GB1517308A – Non-contaminating anode for electro-winning applications
– Google Patents
GB1517308A – Non-contaminating anode for electro-winning applications
– Google Patents
Non-contaminating anode for electro-winning applications
Info
Publication number
GB1517308A
GB1517308A
GB44519/75A
GB4451975A
GB1517308A
GB 1517308 A
GB1517308 A
GB 1517308A
GB 44519/75 A
GB44519/75 A
GB 44519/75A
GB 4451975 A
GB4451975 A
GB 4451975A
GB 1517308 A
GB1517308 A
GB 1517308A
Authority
GB
United Kingdom
Prior art keywords
layer
anode
mno
substrate
alloy
Prior art date
1974-11-04
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB44519/75A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Vale Canada Ltd
Original Assignee
Vale Canada Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1974-11-04
Filing date
1975-10-29
Publication date
1978-07-12
1975-10-29
Application filed by Vale Canada Ltd
filed
Critical
Vale Canada Ltd
1978-07-12
Publication of GB1517308A
publication
Critical
patent/GB1517308A/en
Status
Expired
legal-status
Critical
Current
Links
Espacenet
Global Dossier
Discuss
Classifications
C—CHEMISTRY; METALLURGY
C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
C25C7/02—Electrodes; Connections thereof
Abstract
1517308 Anodes for electrowinning; electrodeposition INCO Ltd 29 Oct 1975 [4 Nov 1974] 44519/75 Heading C7B An insoluble anode for electrowinning Ni, Cu, Co or Zn from an aqueous solution, e.g. containing 40 to 60 g/l Ni ions, 42 g/l H 2 SO 4 , 10 (or 5) g/l H 3 BO 3 and 3 to 5 g/l Mg ions, comprises a substrate of Ti, Zr, Ta or alloy thereof coated successively with a flash layer, e.g. 0.01 to 1 micron thick, of a Pt group metal (preferably Pt, Pd, Ru or Rh) or alloy thereof, an adherent PbO 2 layer and an adherent MnO 2 layer, e.g. respectively 50 to 2000 and 10 to 1000 microns thick. The successive coatings are preferably electro-deposited: e.g. Pt from a bath containing 5 g/l Pt as H 2 Pt(NO 2 ) 2 SO 4 dissolved in aqueous H 2 SO 4 using a Pt anode; PbO 2 from an aqueous bath containing 100 to 300 g/l Pb(NO 3 ) 2 , 20 to 200 ml/l concentrated nitric acid and 10 mg/l polypropyleneglycol methyl ether wetting agent using a stainless steel cathode; and MnO 2 from an aqueous bath containing 100 to 150 g/l MnSO 4 .H 2 O and 10 to 30 g/l H 2 SO 4 (or Mn(NO 3 ) 2 and HNO 3 ) using a Pb alloy cathode. Alternatively the MnO 2 layer may be deposited by repeated thermal decomposition of Mn(NO 3 ) 2 at 190C, and can be renewed for reconditioning the anode. The substrate may be in bulk, e.g. in the form of rods, sheet, foraminous structures such as expanded metal or porous sintered compacts of metal powder; or as a layer, coating or sheath on another material e.g. Cu. The substrate e.g. Ti mesh may be sand blasted, treated with detergent comprising complex organic phosphates and sulphonates, degreased with acetone and dipped in boiling concentrated HCl prior to electrodeposition.
GB44519/75A
1974-11-04
1975-10-29
Non-contaminating anode for electro-winning applications
Expired
GB1517308A
(en)
Applications Claiming Priority (1)
Application Number
Priority Date
Filing Date
Title
CA212,965A
CA1041944A
(en)
1974-11-04
1974-11-04
Non-contaminating anode suitable for electrowinning applications
Publications (1)
Publication Number
Publication Date
GB1517308A
true
GB1517308A
(en)
1978-07-12
Family
ID=4101532
Family Applications (1)
Application Number
Title
Priority Date
Filing Date
GB44519/75A
Expired
GB1517308A
(en)
1974-11-04
1975-10-29
Non-contaminating anode for electro-winning applications
Country Status (9)
Country
Link
US
(1)
US4051000A
(en)
JP
(1)
JPS5168406A
(en)
BR
(1)
BR7507152A
(en)
CA
(1)
CA1041944A
(en)
FR
(1)
FR2289635A1
(en)
GB
(1)
GB1517308A
(en)
NO
(1)
NO144638C
(en)
ZA
(1)
ZA756492B
(en)
ZM
(1)
ZM15075A1
(en)
Families Citing this family (15)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
US4140617A
(en)
*
1976-05-25
1979-02-20
Dzhaparidze Levan N
Anode for producing electrolytic manganese dioxide
CA1074250A
(en)
*
1977-03-21
1980-03-25
John Ambrose
Anodic deposition of manganese dioxide during electrowinning
AU523857B2
(en)
*
1978-07-14
1982-08-19
International Nickel Inc.
