GB1584881A

GB1584881A – Ocular membrane and method for the preparation thereof
– Google Patents

GB1584881A – Ocular membrane and method for the preparation thereof
– Google Patents
Ocular membrane and method for the preparation thereof

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Publication number
GB1584881A

GB1584881A
GB15725/77A
GB1572577A
GB1584881A
GB 1584881 A
GB1584881 A
GB 1584881A
GB 15725/77 A
GB15725/77 A
GB 15725/77A
GB 1572577 A
GB1572577 A
GB 1572577A
GB 1584881 A
GB1584881 A
GB 1584881A
Authority
GB
United Kingdom
Prior art keywords
zone
extrapupillary
membrane
ocular
ocular membrane
Prior art date
1976-04-15
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired

Application number
GB15725/77A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Individual

Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
1976-04-15
Filing date
1977-04-15
Publication date
1981-02-18

1977-04-15
Application filed by Individual
filed
Critical
Individual

1981-02-18
Publication of GB1584881A
publication
Critical
patent/GB1584881A/en

Status
Expired
legal-status
Critical
Current

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Classifications

C—CHEMISTRY; METALLURGY

C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON

C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients

C08K5/00—Use of organic ingredients

C08K5/04—Oxygen-containing compounds

C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof

C08K5/092—Polycarboxylic acids

B—PERFORMING OPERATIONS; TRANSPORTING

B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL

B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING

B29C33/00—Moulds or cores; Details thereof or accessories therefor

B29C33/44—Moulds or cores; Details thereof or accessories therefor with means for, or specially constructed to facilitate, the removal of articles, e.g. of undercut articles

B29C33/52—Moulds or cores; Details thereof or accessories therefor with means for, or specially constructed to facilitate, the removal of articles, e.g. of undercut articles soluble or fusible

