1

238000009987
spinning
Methods

0.000
abstract
1

LXEJRKJRKIFVNY-UHFFFAOYSA-N
terephthaloyl chloride
Chemical compound

ClC(=O)C1=CC=C(C(Cl)=O)C=C1
LXEJRKJRKIFVNY-UHFFFAOYSA-N
0.000
abstract
1

YBRBMKDOPFTVDT-UHFFFAOYSA-N
tert-butylamine
Chemical compound

CC(C)(C)N
YBRBMKDOPFTVDT-UHFFFAOYSA-N
0.000
abstract
1

229940073455
tetraethylammonium hydroxide
Drugs

0.000
abstract
1

LPSKDVINWQNWFE-UHFFFAOYSA-M
tetrapropylazanium;hydroxide
Chemical compound

[OH-].CCC[N+](CCC)(CCC)CCC
LPSKDVINWQNWFE-UHFFFAOYSA-M
0.000
abstract
1

Classifications

C—CHEMISTRY; METALLURGY

C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON

C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients

C08K5/00—Use of organic ingredients

C08K5/16—Nitrogen-containing compounds

Abstract

1479394 Polyhydrazide solutions E I DU PONT DE NEMOURS & CO 22 Sept 1975 [23 Sept 1974] 38787/75 Heading C3R A solution from which fibres and films may be made comprises a palyhydrazide or copolyhydrazide dissolved in an aqueous solution of an organic base. The polymer has equimolar amounts of repeating units of formulµ where R1 and R2 are divalent radicals or bonds and R3 is hydrogen or methyl. Fibres are obtained by spinning the solution into a dilute acidic bath. The polymers are obtained by reacting dihydrazides with dicarboxylic acid chlorides. In examples the dihydrazides are terephthalic dihydrazide, chloroterephthalic dihydrazide, oxalic dihydrazide, terephthalic acid bis(2 – methylhydrazide), p – phenylenediacetic acid dihydrazide, 2,5 – pyridinedicarboxylic acid dihydrazide and isophthalic dihydrazide; the acid chlorides are terephthaloyl chloride, 2,5 – pyridinedicarbonyl chloride, chloroterephthaloyl chloride, oxalyl chloride, 5 – tert. – butylisophthaloyl chloride, 4,41– bibenzoyl chloride and 2,5 – dihydroterephthaloyl chloride; various polymers and copolymers are prepared and dissolved in aqueous solutions of the organic bases tetraethylammonium hydroxide, tetramethylammonium hydroxide, diethylamine, piperidine, tert.-butylamine, methylbutylamine, pyrrolidine, triethylamine and tetrapropylammonium hydroxide.

GB38787/75A
1974-09-23
1975-09-22
Solutions of polyhydrazides

Expired

GB1479394A
(en)

Applications Claiming Priority (1)

Application Number
Priority Date
Filing Date
Title

US05/508,654

US3966656A
(en)

1974-09-23
1974-09-23
Aqueous organic base solution of polyhydrazides

Publications (1)

Publication Number
Publication Date

GB1479394A
true

GB1479394A
(en)

1977-07-13

Family
ID=24023543
Family Applications (1)

Application Number
Title
Priority Date
Filing Date

GB38787/75A
Expired

GB1479394A
(en)

1974-09-23
1975-09-22
Solutions of polyhydrazides

Country Status (8)

Country
Link

US
(1)

US3966656A
(en)

JP
(1)

JPS5922744B2
(en)

CA
(1)

CA1060641A
(en)

DE
(1)

DE2542422C2
(en)

FR
(1)

FR2285436A1
(en)

GB
(1)

GB1479394A
(en)

IT
(1)

IT1054315B
(en)

NL
(1)

NL182968C
(en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

DE2744621A1
(en)

*

1977-10-04
1979-04-12
Akzo Gmbh

ZINC COMPOUNDS OF TEREPHTHALOYL-TEREPHTHAL/OXAL-COPOLYHYDRAZIDE

US4461887A
(en)

*

1981-03-02
1984-07-24
Polaroid Corporation
Birefringent polymer containing recurring units from dienoic acid

US4393196A
(en)

*

1981-03-02
1983-07-12
Polaroid Corporation
Polymers containing recurring units from dienoic acid

JP5626751B2
(en)

*

2009-08-31
2014-11-19
学校法人神奈川大学

Method for producing poly (diacylhydrazine) and poly (diacylhydrazine)

Family Cites Families (5)

* Cited by examiner, † Cited by third party

Publication number
Priority date
Publication date
Assignee
Title

US3130182A
(en)

*

1960-08-11
1964-04-21
Du Pont
Wholly aromatic polyhydrazides

US3130183A
(en)

*

1960-09-06
1964-04-21
Du Pont
Polyhydrazides from oxalic acid dihydrazides and aromatic dicarboxylic acid halides

DE1694328B2
(en)

*

1967-05-10
1974-07-18
Enka Glanzstoff Ag, 5600 Wuppertal

Dissolving polyhydrazides

US3536651A
(en)

*

1967-10-04
1970-10-27
Du Pont
Aromatic polyhydrazide solutions and articles

US3842028A
(en)

*

1972-07-19
1974-10-15
Monsanto Co
Process for preparing spinning solutions of polyhydrazides

1974

1974-09-23
US
US05/508,654
patent/US3966656A/en
not_active
Expired – Lifetime

1975

1975-09-19
CA
CA236,058A
patent/CA1060641A/en
not_active
Expired

1975-09-22
FR
FR7528989A
patent/FR2285436A1/en
active
Granted

1975-09-22
IT
IT27506/75A
patent/IT1054315B/en
active

1975-09-22
GB
GB38787/75A
patent/GB1479394A/en
not_active
Expired

1975-09-22
JP
JP50113784A
patent/JPS5922744B2/en
not_active
Expired

1975-09-23
NL
NLAANVRAGE7511211,A
patent/NL182968C/en
not_active
IP Right Cessation

1975-09-23
DE
DE2542422A
patent/DE2542422C2/en
not_active
Expired

Also Published As

Publication number
Publication date

DE2542422A1
(en)

1976-04-01

NL182968B
(en)

1988-01-18

DE2542422C2
(en)

1986-05-22

IT1054315B
(en)

1981-11-10

JPS5163862A
(en)

1976-06-02

NL7511211A
(en)

1976-03-25

FR2285436B1
(en)

1981-10-09

CA1060641A
(en)

1979-08-21

FR2285436A1
(en)

1976-04-16

JPS5922744B2
(en)

1984-05-29

NL182968C
(en)

1988-06-16

US3966656A
(en)

1976-06-29

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Legal Events

Date
Code
Title
Description

1977-11-23
PS
Patent sealed [section 19, patents act 1949]

1990-05-16
PCNP
Patent ceased through non-payment of renewal fee

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