Alloys and electrodes
US4265728A
(en)
*
1978-11-03
1981-05-05
Diamond Shamrock Corporation
Method and electrode with manganese dioxide coating
US4422917A
(en)
*
1980-09-10
1983-12-27
Imi Marston Limited
Electrode material, electrode and electrochemical cell
JPS5754291A
(en)
*
1980-09-18
1982-03-31
Agency Of Ind Science & Technol
Electrolytic extraction of nickel by lead dioxide electrode
US5344538A
(en)
*
1993-01-11
1994-09-06
Gould Inc.
Thin plate anode
CN102465314A
(en)
*
2010-11-17
2012-05-23
北京有色金属研究总院
Preprocessing method of lead/lead-alloy inert anode for zinc electrowinning
US9595360B2
(en)
2012-01-13
2017-03-14
Energy Power Systems LLC
Metallic alloys having amorphous, nano-crystalline, or microcrystalline structure
US9263721B2
(en)
2012-01-13
2016-02-16
Energy Power Systems LLC
Lead-acid battery design having versatile form factor
WO2013106419A1
(en)
*
2012-01-13
2013-07-18
Energy Power Systems Llc.
Improved substrate for electrode of electrochemical cell
US8808914B2
(en)
2012-01-13
2014-08-19
Energy Power Systems, LLC
Lead-acid battery design having versatile form factor
CN103993330A
(en)
*
2014-05-07
2014-08-20
成都理工大学
Zinc electrolysis technology of zinc ammonia complex aqueous solution
CN104947147B
(en)
*
2015-06-24
2017-04-12
昆明理工大学
Method of recovering valuable metal in copper-containing tantalum-niobium waste materials by adopting frame type anode device direct electrolysis and acid leaching combined method
RU2724264C1
(en)
*
2020-02-04
2020-06-22
Федеральное государственное учреждение «Федеральный научно-исследовательский центр «Кристаллография и фотоника» Российской академии наук»
Method of producing nickel-bearing nanorods with controlled aspect ratio
Family Cites Families (6)
* Cited by examiner, † Cited by third party
Publication number
Priority date
Publication date
Assignee
Title
US3207679A
(en)
*
1960-05-03
1965-09-21
American Potash & Chem Corp
Method for electroplating on titanium
US3213004A
(en)
*
1961-03-08
1965-10-19
American Potash & Chem Corp
Surface preparation of platinum group metals for electrodeposition
US3616302A
(en)
*
1967-02-27
1971-10-26
Furerkawa Electric Co Ltd The
Insoluble anode for electrolysis and a method for its production
US3855084A
(en)
*
1973-07-18
1974-12-17
N Feige
Method of producing a coated anode
JPS5072878A
(en)
*
1973-09-05
1975-06-16
US3850764A
(en)
*
1974-04-11
1974-11-26
Corning Glass Works
Method of forming a solid tantalum capacitor
1974
1974-11-04
CA
CA212,965A
patent/CA1041944A/en
not_active
Expired
1975
1975-10-14
ZA
ZA00756492A
patent/ZA756492B/en
unknown
1975-10-28
US
US05/625,899
patent/US4051000A/en
not_active
Expired – Lifetime
1975-10-29
GB
GB44519/75A
patent/GB1517308A/en
not_active
Expired
1975-10-30
NO
NO753656A
patent/NO144638C/en
unknown
1975-10-31
ZM
ZM150/75A
patent/ZM15075A1/en
unknown
1975-10-31
FR
FR7533397A
patent/FR2289635A1/en
active
Granted
1975-10-31
BR
BR7507152*A
patent/BR7507152A/en
unknown
1975-11-04
JP
JP50131563A
patent/JPS5168406A/en
active
Granted
Also Published As
Publication number
Publication date
ZA756492B
(en)
1976-09-29
US4051000A
(en)
1977-09-27
ZM15075A1
(en)
1976-12-21
NO144638B
(en)
1981-06-29
JPS5168406A
(en)
1976-06-14
BR7507152A
(en)
1976-08-10
NO753656L
(en)
1976-05-05
FR2289635A1
(en)
1976-05-28
AU8585075A
(en)
1977-04-28
CA1041944A
(en)
1978-11-07
NO144638C
(en)
1981-10-07
FR2289635B1
(en)
1980-01-11
JPS569236B2
(en)
1981-02-27
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Legal Events
Date
Code
Title
Description
1978-11-08
PS
Patent sealed [section 19, patents act 1949]
1984-07-11
PCNP
Patent ceased through non-payment of renewal fee