B—PERFORMING OPERATIONS; TRANSPORTING

B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL

B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE

B29D11/00—Producing optical elements, e.g. lenses or prisms

B29D11/00009—Production of simple or compound lenses

B29D11/00038—Production of contact lenses

B29D11/00067—Hydrating contact lenses

C—CHEMISTRY; METALLURGY

C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON

C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS

C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G

C08F283/12—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polysiloxanes

C—CHEMISTRY; METALLURGY

C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON

C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS

C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule

C08G77/04—Polysiloxanes

C08G77/38—Polysiloxanes modified by chemical after-treatment

C—CHEMISTRY; METALLURGY

C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON

C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients

C08K5/00—Use of organic ingredients

C08K5/04—Oxygen-containing compounds

C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof

C—CHEMISTRY; METALLURGY

C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON

C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients

C08K5/00—Use of organic ingredients

C08K5/04—Oxygen-containing compounds

C08K5/10—Esters; Ether-esters

C—CHEMISTRY; METALLURGY

C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON

C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients

C08K5/00—Use of organic ingredients

C08K5/04—Oxygen-containing compounds

C08K5/10—Esters; Ether-esters

C08K5/101—Esters; Ether-esters of monocarboxylic acids

C08K5/103—Esters; Ether-esters of monocarboxylic acids with polyalcohols

B—PERFORMING OPERATIONS; TRANSPORTING

B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL

B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS

B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds

B29K2995/0037—Other properties

B29K2995/0065—Permeability to gases

B—PERFORMING OPERATIONS; TRANSPORTING

B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL

B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS

B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds

B29K2995/0037—Other properties

B29K2995/0093—Other properties hydrophobic

Description

PATENT SPECIFICATION
( 11) 1 584881 ( 21) Application No 15725/77 ( 22) Filed 15 April 1977 ( 19) ( 31) Convention Application No 677246 ( 32) Filed 15 April 1976 in k O ( 33) United States of America (US) C: ( 44) Complete Specification published 18 Feb 1981 < ( 51) INT CL 3 GO 2 C 7/04 ( 52) Index at acceptance G 2 J 56 C ( 54) OCULAR MEMBRANE AND METHOD FOR THE PREPARATION THEREOF ( 71) I, WILLIAM SETH COVINGTON, a citizen of the United States of America, of Litchfield County, West Cornwall, Connecticut 06796, United States of America, do hereby declare the invention, for which I pray that a patent may be granted to me, and the method by which it is to be performed, to be particularly described in and by the following statement:- This invention relates to an ocular membrane, more particularly to a disposable, ultrathin ocular membrane which can be worn for long periods of time without discomfort. The present invention provides an ocular membrane made of a single homogeneous material and comprising a pupillary zone and an extrapupillary zone concentrically disposed about the pupillary zone, the said extrapupillary zone having an average thickness less than the thickness of the said pupillary zone, and the extrapupillary zone having sufficient elasticity to be deformed by the eyelid during the normal blinking process when the ocular membrane is disposed on the eye of the wearer to form folds in the extrapupillary zone of the ocular membrane. Preferably the pupillary zone is relatively thicker and hence less elastic than the extrapupillary zone to the extent that the pupillary zone will not be deformed by an eyelid during the normal blinking process. The ocular membrane according to the present invention may be formed from a composition as described and claimed in my co-pending Application No 48502/78 (Serial No 1584882) and/or may be formed by the method described and claimed in either of my co-pending Application Nos 48503/78 and 48729/78 (Serial Nos 1584883 and 1584884). The invention will be further described, by way of example only, with reference to the accompanying drawings, in which: Figure 1 is a top plan view of an ocular membrane in accordance with the present invention; Figures 2-4 are cross-sectional view of ocular membranes in accordance with the present invention; Figure 5 shows an ocular membrane in accordance with the present invention in position when operatively placed on the human eye; Figure Sa is an enlarged view of a portion of Figure 5; and 55 Figure 6 is an enlarged view of a portion of an ocular membrane of the present invention. Referring to the drawings, Figures 1 and 2 are plan and cross-sectional views respectively of an ocular membrane of the present inven 60 tion made of a single homogeneous material, while Figures 3 and 4 are cross-sectional views of other ocular membranes of the present invention which are also each made of a single homogeneous material Of course, 65 the specific shape of the membrane itself will depend upon the specific ophthalmic prescription required. Figures 1 and 2 show a planar membrane generally indicated at 10 having an anterior 70 surface 12 and a posterior surface 14 The pupillary zone of the membrane 16 is concentrically disposed with the extrapupillary zone 18 about the central axis 20 of the membrane The anterior surface meets 75 the posterior surface at the edge 22 of the membrane in a manner to be more fully described below. Figure 3 shows a plus membrane generally indicated at 24 having an extrapupillary 80 section 26 with a pupillary section 28 of a converging miniscus type, having an anterior surface 30 of the pupillary zone with a shorter radius of curvature than the posterior surface of the pupillary zone 32 The edge of 85 the membrane 34 is formed in the same manner as that of the membrane shown in Figure 2 and Figure 4 to be described below. Figures 4 and 5 show a minus power membrane generally' indicated at 36 posi 90 tioned on a human eye generally indicated at 38 partially beneath the eyelid 40 The pupillary zone 41 of the membrane 36 is a minus powered miniscus consisting of an anterior surface 42 having a larger radius of 95 curvature than the posterior pupillary surface 44. The extrapupillary zone 46 of the membrane 36 terminates at an edge 48 which is formed by an annular curved surface on the 100 1,584,881 anterior surface of the membrane which intersects with the uniformly curved extrapupillary surface of the posterior surface. The edges of the other ocular membranes also terminate in this manner which is most clearly shown in Figure 6, where the intersecting curved surface designated R 3 is formed on the anterior surface of the ocular membrane having a radius of curvature R 2, and R 3 intersects the uniformly curved extrapupillary posterior surface having a radius of curvature R 1. The important aspect of an ocular membrane of the present invention insofar as its physical form is concerned is the fact that it is extremely thin Thus, the ocular membranes as shown would have an average extrapupillary thickness of less than 0 10 mm. Because of this thinness and the resultant lightness and permeability of the material to oxygen and carbon dioxide, the membrane may simply be placed on the eye in the usual manner and may be retained there for a number of days, weeks and even months without adverse effects of the eye Additionally, the thickness of the membrane coupled with the elasticity of the composition makes the membrane extremely flexible so that it is deformable by pressure of the eye lid during the normal blinking cycle This deformation enhances circulation of the precorneal fluid further improving the metabolic compatibility of the membrane with the eye Of course, the period of time that a given ocular membrane can be worn will depend to a great extent on the wearer and the ophthalmic prescription involved However, it is clear that the ocular membrane of the present invention for any given wearer, can be worn for significantly greater periods than the conventional contact lenses presently known. As seen near the periphery of the membrane 36, a wrinkle or local temporary deformation 50 is produced during the blinking cycle This wrinkle which can be compared to a wave effect on the extrapupillary surface. The wrinkle literally produces a pumping action circulating corneal liquid from beyond the periphery of the membrane to and from under the membrane in order to enhance the metabolic compatibility of the membrane with the eye. Additionally, because the extrapupillary zone of the membrane is so thin, deformation produced by the blinking process is restricted to the extrapupillary section and does not in any way produce deformations in the pupillary zone of the membrane which would result in visual distortions to the wearer of the membrane This is made possible because the relative thinness of the extrapupillary section produces a relatively greater flexibility in the extrapupillary section than in the pupillary section of the membrane. Claims (4) WHAT I CLAIM IS:- 1 An ocular membrane made of a single homogeneous material and comprising a pupillary zone and an extrapupillary zone concentrically disposed about the pupillary zone, the said extrapupillary zone having an average thickness less than the thickness of the said pupillary zone, and the extrapupillary zone having sufficient elasticity to be deformed by the eyelid during the normal blinking process when the ocular membrane is disposed on the eye of the wearer to form folds in the extrapupillary zone of the ocular membrane. 2 An ocular membrane as claimed in Claim 1, wherein the pupillary zone is relatively thicker and hence less elastic than the extrapupillary zone to the extent that the pupillary zone will not be deformed by a eyelid during the normal blinking process. 3 An ocular membrane as claimed in Claim 1 or 2, wherein the average thickness of the extrapupillary zone is less than 010 mm. 4 An ocular membrane as claimed in any of Claims 1 to 3, wherein the said extrapupillary zone has anterior and posterior surfaces of substantially equal radius of curvature. An ocular membrane according to Claim 1, substantially as herein described with reference to, and as shown in, Figures 1 and 2, Figure 3 or Figure 4 of the accompanying drawings. MARKS & CLERK Printed for Her Majesty's Stationery Office by Burgess & Son (Abingdon), Ltd -1981. Published at The Patent Office, 25 Southampton Buildings, London, WC 2 A l AY, from which copies may be obtained. GB15725/77A 1976-04-15 1977-04-15 Ocular membrane and method for the preparation thereof Expired GB1584881A (en) Applications Claiming Priority (1) Application Number Priority Date Filing Date Title US05/677,246 US4169119A (en) 1976-04-15 1976-04-15 Method of molding an ocular membrane Publications (1) Publication Number Publication Date GB1584881A true GB1584881A (en) 1981-02-18 Family ID=24717926 Family Applications (4) Application Number Title Priority Date Filing Date GB48503/78A Expired GB1584883A (en) 1976-04-15 1977-04-15 Method of forming an ocular membrane GB48729/78A Expired GB1584884A (en) 1976-04-15 1977-04-15 Method of forming an ocular membrane GB48502/78A Expired GB1584882A (en) 1976-04-15 1977-04-15 Composition for forming an ocular membrane GB15725/77A Expired GB1584881A (en) 1976-04-15 1977-04-15 Ocular membrane and method for the preparation thereof Family Applications Before (3) Application Number Title Priority Date Filing Date GB48503/78A Expired GB1584883A (en) 1976-04-15 1977-04-15 Method of forming an ocular membrane GB48729/78A Expired GB1584884A (en) 1976-04-15 1977-04-15 Method of forming an ocular membrane GB48502/78A Expired GB1584882A (en) 1976-04-15 1977-04-15 Composition for forming an ocular membrane Country Status (15) Country Link US (1) US4169119A (en) JP (2) JPS5942850B2 (en) AU (1) AU2421877A (en) BE (1) BE853658A (en) CA (1) CA1097958A (en) CH (1) CH621002A5 (en) DE (1) DE2713444C2 (en) FR (2) FR2348249A1 (en) GB (4) GB1584883A (en) IL (1) IL51697A (en) IT (1) IT1086695B (en) NL (1) NL7704136A (en) NZ (2) NZ183696A (en) SE (1) SE7704080L (en) ZA (1) ZA771812B (en) Cited By (1) * Cited by examiner, † Cited by third party Publication number Priority date Publication date Assignee Title GB2239532A (en) * 1989-12-07 1991-07-03 Erich A Koeniger Bifocal contact lens Families Citing this family (24) * Cited by examiner, † Cited by third party Publication number Priority date Publication date Assignee Title US4245069A (en) * 1978-12-28 1981-01-13 Permavision Polysiloxane composition US4250127A (en) * 1977-08-17 1981-02-10 Connecticut Research Institute, Inc. Production of electron microscope grids and other micro-components US4276402A (en) * 1979-09-13 1981-06-30 Bausch & Lomb Incorporated Polysiloxane/acrylic acid/polcyclic esters of methacrylic acid polymer contact lens US4277595A (en) * 1979-09-13 1981-07-07 Bausch & Lomb Incorporated Water absorbing contact lenses made from polysiloxane/acrylic acid polymer US4254248A (en) * 1979-09-13 1981-03-03 Bausch & Lomb Incorporated Contact lens made from polymers of polysiloxane and polycyclic esters of acrylic acid or methacrylic acid DE3004685C2 (en) * 1980-02-08 1986-07-31 Titmus Eurocon Kontaktlinsen GmbH, 8750 Aschaffenburg Process for making contact lenses made of silicone rubber hydrophilic US4407766A (en) * 1981-05-26 1983-10-04 National Patent Development Corporation Molds and procedure for producing truncated contact lenses US4402579A (en) * 1981-07-29 1983-09-06 Lynell Medical Technology Inc. Contact-lens construction US4605524A (en) * 1984-11-19 1986-08-12 Danker Laboratories, Inc. Method and master-die for casting a bifocal contact lens in a single piece JPS61215629A (en) * 1985-03-22 1986-09-25 Nippon Shokubai Kagaku Kogyo Co Ltd Surface modifying composition US4734475A (en) * 1986-12-15 1988-03-29 Ciba-Geigy Corporation Wettable surface modified contact lens fabricated from an oxirane containing hydrophobic polymer JPH0812341B2 (en) * 1987-01-09 1996-02-07 株式会社メニコン Soft contact lens manufacturing method US6007747A (en) * 1987-08-24 1999-12-28 Pharmacia & Upjohn Company Method of making an aspheric soft lens EP0315836A3 (en) * 1987-10-30 1990-10-17 HÜLS AMERICA INC. (a Delaware corporation) Polyorganosiloxane based interpenetrating network polymers and methods of making US4923467A (en) * 1988-03-02 1990-05-08 Thompson Keith P Apparatus and process for application and adjustable reprofiling of synthetic lenticules for vision correction US5760100B1 (en) 1994-09-06 2000-11-14 Ciba Vision Corp Extended wear ophthalmic lens US7468398B2 (en) 1994-09-06 2008-12-23 Ciba Vision Corporation Extended wear ophthalmic lens US6467903B1 (en) * 2000-03-31 2002-10-22 Ocular Sciences, Inc. Contact lens having a uniform horizontal thickness profile US7628485B2 (en) * 2000-03-31 2009-12-08 Coopervision International Holding Company, Lp Contact lens having a uniform horizontal thickness profile US20070218007A1 (en) * 2006-03-17 2007-09-20 Allergan, Inc. Ophthalmic visualization compositions and methods of using same US8163358B2 (en) * 2009-02-18 2012-04-24 Synergeyes, Inc. Surface modification of contact lenses JP5707607B2 (en) * 2009-04-24 2015-04-30 Jnc株式会社 Organosilicon compound and thermosetting resin composition containing the same WO2017083774A1 (en) 2015-11-11 2017-05-18 Onefocus Vision, Inc. Accommodating lens with cavity CN113827179B (en) * 2021-09-26 2023-06-06 温州医科大学 Eyelid pressure detection method and device, medium and electronic equipment Family Cites Families (18) * Cited by examiner, † Cited by third party Publication number Priority date Publication date Assignee Title US2976576A (en) * 1956-04-24 1961-03-28 Wichterle Otto Process for producing shaped articles from three-dimensional hydrophilic high polymers US2959569A (en) * 1956-07-05 1960-11-08 Dow Corning Method of preparing organosilicon graft polymers US2970150A (en) * 1957-12-17 1961-01-31 Union Carbide Corp Processes for the reaction of silanic hydrogen-bonded siloxanes with unsaturated organic compounds with a platinum catalyst GB943600A (en) * 1959-03-26 1963-12-04 Oxley Robert Frederick Shaft couplings US3034403A (en) * 1959-04-03 1962-05-15 Neefe Hamilton Res Company Contact lens of apparent variable light absorption US3228741A (en) * 1962-06-29 1966-01-11 Mueller Welt Contact Lenses In Corneal contact lens fabricated from transparent silicone rubber US3518338A (en) * 1964-06-08 1970-06-30 William C Tambussi Molding process US3422168A (en) * 1964-12-01 1969-01-14 Ppg Industries Inc Process of casting resinous lenses in thermoplastic cast replica molds US3423488A (en) * 1966-05-11 1969-01-21 Ppg Industries Inc Process for casting resinous lenses in thermoplastic cast replica molds US3529054A (en) * 1967-11-15 1970-09-15 Burroughs Corp Method for fabricating printing drums US3830460A (en) * 1969-07-15 1974-08-20 Beattie Dev Co Polymeric replica molds and replication processes for producing plastic optical components FR2109470A5 (en) * 1970-10-19 1972-05-26 Silor US3715329A (en) * 1971-04-15 1973-02-06 Gen Electric Heat vulcanizable polysiloxane compositions containing asbestos US3916033A (en) * 1971-06-09 1975-10-28 High Voltage Engineering Corp Contact lens US3808178A (en) * 1972-06-16 1974-04-30 Polycon Laboratories Oxygen-permeable contact lens composition,methods and article of manufacture FR2240463B1 (en) * 1973-08-06 1976-04-30 Essilor Int GB1480880A (en) * 1974-05-06 1977-07-27 Bausch & Lomb Shaped body of a simultaneously interpenetrating network polymer and method of preparing same FR2365606A2 (en) * 1976-09-27 1978-04-21 Bausch & Lomb Solid object, partic. contact lens - prepd. from polymer with simultaneous inter-penetration networks formed from crosslinked hydrophilic and hydrophobic polymers 1976 1976-04-15 US US05/677,246 patent/US4169119A/en not_active Expired - Lifetime 1977 1977-03-18 IL IL51697A patent/IL51697A/en unknown 1977-03-24 NZ NZ183696A patent/NZ183696A/en unknown 1977-03-24 NZ NZ189240A patent/NZ189240A/en unknown 1977-03-25 ZA ZA00771812A patent/ZA771812B/en unknown 1977-03-26 DE DE2713444A patent/DE2713444C2/en not_active Expired 1977-04-04 CA CA275,488A patent/CA1097958A/en not_active Expired 1977-04-06 IT IT48852/77A patent/IT1086695B/en active 1977-04-06 SE SE7704080A patent/SE7704080L/en unknown 1977-04-08 FR FR7710744A patent/FR2348249A1/en active Granted 1977-04-12 CH CH448077A patent/CH621002A5/fr not_active IP Right Cessation 1977-04-12 JP JP52041027A patent/JPS5942850B2/en not_active Expired 1977-04-13 AU AU24218/77A patent/AU2421877A/en not_active Expired 1977-04-15 GB GB48503/78A patent/GB1584883A/en not_active Expired 1977-04-15 GB GB48729/78A patent/GB1584884A/en not_active Expired 1977-04-15 BE BE176768A patent/BE853658A/en not_active IP Right Cessation 1977-04-15 GB GB48502/78A patent/GB1584882A/en not_active Expired 1977-04-15 NL NL7704136A patent/NL7704136A/en not_active Application Discontinuation 1977-04-15 GB GB15725/77A patent/GB1584881A/en not_active Expired 1977-11-23 FR FR7735165A patent/FR2375615A1/en not_active Withdrawn 1982 1982-02-05 JP JP57017387A patent/JPS606971B2/en not_active Expired Cited By (2) * Cited by examiner, † Cited by third party Publication number Priority date Publication date Assignee Title GB2239532A (en) * 1989-12-07 1991-07-03 Erich A Koeniger Bifocal contact lens GB2239532B (en) * 1989-12-07 1993-08-25 Erich A Koeniger Biofocal contact lens Also Published As Publication number Publication date BE853658A (en) 1977-08-01 DE2713444A1 (en) 1977-11-03 JPS5942850B2 (en) 1984-10-18 IT1086695B (en) 1985-05-28 CH621002A5 (en) 1980-12-31 SE7704080L (en) 1977-10-16 FR2375615A1 (en) 1978-07-21 AU2421877A (en) 1978-10-19 IL51697A (en) 1980-12-31 US4169119A (en) 1979-09-25 NZ183696A (en) 1980-05-08 GB1584882A (en) 1981-02-18 JPS606971B2 (en) 1985-02-21 ZA771812B (en) 1978-04-26 DE2713444C2 (en) 1986-05-07 JPS57164153A (en) 1982-10-08 NL7704136A (en) 1977-10-18 GB1584883A (en) 1981-02-18 NZ189240A (en) 1980-05-08 FR2348249A1 (en) 1977-11-10 CA1097958A (en) 1981-03-24 FR2348249B1 (en) 1980-09-19 JPS52145458A (en) 1977-12-03 GB1584884A (en) 1981-02-18 Similar Documents Publication Publication Date Title GB1584881A (en) 1981-02-18 Ocular membrane and method for the preparation thereof US3228741A (en) 1966-01-11 Corneal contact lens fabricated from transparent silicone rubber CA1116446A (en) 1982-01-19 Semi-scleral contact lens US3973838A (en) 1976-08-10 Contact lenses KR890000205B1 (en) 1989-03-10 Intracolar lens implants US4787732A (en) 1988-11-29 Contact lens and method of making same US4193672A (en) 1980-03-18 Contact lens with improved interior surface JPH07506014A (en) 1995-07-06 Methods to change the curvature of the cornea JPS59208524A (en) 1984-11-26 Continuously varying multifocus soft contact lens and manufacture thereof JPS60501273A (en) 1985-08-08 Hydrophilic bifocal contact lenses WO1989007281A1 (en) 1989-08-10 Pattern contact lens US3698802A (en) 1972-10-17 Hydrophilic contact lens EP0235328B1 (en) 1993-04-21 Contact lens for the eye of a patient with keratoconus disease and method of making the same US4820038A (en) 1989-04-11 Hydrogel contact lens US4103992A (en) 1978-08-01 Corneal contact lens and method of making the same EP0551439B1 (en) 1995-08-09 Apparatus for surgically profiling the cornea using vacuum US4126138A (en) 1978-11-21 Soft contact lens Lyons et al. 1989 Development of the gas‐permeable impression‐moulded scleral contact lens: a preliminary report WO1998052090A1 (en) 1998-11-19 Improved contact lens CN208552131U (en) 2019-03-01 The intraocular lens of optical section punching KR0129569Y1 (en) 1999-05-01 Contact lense US4948245A (en) 1990-08-14 Hydrogel contact lens EP0242795A2 (en) 1987-10-28 Contact lens for the eye of a patient with an abnormally flattened cornea and method of making same US20220011599A1 (en) 2022-01-13 Orthokeratology lens with displaced shaping zone LASCOLA 1970 The scleral cosmetic shell: technique and method Legal Events Date Code Title Description 1981-05-28 PS Patent sealed [section 19, patents act 1949] 1984-12-19 PCNP Patent ceased through non-payment of renewal fee
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